• Title/Summary/Keyword: 자유 에너지

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Effect of Acid-Base Characteristics of Carbon Black Surfaces on Mechanical Behaviors of EPDM Matrix Composites (카본블랙 표면의 산-염기 특성변화가 카본블랙/EPDM 복합재료의 기계적 특성에 미치는 영향)

  • Park Soo-Jin;Kang Jin-Young;Hong Sung-Kwon
    • Polymer(Korea)
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    • v.29 no.2
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    • pp.151-155
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    • 2005
  • The effect of acid-base treatments of carbon blacks (CBs) was investigated in the mechanical properties of CBs/rubber composites. The surface characteristics of the CBs were determined by the pH, acid-base values, and surface energetics. Their mechanical properties of the composites were also evaluated by the crosslink density $(V_e)$ and tearing energy (T). As an experimental result, acidically treated CBs led to the increase of the specific component $({\gamma}s^{sp})$, resulting in decreasing the mechanical properties of the composites. However, basically treated CBs showed a higher value of the dispersive component $({\gamma}s^L)$ than that of the untreated or acidically treated CBs. It was also found that the interaction of the CBs-rubber was improved, resulting in the improvement of the crosslink density and mechanical properties of the composites. It was then remarked that the acid-base characteristics of the CB surfaces made an important role in improving the physical properties of the rubber matrix composites.

Dynamic Characteristics and Piezoelectric Effect of Energy Harvesting Block Structures with Different Shapes (다양한 형상 변화에 따른 에너지 수확용 블록 구조의 동적 특성 및 압전 효과)

  • Noh, Myung-Hyun;Lee, Sang-Youl
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.32 no.6A
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    • pp.379-387
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    • 2012
  • This study investigates free vibration characteristics of new energy harvesting multi-layer block structures with different geometrical shapes using solid and shell finite elements and evaluate their piezoelectric effect on experiments. The two and three-dimensional finite element (FE) delamination models for block structures described in this paper is attractive not only because it shows excellent accuracy in analysis but also it shows the entire vibration mode shape. The FE model using ABAQUS is used for studying free vibrations of multi-layer block structures for various tip mass and PZT. In particular, new results reported in this paper are focused on the significant effects of the global and local vibration modes for various parameters, such as size of block shape, existence of tip mass and hole, and location of tip mass and PZT. In addition, we evaluate the power generation capacity of developed energy block structures through a laboratory-scale experiment.

Prediction of Fatigue Life in 2 Ply Rubber/Cord Laminate (2층 고무/코드 적층판의 피로 수명 예측)

  • 임동진;이윤기;윤희석;김민호
    • Composites Research
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    • v.16 no.3
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    • pp.9-17
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    • 2003
  • In order to simulate the crack connection between cords and the interply crack growth in the belt-layer of real tire, 2 ply rubber/cord laminate specimens with exposed edges were tested in 4~11mm displacement control. Measurement of the crack connection is evaluated when crack reaches the half of the length between 45$^{\circ}$ aligned cords, and the amount of the crack growth is measured by the steel probe method. 2 dimensional analytic modeling was performed to simulate the crack connection between cords at the exposed edges. Also, the theoretical life of the specimens was calculated from the crack connection life between cords(critical value) and from the critical value to the final failure by the use of Tearing energy(T); the strain energy release per unit area of one fracture surface of a crack. Then, theoretical life was compared with those of experiments. The life prediction up to the critical value has about 20% error compared to experimental life, and up to the final failure about 65% error. Therefore, total theoretical life has about 45% error compared to the experimental life, which is conceivable in the case of rubber.

Transition of Turbulent Kinetic Energy Through a Serial Unit of Straight-Duct, Contraction and Free-Jet (상류유동전개부, 수축부 및 자유분사류로 이어지는 유동장에서의 난류에너지 천이에 대한 연구)

  • 한용운;남경덕
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.16 no.12
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    • pp.2368-2375
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    • 1992
  • The transition of turbulent kinetic energy(TKE) balance along the centerline of the flow unit, which is composed of straight-duct, contraction and free-jet, has been investigated by the hot-wire anemometry. It is found that the mean turbulent kinetic energy is balanced by the dissipation in the internal flow region ; by the production and the dissipation, through contraction ; and by the dissipation, in initial region(X〈8D) of free-jet. But in the developing region (8D〈X〈20D) it is balanced by all of the three(ie, diffusion, production and dissipation). Finally, in the downstream of free-jet, the mean TKE is balanced again by dissipation like as the beginning. The decay-laws along the centerline are checked in the region of free jet as well as in the straightduct. After the developing region of free-jet also exist the decay-laws, the exponent of the axial turbulence being bigger than of the radial.

Evaluation of Free-Edge Delamination in Composite Laminates (복합재 적층판의 자유단 층간분리의 평가)

  • 김인권;공창덕;방조혁
    • Composites Research
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    • v.14 no.1
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    • pp.8-14
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    • 2001
  • A simplified method for determining the three mode(I, II, III) components of the strain energy release rate of free-edge delaminations in composite laminates is proposed. The interlaminar stresses are evaluated using the interface moment and the interface shear forces which are obtained from the equilibrium equations at the interface between the adjacent layers. Deformation of an edge-delaminated laminate is analysed by using a generalized quasi-three dimensional classical laminated plate theory. The analysis provides closed-form expression for the three components of the strain energy release rate. The analyses are performed for composite laminates subjected to uniaxial tension, with free-edge delaminations located symmetrically and asymmetrically with respect to the laminate midplane. The analysis results agreed with a finite element solution using the virtual crack closure technique.

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Free Vibration Analysis of Arbitrarily Shaped Plates with Free Edges Using Non-dimensional Dynamic Influence Functions: the case that straight and curved boundaries are mixed (무차원 동영향 함수를 이용한 자유단 경계를 가진 임의 형상 평판의 진동해석 : 직선 및 곡선 경계가 혼합된 경우)

  • Choi, Jang-Hoon;Kang, Sang-Wook
    • 한국신재생에너지학회:학술대회논문집
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    • 2005.06a
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    • pp.534-537
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    • 2005
  • Free Vibration Analysis using Non-dimensional Dynamic Influence Function (NDIF) is extended to arbitrarily shaped plates including polygonal plates. Since the corners of polygonal plates have indefinite normal directions and additional boundary conditions related to a twisting moment at a corner along with moment and shear force zero conditions, it is not easy to apply the NDIF method to polygonal plates wi th the free boundary condition. Moreover, owing to the fact that the local polar coordinate system, which has been introduced for free plates with smoothly varying edges, cannot be employed for the straight edges of the polygonal plates, a new coordinate system is required for the polygonal plates. These problems are solved by developing the new method of modifying a corner into a circular arc and setting the normal direction at the corner to an average value of normal direct ions of two edges adjacent to the corner. Some case studies for plates with various shapes show that the proposed method gives credible natural frequencies and mode shapes for various polygons that agree well with those by an exact method or FEM (ANSYS).

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Study on the Free Surface Behavior Using the Lattice Boltzmann Method (격자볼츠만법을 이용한 자유수면 거동 특성 연구)

  • Jung, Rho-Taek
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.16 no.4
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    • pp.255-262
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    • 2013
  • The boltzmann equation is based on the particle distribution function while the Navire-Stokes equation based on the continuum theory. In order to simulate free surface flow, this paper used the Lattice Boltzmann Method of which is the discretized form. The detail study on the characteristics of the Lattice Boltzmann Method for the free surface simulation was investigated. The developed code was validated with the traditional dam breaking problem by tracking the front position of the water. A basic roles of density functions in the Lattice Boltzmann Method is discussed. To have an engineering applications, the simulation is also conducted the free surface behavior with an arbitrary wall geometry.

Ablation characteristics of femtosecond laser pulse-induced pressure waves in biological tissue (펨토초 펄스로 인한 조직 제거시 생성된 압력파의 특성 연구)

  • ;A. Komashko;M. Feit;A. Rubenchik
    • Proceedings of the Optical Society of Korea Conference
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    • 2002.07a
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    • pp.244-245
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    • 2002
  • 1 picosecond 보다 짧은 펄스길이를 갖는 초단파길이 레이저 펄스 (Ultrashort laser pulse, USLP)를 이용한 물질의 절제 (ablation)는 여타 nanosecond 영역의 레이저 절제와 많은 차이를 보인다(1). USLP는 순간 파워가 매우 높기 때문에 직접적으로 물질의 원자를 분리시켜 자유전자를 형성한다 이들 자유전자는 일반 선형흡수체 (linear absorbing chromophore)보다 흡수계수가 몇 십 배로 높아 대부분의 펄스 에너지가 표면 100-200 m 이내의 극히 작은 지역에 밀집되게 된다. (중략)

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전방향 이동로봇의 에너지효율 개선을 위한 제어방법

  • 김정근;송재복
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2004.05a
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    • pp.23-23
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    • 2004
  • 이동로봇의 독립성과 움직임에 자유도를 높이기 위해서 축전지를 이동로봇에 탑재하고, 이를 이용하여 동력을 공급하는 경우가 대부분이다 이러한 경우에 에너지 효율은 제한된 동력을 가지는 시스템의 가동 가능시간을 결정하는 중요한 성능지수가 된다. 또한, 이동로봇의 최대속도나 최대가속도, 등판각도 등의 설계 사양을 소형의 모터를 사용하여 만족시키는 것은 이동로봇의 소형화, 경량화 및 시스템의 가격을 낮추기 위해 필수적이다. 그러나 이동로봇의 최대의 문제점 중의 하나인 소비전력의 감소에 대한 문제는 활발히 연구되고 있지 않다.(중략)

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결정 구조가 PtFe 산소 발생 반응 전기 화학적 촉매에 미치는 영향

  • Jeong, Won-Seok
    • Proceeding of EDISON Challenge
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    • 2015.03a
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    • pp.308-311
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    • 2015
  • https://nano.edison.re.kr/에서 제공하는 Linear Combination of Atomic Orbitals 기반 Density Functional Theory 전자구조계산 SW을 이용하여 정렬된 FCC 결정구조의 PtFe와 원자의 배열이 무질서한 PtFe의 산소 발생 반응의 과전압을 알아보았다. 화학 반응에 참여하는 정렬된 FCC PtFe의 표면 방위는 표면 에너지 계산을 통해 (111) 면으로 설정하였다. 과전압 값은 산소 발생 반응의 각 단계의 자유 에너지 변화를 계산하여 양의 반응 에너지이다. 과전압 측정 결과 정렬된 FCC 결정구조의 PtFe와 원자의 배열이 무질서한 PtFe의 과전압은 각 각 0.623875eV, 0.603118eV 이다.

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