• 한국전기전자재료학회논문지
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• 제11권10호
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• pp.931-939
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• 1998

Preparation of the hexagonal Sr-ferrite powsers with high performance by co-spraying precusor of the FeCl$_2$+SrCO$_3$ at a low temperature was proved as a cost =-effective method. The co-spray roasting was carried out in the temperature range of 300~$700^{\circ}C$ after SrCO$_3$ powders were mixed into 12FeCi$_2$.4$H_2O$ liquor. By this low temperature roasting method fine particles of multi-phased FeO$_2$+SrCO$_3$ were formulated. Powders calcined at 105$0^{\circ}C$ for 1 hour show the best magnetic property of M\ulcorner=69.96 emu/g, M\ulcorner=36.98 emu/g, and \ulcornerH\ulcorner=4.31 Oe. This calcining temperature is lower than that of the conventional dry method by 10$0^{\circ}C$.

• 한국분무공학회지
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• 제20권1호
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• pp.20-27
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• 2015

Urea-SCR which is one of the aftertreatment technologies for reducing the NOx emission is widely used. An experimental study was performed to investigate urea decomposition under various thermo-fluid conditions, with different temperatures and velocities of inflow gas, and urea solution quantities. 40 wt. % aqueous urea solutions were used in this study. The inflow gas conditions were similar to the exhaust conditions of a large marine engine. The spray performance of urea solution injector was identical under all experimental conditions. The conversion efficiency of $NH_3$ was larger than that of HNCO under all experimental conditions, unlike for the theoretical thermolysis reaction.

• 한국초전도저온공학회:학술대회논문집
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• 한국초전도저온공학회 2003년도 추계학술대회 논문집
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• pp.99-102
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• 2003

Many researches on synthesis process for BSCCO precursor powders have been developed for high J$_{c}$ BSCCO-2223/Ag tape. Spray pyrolysis method for fabrication of precursor powder has many advantages, such as high purity, fine particle size of BSCCO precursor powder. Fine, spherical powders were prepared by ultrasonic spray pyrolysis from the aqueous solution of metal nitrates. BSCCO precursor powders were synthesized with 0.1 M concentration and heat treatment conditions. Average particle size for spray pyrolysis powders was 1.5 ~ 3 ${\mu}{\textrm}{m}$. BSCCO -2223/Ag tape was prepared by PIT method and followed by various sintering conditions. The critical current density of BSCCO-2223/Ag tape sintered in low oxygen partial pressure was ~ 23 kAcm$^{-2}$.

• Korean Chemical Engineering Research
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• 제43권5호
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• pp.616-620
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• 2005

Ammonium dihydrogen phosphate 융제의 첨가가 고온 분무열분해 공정에 의해 합성된 녹색 발광의 헥사알루미네이트계 형광체의 형태 및 발광 특성에 미치는 영향을 보았다. 융제를 함유하지 않은 분무용액으로부터 반응기 온도 $900^{\circ}C$ 에서 $1,650^{\circ}C$ 사이에서 합성된 분말은 매우 속이 빈 형태를 가졌다. 반면에 ammonium dihydrogen phosphate 융제를 첨가한 분무용액으로부터 반응기 온도 $900^{\circ}C$ 에서 $1,650^{\circ}C$ 사이에서 합성된 분말은 완벽한 구형 형상을 가지면서 치밀한 구조를 가졌다. 반응기 온도 $1,600^{\circ}C$ 이상에서 ammonium dihydrogen phosphate 융제를 첨가한 분무용액으로부터 마그네토플룸비아트 구조를 가지는 헥사알루미네이트 형광체 분말이 합성되었다. Ammonium dihydrogen phosphate 융제는 저온에서 형광체의 발광 특성을 증가시키는데 효과적이었다. 반응기 온도 $1,650^{\circ}C$의 환원분위기하에서 분무열분해 공정에 의해 직접 제조된 형광체는 융제의 첨가 유무에 무관하게 후열처리 과정을 통해 최적화된 형광체와 유사한 발광 세기를 가졌다.

• 한국입자에어로졸학회지
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• 제8권2호
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• pp.69-74
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• 2012

This study describes how successfully a conventional flame aerosol synthesis was used to continuously synthesize Pt-Ru catalysts supported by carbon agglomerates. Nearly spherical catalysts produced in the flame were mainly composed of metallic Pt and Ru with the molar ratio of 1:1 and those sizes were controllable from ~1.5 nm to ~2.0 nm. Nevertheless, only Pt peaks were found from X-ray diffraction experiments, suggesting that amorphous-like Ru was well mixed in the crystalline Pt lattices. It was found from Cyclo-voltamograms and CO stripping experiments that the electrochemical properties of the catalysts are at least comparable to that of a conventional commercial sample.

• 한국초전도ㆍ저온공학회논문지
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• 제10권1호
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• pp.19-23
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• 2008

Spherical $MgB_2$ powders was synthesized with the ultrasonic spray pyrolysis(USP) process using aqueous solutions of boron and magnesium ion. The properties of synthesized $MgB_2$ powder were characterized by XRD, SEM and EDS. A small amount of MgO was detected as the secondary phase out of the synthesized powder and the ratios of $MgB_2$ to MgO increased with increasing furnace temperature. The particle size and morphology of $MgB_2$ powder were investigated with varying molar concentration of the boron and magnesium solution and furnace temperature between $600^{\circ}C$ and $1000^{\circ}C$ in $Ar/H_2$. The average particle size of $MgB_2$ showed narrow distribution ranging from 300nm to 400nm. The morphology of particles exhibited mostly spherical shapes and uniform distribution.

• 한국결정성장학회지
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• 제4권2호
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• pp.178-189
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• 1994

$BaTiO_3$ 미분말은 여러종류의 0.05 M 출발용액으로부터 초음파 분무 열분해법으로 합성하였다. 이때, 유속은 0.5 cm/sec, 저온로는 $300^{\circ}C$, 고온로는$700^{\circ}C$로 고정하였다. 입자의 형성과정은 반응 단계별로 포집된 분말을 SEM으로 직접 관찰하였고 또한, 반응기내에서의 입자의 거동을 이론적으올 고찰하고자 하였다. 순수한 $BaTiO_3$ 미분말은 출발용액이 nitrate aqueous solution인 경우에 합성이 가능하였다. 합성된 미분말은 19.1 nm의 일차입자들로 구성된 porous한 약 $0.42 {mu}m$크기의 구형의 이차임자였다. 형성과정은 건조단계에서 입자의 크기가 감소한 후 열분해 초기단계에서 증가하고 반응이 진행됨에 따라 점차 다시 감소하여 최종 $0.42 {mu}m$의 고화된 입자로 되었고 입도분포는 반응이 진행됨에 따라 점차 넓어졌다. 또한, 반응기내에서 입자들의 이론적 거동은 반응기 중심쪽으로 향하여 진행된다.