• Title/Summary/Keyword: 재염소

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제주도 대체수자원 확보를 위한 하수처리장 방류수 재이용 연구

  • Kang, Bong-Rae;Kim, Geon-Tae;Koh, Gi-Won;Heo, Mok
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2003.09a
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    • pp.180-183
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    • 2003
  • 제주지역 하수종말처리장에서 발생하는 방류수(2차 처리수)를 재이용함으로써 지하수에 편중된 제주도의 용수 이용패턴을 다원화하는 대체수자원으로 활용하기 위하여 2001년 6월부터 하수처리장 방류수 재이용 방안연구를 실시하였다. 제주도내에서 운영 중인 3개 하수종말처리장의 방류수에 대한 장기적인 수질검사 결과, 염소이온 함량이 높아 재처리를 하지 않은 상태로 재이용 하기는 곤란한 것으로 파악되었다. 따라서, 재처리를 위한 최적의 공정을 선정하기 위해 pilot test를 실시한 결과, 방류수를 MF(정밀여과)막 전처리 + RO(역삼투)막 처리의 재처리 공정으로부터 재처리된 물(3차 처리수)의 수질은 먹는물로 사용하더라도 전혀 문제가 없을 만큼 깨끗하게 처리되었다. 따라서 방류수 배출량이 많은 제주시 도두 하수처리장과 서귀포 보목 하수처리장의 방류수를 재처리하여 비음용 생활용수, 골프장 관개 수용수, 농업용수, 지하수 인공 함양용수 등으로 재이용하는 방안을 제시하였다.

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Estimation on the Durability of High-Strength Concrete using Metakaolin (Metakaolin 혼합 고강도 콘크리트의 내구특성 예측)

  • Lee, Sang-Ho;Moon, Han-Young
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.9 no.2
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    • pp.173-180
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    • 2005
  • Metakaolin is a cementitious material for producing high-strength concrete. This material is now used as substitute for silica-fume. In this paper, we did the mechanical and durability test such as compressive/tensile/flexural strength test, chloride ion diffusion, chemical attack and repeated freezing and thawing, carbonation test. In the mechanical tests, 10~15% for binder is optimum substitute rate. And, in the chloride ion diffusion test, according to the increase of substitute of metakaolin & silica-fume for binder, the diffusion coefficient was more reduced. In the chemical attack test, by the filler effect of fine powder such metakaolin and silica-fume, the resistance is more excellent than normal concrete. In the other durability test, the concrete using metakaolin also compared with those of silica-fume substitute concrete. Through these tests, we recognized that metakaolin can be used as a substitute for silica-fume.

Treatment of ASR from End-of-Life Vehicles by Air and Gravimetric Separation (廢自動車 ASR의 風力 및 比中選別에 의한 處理 硏究)

  • Lee, Hwa-Young;Oh, Jong-Kee
    • Resources Recycling
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    • v.14 no.2
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    • pp.3-9
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    • 2005
  • A study on the air and gravity separation has been performed for the removal of chlorine containing materials from ASR of end-of-life vehicles. The gravity separation was also conducted on waste plastics collected from ASR. In this work, ASR were previously shredded to pass through 8 mm sieve prior to separation tests and the gravity separation of waste plastics was conducted for three different particle sizes. The two-stage air classification was conducted with the range of air flow rate of 9~20 M$^3$/hr at first stage and 25~34 M$^3$/hr at second stage, respectively. The fraction of overflow product was remarkably increased in the 2nd stage air classification because of high air flow rate while that of underflow product obtained from 1st stage air classification was found to be 62~66%. From the results of gravity separation on waste plastics, it was also found that the amount of the float product was much greater than sink product. It is believed that the gravity separation may be used very efficiently for the removal of calorine bearing materials from waste plastics.

Damage Effects Modeling by Chlorine Leaks of Chemical Plants (화학공장의 염소 누출에 의한 피해 영향 모델링)

  • Jeong, Gyeong-Sam;Baik, Eun-Sun
    • Fire Science and Engineering
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    • v.32 no.3
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    • pp.76-87
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    • 2018
  • This study describes the damage effects modeling for a quantitative prediction about the hazardous distances from pressurized chlorine saturated liquid tank, which has two-phase leakage. The heavy gas, chlorine is an accidental substance that is used as a raw material and intermediate in chemical plants. Based on the evaluation method for damage prediction and accident effects assessment models, the operating conditions were set as the standard conditions to reveal the optimal variables on an accident due to the leakage of a liquid chlorine storage vessel. A model of the atmospheric diffusion model, ALOHA (V5.4.4) developed by USEPA and NOAA, which is used for a risk assessment of Off-site Risk Assessment (ORA), was used. The Yeosu National Industrial Complex is designated as a model site, which manufactures and handles large quantities of chemical substances. Weather-related variables and process variables for each scenario need to be modelled to derive the characteristics of leakage accidents. The estimated levels of concern (LOC) were calculated based on the Gaussian diffusion model. As a result of ALOHA modeling, the hazardous distance due to chlorine diffusion increased with increasing air temperature and the wind speed decreased and the atmospheric stability was stabilized.

A Study on Mineral Carbonation of Chlorine Bypass Dust with and without Water Washing (수세 유무에 따른 염소 바이패스 분진의 광물 탄산화 연구)

  • Hye-Jin Yu;Woo Sung Yum
    • Resources Recycling
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    • v.32 no.6
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    • pp.18-24
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    • 2023
  • This study undertook initial investigations into the carbonation of chlorine bypass dust, aiming to apply it as a raw material for cement and as an admixture for concrete. Various experimental methods, including XRD(X-ray diffraction), XRF(X-ray fluorescence), and particle size distribution analyses, were employed to verify the physical and chemical properties of chlorine bypass dust, with and without water washing. The mineral carbonation extent of chlorine bypass dust was examined by considering the dust type, stirring temperature, and experiment duration. Notably, a higher degree of mineral carbonation was observed in water-washed bypass dust than its non-water-washed counterpart, indicating an elevated calcium content in the former. Furthermore, an augmented stirring temperature positively impacted the initial stages of mineral carbonation. However, divergent outcomes were observed over time, contingent upon the specific characteristics of dust types under consideration.

Time-related Histopathologic Changes of Fresh Frozen Vascular Xenograft in Pig-to-goat Model (돼지-염소 모델에서 신선 동결된 이종 경동맥 이식편의 시간 경과에 따른 조직병리학적 변화)

  • Chang, Ji-Min;Kim, Won-Gon
    • Journal of Chest Surgery
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    • v.40 no.3 s.272
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    • pp.180-192
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    • 2007
  • Background: As determined from the recent investigations of discordant cardiac xenotransplantation, hyperacute rejection occurs mainly at the endothelial cells in donor microvascular systems, but this does not occur at cardiac valve leaflets or at medium-to-large caliber vessels. On the basis of this background, this study was performed to look into the biocompatibility for transplantation of a middle or large diameter xenogenic blood vessel by conducting xenogenic arterial transplantation with the carotid artery in a pig-to-goat model. Material and Method: The experimental group was composed of 10 pairs of pig-to-goat combinations. They were divided into each period of 1 week, and 1, 3, 6 and 12 months. Four carotid artery grafts obtained through collection of the bilateral carotid arteries from two pigs were preserved at $-70^{\circ}C$ without other treatment, and then they were transplanted into the bilateral carotid arteries of two goats. Doppler ultrasonography was done on a periodic basis after transplantation to evaluate the patency of the grafted blood vessel. At the ends of a predetermined period, the grafts were explanted from the goats and they underwent gross examination. Hematoxylin-eosin and Masson's trichrome staining were conducted. In addition, in order to examine the immunological rejection of the grafted xenogenic blood vessel, immunohistochemical staining was conducted with T-lymphocyte indicator and von Willebrand factor. Result: Two goats at the each one-week period and the one-year period died during the experimental period because of a reason unrelated to the experimental procedure, and the remaining 8 goats survived until the end of each experiment period. On Doppler ultrasonography, unilateral carotid artery occlusion was found in a goat, whose period was specified as 3 months, among the 8 survived goats. However, the vascular patency was maintained well and there was no graft that formed aneurysms in the other goats. On gross examination, the region of vascular anastomosis was preserved well, and calcification of the grafted blood vessel was not shown. Histologically, the endothelial cells of the graft disappeared one week after transplantation, and then there was progressive spread of the recipients' endothelial cells from the anastomotic site. The reendothelialization occurred over the whole graft at one month after transplantation. The neointimal thickening and adventitial inflammation became severe by 3 months after transplantation, but this lessened at 6 months and 12 months, respectively. The rate of CD3 positive cells was very low among the infiltrated inflammatory cells. Conclusion: The fresh-frozen xenogenic artery kept its patency without being greatly influenced by xenogenic immune reaction.

Effect of chloride ions on the catalytic properties of human pancreatic α-amylase isozyme produced in Pichia pastoris (Pichia pastoris에서 생산된 인체 췌장 α-아밀레이스 동질효소의 촉매활성에 대한 염소이온의 영향)

  • Kim, Min-Gyu;Kim, Young-Wan
    • Korean Journal of Food Science and Technology
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    • v.48 no.4
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    • pp.341-346
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    • 2016
  • The AMY2B gene, encoding human pancreatic ${\alpha}$-amylase isozyme (HPA II), was expressed in Pichia pastoris, and the effects of chloride ions on HPA II activity toward starch substrates were investigated. As seen with chloride ion-dependent ${\alpha}$-amylases-including HPA I, the isozyme of HPA II-chloride ions increased enzyme activity and shifted the optimal pH to an alkaline pH. The activity enhancement by chloride was more significant at pH 8 than that at pH 6, suggesting that the protonation state of the general acid/base catalyst of HPA II was important for the hydrolysis of starches at an alkaline pH because of the increase in its $pK_a$ by chloride ions. The turnover values for cereal starches as the substrates markedly increased in the presence of chloride by up to 7.2-fold, whereas that for soluble starch increased by only 1.7-fold. Chloride inhibited substrate hydrolysis at high substrate concentrations, with $K_i$ values ranging from 6 to 15 mg/mL.

Investigation on the Properties of Mortar Corresponding to a High Durability Admixture (고내구성 혼화재 첨가에 따른 모르타르의 특성 검토)

  • Kim, Jong-Baek;Bae, Jun-Yeong;Cho, Sung-Hyun;Woo, Seung-Min;Jun, Sung-Yong
    • Proceedings of the Korea Concrete Institute Conference
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    • 2009.05a
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    • pp.443-444
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    • 2009
  • This study investigated the development of high durability concrete under an oceanic region through the examination and comparison of the fundamental property and diffusion of chloride ion to apply a high durability admixture on the mortar.

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Ability to Resist Chloride Ion Penetration and Dry Shrinkage Evaluation of Magnesium Phosphate Ceramics (인산마그네슘 세라믹의 염소 이온 투과 저항성 및 길이변화 특성에 관한 성능 평가)

  • Ko, Jeong-Won;Yang, Wan-Hee;Park, Dong-Cheol
    • Journal of the Korea Institute of Building Construction
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    • v.17 no.4
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    • pp.341-348
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    • 2017
  • The performance degradation of concrete pavement by winter deicer is very serious in Korea, and its maintenance and rehabilitation brings a high expense. Therefore, a suitable method for rehabilitation of such concrete pavement and repair material of proper performance are required. In this study, the properties of compressive strength, ability to resist chloride ion penetration, and properties of dry shrinkage of magnesium phosphate ceramics were assessed to evaluate its applicability as a repair material for concrete pavement in Korea. As a result, the mortar flow showed a normal level of 190 mm, but the viscosity was high and the self-flow ability was poor. The setting time was 12 minutes, leading very rapid-hardening, and thus a prompt work was required. The compressive strength of mortar was 38.4MPa in 2 hours, 73.8MPa in 24 hours, and 111.0MPa in 28 days, showing a significant level. As a result of the test to chloride ion penetration resistance, mortar showed 143 Coulombs, and concrete showed 172.6 Coulombs, which fell under very low level. The drying shrinkage of MPC concrete in 40 days was below $60{\times}10-6$, and comparing with normal cement concrete, it showed the level below 1/10 of other concrete to secure an excellent volume stability. As above, magnesium phosphate ceramics has excellent strength performance, chloride ion penetration resistance, and volume stability, and this in the future shall be used in construction under the consideration of working time or workability, requiring further improvement for such performance.

A Study on the Strength Estimation Formular of the Precast Concrete Products Using the Chloride Ion Penetrating Test (염소이온투과시험을 이용한 콘크리트제품의 강도추정에 관한 연구)

  • 장문기;이정재
    • Proceedings of the Korean Society of Agricultural Engineers Conference
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    • 1998.10a
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    • pp.146-149
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    • 1998
  • In this study, the chloride ion penetration test and the compressive strength test should be done simultaneously on the standard cylinder specimen. And from analyzing the data from those tests, a strength estimation equation with high credibility is to be developed.

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