• Journal of the Korean Applied Science and Technology
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• v.29 no.2
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• pp.268-277
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• 2012

The thermal decomposition characteristic of waste PVC wires has been studied by using TGA and fixed-bed reactor. The experimental conditions of decomposition temperatures, air flow rates and weight ratio of CaO/PVC were considered in this work. To verify the effectiveness of CaO addition to remove HCl and toxic gases generated from thermal decomposition of PVC wire, the gaseous products obtained from the thermal decomposition of PVC were analyzed by GC/MS(Gas Chromatograph and Mass Spectrometry). To investigate the effect of CaO in thermal decomposition of PVC, liquid products were also analyzed by GC/MS. And the effect of decomposition temperature, air flow rate and CaO/ PVC weight ratio on the yield of liquid, gas and residue fraction have been also studied. From this work, it was found that the removal amount of HCl generated from thermal decomposition of PVC increased with increase of CaO addition.

• Journal of the Korean Geotechnical Society
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• v.23 no.6
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• pp.77-84
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• 2007

One of the most sensitive design specifications to be considered is infiltration and external pore-water pressures on underground structure construction. Development of pore-water pressure may accelerate leakage and consequently cause deterioration of the lining. In this paper, the development of pore-water pressure due to malfunctioning of drainage system and its potential effect on the linings are investigated using physical model tests. The deterioration procedure was simulated by controlling both permeability and flow rate. Development of pore-water pressure was monitored on the lining using pore pressure measurement cells. Test results identified the mechanism of pore-water pressure development on the tunnel lining. In addition, they showed that controlling flow rate is more effective method fur simulating deterioration procedure than permeability control. The laboratory model tests were reproduced using coupled numerical method, and showed that the effect of deterioration of drainage system can be theoretically expected using coupled numerical modeling method.

• Resources Recycling
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• v.22 no.2
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• pp.22-28
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• 2013

In the present study, the possibility of recovering and recycling the silicon carbide(SiC) from a silicon sludge by removing Fe and Si impurities was investigated. Si and SiC were separated from the silicon sludge using centrifugation. The separated SiC concentrate consisted of Fe, Si and SiC, in which Fe and Si were removed to recover the pure SiC. Leaching with acid/alkali solution was compared with the vapor-phase chlorination. The Fe concentration removed in the SiC was 49 ppm, and it was separated by leaching with 1 M HCl solution at $80^{\circ}C$ for 1 h. The Si concentration removed in the SiC was 860 ppm, and it was separated by leaching with 1M NaOH solution at $50^{\circ}C$ for 1 h. The SiC concentrate was chlorinated in a tubular reactor, 2.4 cm in diameter and 32 cm in length. The boat filled with SiC concentrate was located at the midpoint of the alumina tube, then, the chlorine and nitrogen gas mixture was introduced. The Fe and Si concentration removed in the SiC were 48 ppm and 405 ppm, respectively, at $500^{\circ}C$ reactor temperature, 4 h reaction time, 300 cc/min gas flow rate, and 10% $Cl_2$ gas mole fraction.

• Korean Journal of Environmental Agriculture
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• v.29 no.3
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• pp.273-281
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• 2010

Concentration of antibiotics including a tetracycline group (TCs) of tetracycline (TC), chlortetracycline (CTC), and oxytetracycline (OTC), a sulfonamide group (SAs) of sulfamethoxazole (SMX), sulfathiazole (STZ), and sulfamethazine (SMT), an ionophore group (IPs) of lasalocid (LSL), monensin (MNS), and salinomycin (SLM), and a macrolide group (MLs) of tylosin (TYL) was determined from samples collected from the agricultural soil, stream water, and sediment. For the agricultural soil samples, the concentration of TCs had the highest value among all tested antibiotic's groups due to its high accumulation rate on the surface soils. The lower concentrations of SAs in the agricultural soils may be resulted from its lower usage and lower distribution coefficient (Kd) compared to TCs. The concentration of TCs in stream water was significantly increased through June to September. It would be likely due to soil loss during an intensive rainfall event and a reduction of water level after the monsoon season. A significant amount of TCs in the sediment was also detected due to its accumulation from runoff, which occurred by complexation of divalent cations, ion exchange, and hydrogen bonding among humic acid molecules. To ensure environmental or human safety, continuous monitoring of antibiotics residues in surrounding ecosystems and systematic approach to the occurrence mechanism of antibiotic resistant bacteria are required.

• Proceedings of the Korea Water Resources Association Conference
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• 2015.05a
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• pp.46-46
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• 2015

강우가 지역별 계절별로 편중되어 있는 우리나라는 수자원의 안정적인 확보와 이용을 위해 다양한 형태의 댐을 건설하여 운영하고 있다. 그러나 대부분의 댐건설을 통해 형성된 저수지들은 탁수 장기화 및 녹조 발생 등의 환경, 생태적인 문제를 겪고 있으며, 그에 따른 사회적 우려로 인해 신규댐 건설을 통한 수자원확보는 더 이상 어려운 실정이다. 이러한 문제에 대응하기 위한 대안으로 기존 댐 저수지들(안동호-임하호)의 구조적 연계운영방안이 진행되고 있다. 본 연구의 목적은 2차원 CE-QUAL-W2모형을 활용하여 안동호와 임하호의 구조적 연결에 따른 탁수의 이동과 각 저수지 내에서의 유동 변화를 해석하는데 있다. 저수지 연계 시나리오는 EL. 138 m 위치에 길이 2 km, 직경 5.5 m 의 콘크리트관(마찰계수 0.05)이 안동호 좌안인 임동면 마리와 임하호 우안 망천리를 연결하는 것으로 가정하였다. 모델의 보정은 실측자료가 풍부한 2006년도 수문사상을 대상으로, 개별 저수지에 대해 수행하였고, 탁수 유동 시나리오 해석은 임하호에 심각한 탁수장기화 문제가 발생했던 2002년을 대상으로 댐 연계 탁수모의를 수행하였다. 안동호와 임하호의 댐 앞에서 모의값과 실측값을 오차를 분석한 결과 탁수예측오차는 AME 0.5~24 mg/L, RMSE 0.7~30.2mg/L의 범위로 비교적 실측값을 잘 반영한 것으로 나타났다. 임하댐의 경우 탁수층의 위치와 두께, 그리고 최고 탁도값을 적절히 재현 하였지만, 안동댐은 최고 탁도값 예측에서 다소 오차가 발생하는 것으로 나타났다. 안동호와 임하호 단독 운영시와 연계 운영시의 탁수변화 파악을 위해 초기 홍수사상이 발생한 8월 이후부터 저수지내의 TSS농도 분포를 비교하였다. 안동호의 경우 댐앞지점의 탁수분포는 수온성층구조에 영향을 받아, 단독 운영시(EL. 130 m)보다 연계운영시(EL. 140 m)에 탁수의 중심이 높은 위치에 형성되었다. 단독 운영시 10월 이후에 전도현상으로 인해 침강되지 않은 잔류 탁수층이 저수지 하부로 확산되었지만, 연계 운영시에는 재부상 되어 상층으로 확산되는 것으로 모의되었다. 또한 연계운영시 유량이동으로 인해 안동호의 탁수 댐앞 도달시간이 짧아지는 것으로 나타났다. 반면 임하호는 연계 운영시 안동댐으로 유출이 생기면서 중층에서 탁수량이 저감되는 것으로 모의되었다. 저수지 내 탁수량 분석을 위해 SS 15 mg/L 이상의 잔류 탁수량을 분석한 결과, 연계운영시 안동호의 평균 잔류탁수량 비율은 11.8% 증가, 임하호의 경우 11.7% 감소하였다. 또한, 탁수의 댐하류 방류일수도 SS 15 mg/L 기준 임하호 9일 저감, 안동호는 70일 증가하여 임하호의 탁수가 안동호의 탁수 장기화에 영향을 주는 것으로 나타났다.

• Proceedings of the Korea Water Resources Association Conference
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• 2009.05a
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• pp.250-254
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• 2009

상수관망의 기능은 정수처리 된 양질의 물을 수용가에게 안전하게 공급하는 것이며, 이를 위해 상수관내에는 수용가에 충분한 양의 물을 공급할 수 있는 적정 유량과 압력이 유지되어야하고 최소기준치 이상의 잔류염소농도 유지 등의 적절한 수질을 만족시켜야한다. 하지만 상수관망은 상수관 파괴에 따른 오염물질 유입이나 테러와 같은 인위적인 오염물 주입 등의 갑작스런 사고에 의한 수질오염에 언제나 노출되어 있다. 이러한 수질오염사고 발생 시 신속한 대처를 위해서는 상수관망의 모든 절점에 수질측정 센서를 설치하는 것이 바람직하겠지만, 이는 경제적 측면과 센서의 유지 관리측면에서는 이상적이지 않다. 또한 발생 가능한 모든 상황에 대한 시뮬레이션 기반의 수질모델링을 통하여 적절한 수질오염 측정지점을 선정할 수도 있겠지만, 이는 상당한 시간과 계산능력을 요한다. 따라서 본 연구에서는 네트워크 분석기법 (Network Analysis)인 Betweenness Centrality와 수리해석 모형인 EPANET을 이용하여 상수관망의 수질오염측정지점 선정기법을 제안하였다. Betweenness Centrality는 네트워크를 구성하는 한 절점과 다른 한 절점을 연결시키는 특정 절점의 매개정도로 중심성을 측정하는 기법이다. Betweenness Centrality는 상수관망의 특정절점에 수질오염 사고가 발생하였을 때 오염원의 이동 가능한 경로의 수에 따라 그 값이 달라지며, 결과값에 의하여 수질오염측정지점이 선정된다. 본 연구에 의한 결과는 상수관망이 복잡하여 시뮬레이션을 통한 분석이 어렵고 많은 시간과 계산능력이 요구 될 경우 대안기법으로 활용될 수 있을 것으로 판단된다.

• Proceedings of the Materials Research Society of Korea Conference
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• 2011.05a
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• pp.36.1-36.1
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• 2011

1차원 양자 구속 효과로 인해 우수한 전하 전송 특성을 갖는 나노선을 차세대 전자소자에 응용하기 위한 일환으로, 실리콘 기판 상에 동일한 실리콘 나노선을 성장하고 이의 미세구조 특징을 분석하였다. 실리콘 나노선은 Au 시드층을 형성한 후 화학기상증착법을 이용한 VLS (vapor-liquid-solid) 공법으로 성장시켰으며, 시드층의 크기에 따른 나노선의 구조 특성을 이미지 프로세싱을 통해 통계분석하였다. 성장된 실리콘 나노선의 결정구조와 성분을 고해상도 투과전자현미경과 EDAX를 이용하여 분석하였으며, 성장 온도 조건에 따른 나노선의 morphology 특성도 실시하였다. 그 결과 Au 시드층의 성분이 나노선과 기판의 계면에서 상당 부분 잔류함과, 성장된 나노선에는 쌍정 결함(twin defect) 등의 결정구조 변화가 수반됨을 알 수 있었다. 또한 금속 시드층의 평균 입도와 성장 온도 및 소스 가스 유량 조절함으로써 실리콘 나노선의 직경과 길이를 최적화 할 수 있었다. 이를 통해 향후 공정 스케일 다운의 한계 상황에 도달하고 있는 반도체 트랜지스터 소자를 대체할 수 있는 나노선 반도체 소자에 대한 공정기술 개발과 이를 이용한 다양한 응용 분야도 동시에 제시할 수 있게 되었다.

• Proceedings of the KIEE Conference
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• 2005.10b
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• pp.279-282
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• 2005

A real-time measurement and control system was developed, This system is used for nurses at hospitals to check the residual quantity and changing time of Ringer's solution in nurses' room. Load Cell is utilized as a sensor to check the residual quantity of Ringer's solution, This Load Cell detects the physical changes of Ringer's solution and transfers electronic signal to the amplifier. Amplified analog signal is converted into digital signal by NO converter. Developed Embedded system, which computes these data with microprocess(8052) then makes it possible to monitor the residual quantity of Ringer's solution real-time on a server computer. A Checking system on Residual Quantity of Ringer's Solution Using Load cell cut costs using a simple design for a circuit

• Korean Journal of Agricultural Science
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• v.2 no.1
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• pp.199-231
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• 1975

It is well known fact that antibiotic residues in milk of cows create significant problem for the fermented dairy industry and public health because of inhibition of starter activity and of creation of allergic disease. It can be assumed that antibiotic residues in milk of other aniimals also can create some problems for their infants as in the case of humen. For the above mentioned reasons, present studies were undertaken to determine concentration and duration of antibiotic residues in milk of cows, goats and dogs following intramuscular or intravenous injection and intramammary infusion of penicillin, streptomycin and oxytetracycline at usual dosage. The cylinder-plate method was used for their assay. The results obtained were summerized as follows: 1) Following the intramuscular injection of penicillin, the antibiotic was detected in milk of cows up to 72 hours, in milk of goats 48 hours and in milk of dogs 60 hours of postinjection. The mean peak concentrations were recorded at 12 hours as 0.136 I.U./ml in cows. 6 hours as 0.773 I.U./ml in goats and 3 hours as 1.192 I.U./ml in dogs. 2) Following the intramuscular injection of streptomycin, the antibiotic was detected in milk of cows and goats up to 36 hours and in milk of dogs 24 hours of post-injection. The mean peak concentration were recorded at 6 hours as $0.26{\mu}g/ml$ in cows and at 3 hours in goats and dogs $0.45{\mu}g/ml$ and $0.36{\mu}g/ml$ respectively. 3) Following the intra venous injection of oxytetracycline, the antibiotic was detectable in milk of all the test animals up to 48 hours of postinjection. The mean peak concentrations were recorded at 6 hours as $3.5{\mu}g/ml$ in cows $2.4{\mu}g/ml$ in goats and $2.0{\mu}g/ml$ in dogs respectively. 4) Following intrarnammary infusion of penicillin in amounts of 100,000 I.U. for cows, 20.000 I.U. for goats and 10,000 I.U. for dogs, the penicillin residues in milk of the infused quarter perssisted to 72 hours in cows and 84 hours in goats and dogs. 5) Following intramammary infusion of streptomycin in amount of 500mg for cows, 100mg for goats and 25mg for dogs, the streptomycin residues in milk of the infused quarter persisted to 72 hours in cows and goats and 60 hours in dogs. 6) Following intramammary infusion of oxytetracycline in amount of 500mg for cows, 100mg for goats and 25mg for dogs, the oxytetracycline residues in milk of the infused quarter persisted to 72 hours in cows and 60 hours in goats and dogs. 7) A corelation between the residual antibiotic concentration and milk yield in cows and goats was observed; That is, the lower in the milk production showed a higher the concentration of an antibiotic residues and a longer the time in persistance. 8) Intramammary transfer of the antibiotic from an infused to non infused quarters, in dogs, was observed following the intramammary infusion of penicillin. streptomycin and oxytetracyclne in amounts of 10.000 I.U. 25mg and 25mg respectively. However, no transfer by 100.000 I.U. or 20.000 I.U. of penicillin. 500mg of streptomycin and 100mg of oxytetracyline was observed in cows and goats. 9) In dogs, minimum dosage of antibiotics for transfer fro in treated to untreated quarters following intramammary infusion were 2,500 I.U. of penicillin and 5mg each of streptomycin and oxytetracycline.

• Journal of Korean Society of Environmental Engineers
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• v.32 no.10
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• pp.916-927
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• 2010

In general water treatment process, the disinfection process by chlorine is used to prevent water borne disease and microbial regrowth in water distribution system. Because chlorines were reacted with organic matter, carcinogens such as disinfection by-products (DBPs) were produced in drinking water. Therefore, a suitable injection of chlorine is need to decrease DBPs. Rechlorination in water pipelines or reservoirs are recently increased to secure the residual chlorine in the end of water pipelines. EPANET 2.0 developed by the U.S. Environmental Protection Agency (EPA) is used to compute the optimal chlorine injection in water treatment plant and to predict the dosage of rechlorination into water distribution system. The bulk decay constant ($k_{bulk}$) was drawn by bottle test and the wall decay constant ($k_{wall}$) was derived from using systermatic analysis method for water quality modeling in target region. In order to predict water quality based on hydraulic analysis model, residual chlorine concentration was forecasted in water distribution system. The formation of DBPs such as trihalomethanes (THMs) was verified with chlorine dosage in lab-scale test. The bulk decay constant ($k_{bulk}$) was rapidly decreased with increasing temperature in the early time. In the case of 25 degrees celsius, the bulk decay constant ($k_{bulk}$) decreased over half after 25 hours later. In this study, there were able to calculate about optimal rechlorine dosage and select on profitable sites in the network map.