• Title/Summary/Keyword: 자외선 산화

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On the Oxidation of Rice Lipid Fractions Extracted from the Whole Grain by Immersion (용매침지(溶媒浸漬)에 의하여 추출(抽出)된 쌀알의 유지획분(油脂劃分)의 산화(酸化)에 대(對)하여)

  • Cheigh, Hong-Sik;Kwon, Tai-Wan
    • Korean Journal of Food Science and Technology
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    • v.4 no.3
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    • pp.206-212
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    • 1972
  • Oxidative changes in the rice lipids under accelerated condition were studied by measuring the changes in weight gain, total carbonyl compound, malonaldehyde, and fatty acid composition. Rice lipids were prepared by extraction with either n-hexane or ethanol from polished rice grain and purified by Folch's method. The lipid preparations were either incubated in dark at $40^{\circ}C$ or irradiated with ultra-violet light for a period of 55 days. Weight gain by oxygen absorbed sharply increased within 3 days in the rice lipids under UV light irradiation. However, with the rice lipids at $40^{\circ}C$ incubation a moderate increase in weight was observed only after 45 days storage. Their induction periods were one day (hexane extracted, under UV light), 2 days (ethanol extracted, under UV light), 30 days (hexane extracted, at $40^{\circ}C$), and 40 days (ethanol extracted, at $40^{\circ}C$) respectively. Oxidative rancid odor appeared at the end of the induction period. Total carbonyl compound and malonaldehyde markedly increased within 7 days, and decreased in the rice lipids under ultra violet light irradiation, while at $40^{\circ}C$ incubation they were continued to increase slowly through out the storage. The hexane extracted lipid were less stable than ethanol extracted lipid on the basis of oxygen absorption, malonaldehyde and other carbonyl compound formation. With the hexane extracted lipid during 55 days incubation at $40^{\circ}C$, the contents of linoleic and linolenic acids decreased, while the oleic, stearic, and palmitic acids increased.

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Role of Coelomocytes in Stress Response and Fertility in Caenorhabditis elegans (꼬마선충의 coelomocyte 세포가 스트레스 저항성 및 번식력에 미치는 영향)

  • Park, Jin-Kook;Hwang, Jin-Kyu;Song, Keon-Hyoung;Park, Sang-Kyu
    • Journal of Life Science
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    • v.25 no.3
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    • pp.263-268
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    • 2015
  • Coelomocytes are specialized cells that continually and nonspecifically scavenge fluid from the body cavity through endocytosis in Caenorhabditis elegans. Our previous study revealed that coelmocytes were specifically required for dietary-restriction-induced longevity in C. elegans. In the present study, we examined the effect of coelomocyte ablation on the response to environmental stressors and reproduction in C. elegans. Coelomocytes were ablated using diphtheria toxin specifically expressed in coelomocytes. After exposing worms to 20 J/cm2/min of ultraviolet irradiation in vivo, the survival of the worms was monitored daily. To examine their response to heat stress, their survival after 10 h of 35℃ heat shock was measured. Oxidative stress was induced using paraquat, and the susceptibility to oxidative stress was compared between wild-type control and coelomocyte-ablated worms. The total number of progeny produced was counted, and the time-course distribution of the progeny was determined. The worms with ablated coelomocytes showed reduced resistance to ultraviolet irradiation, but the ablation of coelomocytes had no effect on their response to heat or oxidative stress. The number of progeny produced during the gravid period was significantly decreased in the coelomocyte-ablated worms. These findings suggest that coelomocytes specifically modulate the response to ultraviolet irradiation and are required for normal reproduction in C. elegans. The findings could contribute to understanding of the mechanisms underlying dietary-restriction-induced longevity.

Present Trend and Prospect of Catalyst Technology at Room Temperature for Controlling Indoor Air Quality (IAQ) (실내대기오염물질 제어를 위한 상온산화 촉매 기술의 동향과 전망)

  • Lee, Sang-Hyun;Kim, Sung Su
    • Prospectives of Industrial Chemistry
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    • v.19 no.5
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    • pp.1-11
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    • 2016
  • 우리나라는 1970년대를 기점으로 하여 급격한 경제성장과 산업기술의 발전이 이루어졌다. 경제성장과 함께 주택의 보급 또한 급격하게 증가하게 되었고, 주택의 보급을 위한 건축자재 및 생활용품의 개발이 급속도로 이루어졌다. 이에 따라 실내에서 사용하는 기구 및 건축재료가 매우 다양해졌으며, 이로 인한 새로운 오염물질의 배출이 급격히 증가하게 되었다. 최근 새로운 기술로 소개되고 있는 촉매 산화법의 경우 제거하려는 대상 실내대기오염물질을 촉매를 이용하여 CO2나 H2O 등으로 산화시켜 제거하는 방법이며, 최근 많은 연구가 활발하게 수행되고 있다. 촉매를 이용하는 촉매 산화법은 광촉매 산화법과, 촉매의 성능만을 이용하여 대상물질을 산화하는 촉매산화법으로 구분된다. 광촉매 산화법은 특정 파장에서 반응하는 촉매에 자외선을 조사하여 실내오염물질을 산화제거하는 방법으로, 산화성능이 우수하여 여러 가지 실내오염가스에 적용되고 있으나, 별도의 광원이 필요하며, 포름알데히드 산화 시 CO2와 H2O 이외에도 dichloroacetyl chloride (C2HCl3O), trichloroethylene (C2HCl3), phosgene (COCl2) 등과 같은 부수적인 2차 유해물질이 발생함에 따라 이를 처리하기 위한 대책이 수반되어야 한다. 반면, 촉매 산화법의 경우 별도의 광원이나 에너지원 없이, 촉매를 이용하여 대기오염물질을 인체에 무해한 물질로 완전 산화시키는 방법으로써, 최근 많은 연구가 수행되어 상온에서 구동 가능한 촉매가 개발되었고, 이의 연구가 활발히 이루어지고 있다. 이에 상온산화촉매기술의 연구동향 및 사례를 확인하고, 향후 상온산화촉매기술이 나아가야 할 방향을 제시하고자 한다. 본 연구는 환경부 환경산업선진화기술개발사업의 지원을 받아 수행되었습니다(2016000140004).

Anti-aging Effects of Marine Natural Extracts against UVB-induced Damages in Human Skin Cells (UVB로 손상이 유도된 피부세포에 해양소재 추출물의 항노화 효능)

  • Lee, Chan;Jang, Jung-Hee;Kim, Bo-Ae;Park, Chan-Ik
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.38 no.3
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    • pp.255-261
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    • 2012
  • The skin is continuously exposed to environmental stresses. One of the most important stress factor is UV radiation. UV radiation causes a variety of biological effects on the skin, including inflammation, pigmentation, photoaging and cancer. Therefore in this study, we tried to search for skin-protective antioxidant materials from marine natural products (Porphyra Thalli, Laminariae japonicae thallus, Ostreae Concha, Sargassum Thallus, Undaria thallus, Haliotidis Concha, Agar, Codium thalli, Hizikia fusiforme thalli; HFE, Thalli) which exhibit protective activities against UVB-induced cytotoxicity and oxidative cell death and antiaging effects. As a results, UVB-induced cytotoxicity and cell death were effectively suppressed by treatment of Sargassum Thallus, Agar, Haliotidis Concha, Codium thalli, Thalli ethanol extracts. UVB-induced cell death was mediated by intracellular accumulation or ROS, which was significantly inhibited by treatment with marine natural products extracts. Also, The protective effect of these marine natural products seemed to be mediated by increased expression of type I collagen and Type I procollagen. These results suggest that marine natural products may have anti-aging effects new functional materials against oxidative stress-mediated skin damages.

Protective Effect of Marine Natural Products against UVB-induced Damages in Human Skin Fibroblast via Antioxidant Mechanism (자외선으로 유도된 섬유아세포 손상에 대한 해양소재 추출물의 항산화 보호효과)

  • Jang, Jung-Hee;Lee, Chan;Kim, Sang-Chan;Chung, Ji-Wook;Park, Chan-Ik
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.36 no.1
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    • pp.79-87
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    • 2010
  • Ultraviolet is the one of the main environmental factors promoting aging process via increased intracellular generation of reactive oxygen species (ROS) and decreased expression of endogenous antioxidant enzymes and molecules. Therefore, in this study, we tried to search for natural skin-protective antioxidant materials from marine origins (Porphyra Thalli, Laminariae japonicae thallus, Ostreae Concha, Sargassum Thallus, Undaria thallus, Haliotidis Concha, Codium thalli, Syngnathoides biaculeatus, Hippocampus, Stichopus Stichopus, Thalli, Hizikia fusiforme thalli) which exhibit free radical scavenging activity and protect against UVB-induced cytotoxicity and oxidative cell death. Free radical scavenging activity was shown in order of Undaria thallus. Sargassum Thallus, Laminariae japonicae thallus, Hippocampus, Haliotidis Concha, Ostreae Concha, Syngnathoides biacuJeatus. In another experiment, UVB-induced cytotoxicity and cell death were effectively suppressed by treatment of Sargassum Thallus, Haliotidis Concha, Codium thalli, or Hippocampus water extract. Furthermore, UVB-induced cell death was mediated by intracellular accumulation or ROS, which was significantly inhibited by treatment with aforementioned extracts. The protective effect of these marine natural products seemed to be mediated by increased expression of antioxidant enzymes such as catalase, superoxide dismutase, and heme oxygenase-1. These results suggest that Sargassum Thallus, Haliotidis Concha, Codium thalli, and Hippocampus may have preventive and protective potentials as new functional cosmetics against oxidative stress-mediated skin damages and aging with antioxidant properties.

A study on the characteristics of VOCs treatment using silent discharge and $TiO_2$ photocatalytic oxidation (Silent discharge 및 $TiO_2$ 광촉매산화반응을 이용한 VOCs 처리에 관한 연구)

  • 박석출;김찬훈;조정구;서정민;최금찬
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 1999.10a
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    • pp.457-458
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    • 1999
  • 산업현장에서 용매, 세정제로 다량 사용되고 있는 휘발성 유기화합물들은 함유하고 있는 유해한 독성 때문에 그 처리에 관심이 집중되고 있으며 이 중 촉매산화법은 1990년대 들어 새로운 VOCs처리기술로서 이산화티타늄과 같은 금속산화물의 광촉매를 사용하는 공정이 활발히 연구되고 있다. TiO$_2$를 광촉매로 이용한 광촉매산화법은 아주 작은 에너지로서 2차적인 부산물없이 VOCs를 완전히 분해시킬 수 있고 태양광의 자외선을 에너지원으로 이용할 수 있는 장점 때문에 장래의 경제적인 처리기술로서 각광을 받는 기술이다.(중략)

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Studies on Photosensitized Oxidation in the Lipids of Irish moss, Laver and Oyster (진두발, 김 및 굴의 지질에 있어서 광증감 산화에 관한 연구)

  • KIM Kui-Shik;KOIZUMI Chiaki;BAE Tae-Jin
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.30 no.3
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    • pp.355-360
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    • 1997
  • In order to investigate the influence of photosensitized oxidation in the sun-dried irish moss (Chondrus Ocellatus), laver (Porphyra Yezoensis) and ultra violet irradiated oyster (Crassostrea gigas) the oxidation of lipid and isomers of hydroperoxides were analyzed by gas chromatography-mass spectrometry. The lipid contents of oyster, irish moss and layer were $2.7\%,\;0.1\%,\;0.1\%$ of respectively. Peroxide value, 56,7 meq/kg in the raw oyster was increased of 100.9 meq/kg by the U.V, irradiation for 4 hours. Also the peroxide values of the irish moss and laver were increased by the sun-drying. In the identification of hydroperoxides isomers by trimethylsily (TMS) derivative of photo-oxidized lipid from oyster, irish moss and laver, the proportions of positional isomer, 9-OOH and 13-OOH were dominant than those 10-OOH and 12-OOH.

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Removal of microorganic pollutants based on reaction model of UV/chlorine process (자외선/염소 반응해석 모델에 의한 미량유기물질 제거에 관한 연구)

  • Hwang, Tae-Mun;Nam, Sookhyun;Kwon, Minhwan;Kang, Joon-Wun
    • Journal of Korean Society of Water and Wastewater
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    • v.31 no.1
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    • pp.73-81
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    • 2017
  • The UV/chlorine process is a UV-based advanced oxidation process for removing various organic pollutants in water. The process is becoming increasingly popular because of its effectiveness in practice. It is important to the safe and efficient operation of a UV/chlorine process that the optimal operating conditions for both target removal objective and saving energy are determined. Treatment efficiency of target compounds in UV/chlorine process was mainly affected by pH and scavenging factor. In this study, kinetic based mathematical model considering water characteristics and electrical energy dose calculations model was developed to predict of treatment efficiency and optimal operating conditions. The model equation was validated for the UV/chlorine process at the laboratory scale and in pilot tests at water treatment plants.

Analyses of Additives Applied in a Polycarbonate (폴리카보네이트에 사용된 첨가제의 분석)

  • Kim, Seog-Jun
    • Analytical Science and Technology
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    • v.13 no.3
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    • pp.282-290
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    • 2000
  • In this study, polymer additives were extracted and separated by Soxhlet extraction method and the dissolution-precipitation method from a polycarbonate (optical grade) which completely absorbed UV light below 390 nm. Analytical techniques such as UV-Vis spectroscopy, FT-IR, and HPLC were applied to analyze additives in polycarbonate. Separated materials from the polycarbonate may be a complex mixture containing additives such as UV stabilizer, antioxidants (primary and secondary), monomers, and oligomers. Several compounds such as bisphenol A, Irganox 1010, and Cyasorb UV-5411 were identified by chromatograms and UV spectra obtained from RP HPLC analysis using Bondapak $C_{18}$ column, methanol mobile phase, and a photodiode array (PDA) detector. Also, the content of UV-5411 in the polycarbonate was about 0.12 wt% by a quantitative analysis through UV spectroscopy.

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Improvement of Hysteresis Characteristics of Low Temperature Poly-Si TFTs (저온 Poly-Si TFT 소자의 Hysteresis 특성 개선)

  • Chung, Hoon-Ju;Cho, Bong-Rae;Kim, Byeong-Koo
    • The Journal of Korea Institute of Information, Electronics, and Communication Technology
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    • v.2 no.1
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    • pp.3-9
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    • 2009
  • Although Active matrix organic light emitting diode (AMOLED) display has a better image quality in terms of viewing angle, contrast ratio, and response time than liquid crystal displays (LCDs), it still has some critical issues such as lifetime, residual images, and brightness non-uniformity due to non-uniformity in electrical characteristics of driving TFTs and IR drops on supplied power line. Among them, we improved irrecoverable residual images of AMOLED displays which is mainly related to the hysteresis characteristics of driving TFTs. We consider four kinds of surface treatment conditions before gate oxide deposition for improving hysteresis characteristics. We can reduce the hysteresis level of p-channel TFT to 0.23 V, interface trap states between the poly-Si layer and gate insulator to $3.11{\times}10^{11}cm^{-2}$, and output current variation of p-channel TFT to 3.65 % through the surface treatment using ultraviolet light and H2 plasma. Therefore, the recoverable residual image problem of AMOLED displays can be improved by surface treatment using ultraviolet light and $H_2$ plasma.

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