• Journal of the Korea Academia-Industrial cooperation Society
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• v.14 no.9
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• pp.4178-4184
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• 2013

Nanoimprint lithography (NIL) is an emerging technology enabling cost-effective and high-throughput nanofabrication. Recently, the major trends of NIL are high throughput and large area patterning. UV curable type NIL (UV NIL) can be performed at room temperature and low pressure. And one advantage of UV NIL is that it does not need vacuum, which greatly simplifies tool construction, so that vacuum oprated high-precision stages and a large vacuum chamber are no longer needed. However, one key issue in non-vacuum environment is air bubble formation problem. Namely, can the air bubbles be completely removed from the resist. In this paper, the air bubbles formation by the method of droplet application in UV NIL with non-vacuum environment are experimentally studied. The effects of the volume of droplet and the number of dispensing points on air bubble formation are investigated.

• Journal of Adhesion and Interface
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• v.20 no.1
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• pp.15-22
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• 2019

In this study, polybutadiene based di-functional urethane acrylate oligomer (PB-UAO) were synthesized from polybutadiene diol and isophorone diisocyanate. And then, pressure sensitive adhesive films were prepared by mixing with synthesized oligomer, tri-functional acrylate monomer (Tris(2-acryloyloxyethyl) isocyanurate (TAOEIC) or Trimethylolpropane triacrylate (TMPTA) or Pentaerythritol triacrylate (PETA)), mono-functional acrylate monomer (Stearyl acrylate) and UV initiators. Effects of types and contents of trifunctional acrylate monomers on peel strength, tensile strength, elongation, thermal stability and water absorption property were studied. As the contents of tri-functional acrylate monomer increased, and as the molecular weight of tri-functional acrylate monomer decreased, peel strength, elongation and water absorption showed a tendency to decrease whereas tensile strength and thermal stability showed a tendency to increase.

• Polymer(Korea)
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• v.35 no.2
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• pp.183-188
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• 2011

Pentaerytritol triacrylate (PETA) was synthesized by a condensation reaction between pentaerytritol and acrylic acid. The highest yield of PETA was obtained when heptane was used as a solvent under the 1:4 mole ratio of pentaerytritol and acrylic acid. The 6-functional urethane acrylates(UA) were also synthesized by a condensation reaction between PETA and diisocyanate. Cured films were prepared from the mixtures of UA oligomer, reactive diluents and UV initiator to investigate their physical properties. The thermal stability of the aliphatic urethane acrylate was better than that of the aromatic urethane acrylate. The UA-2 showed good hardness and scratch resistance properties while the UA-l with a high degree of curing density exhibited a better chemical resistance. All the UA oligomers showed fairly good adhesion strengths but the other physical properties of UA-3 were poor due to its low curing density.

• Proceedings of the Korean Vacuum Society Conference
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• 2014.02a
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• pp.331-331
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• 2014

3족 질화물에 기반한 발광다이오드는 비소화물이나 인화물에 비해 여러 가지 장점을 가져 각광받아왔다. 특히, (Al)GaN 에 기반한 자외선 영역 발광 다이오드는 자외선 경화, 소독 등의 여러 가지 응용 가능성을 가진다 [1]. 하지만, 심자외선 영역으로 갈수록 높은 접촉 저항과 투명전극에서의 광흡수에 의해 전류주입 효율과 광추출 효율이 감소하여 결국 외부양자 효율이 더욱 열화되는 특성을 보인다. 이는 넓은 밴드갭을 가지는 물질을 이용하여 p-(Al)GaN 층에서 오믹접촉을 이루어야만 해결이 가능하지만 아직까지 이러한 결과가 보고된 바 없다. 본 연구에서는, 우리는 넓은 밴드갭을 가지는 silicon dioxide (SiO2) 에 전기장을 인가하여 p-GaN, and p-AlGaN 층에 전도성 필라멘트를 형성하여 전기전도도를 부여하는 연구를 진행하였다. p-GaN 과 p-AlGaN 위에서 5 nm 두께의 SiO2는 schottky 한 특성과 280 nm의 파장대역에서 약 97%의 투과율을 보였다. 비록 schottky 장벽이 형성되었지만, 전기전도도가 크게 향상되었으며 심자외선 영역에서 매우 낮은 흡수율을 보였다. 이는 기존의 증착후 열처리를 거쳐 제조된 전극에 비하여 우수한 특성을 지니며 향후 심자외선 영역 발광다이오드의 p-(Al)GaN 층 위에 오믹접촉을 이룰수 있는 가능성을 제시한다.

• Journal of the Korean Electrochemical Society
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• v.16 no.2
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• pp.91-97
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• 2013

Solid polymer electrolyte films are prepared by ultraviolet radiation in the mixtures of an ionic liquid salt (1-ethyl-3-methylimidazolium tetrafluoroborate, $EMIBF_4$) and solvent (acetonitrile (ACN) or propylene carbonate(PC)), and an oligomer (poly(ethylene glycol)diacrylate, PEGDA, 45-60 wt.%). Electrochemical properties of activated carbon supercapacitors adopting the solid polymer electrolyte films as a separator are also examined by cyclic voltammetry and impedance measurement techniques. As a result, the supercapacitor adopting the PEGDA as much as 45 wt.% exhibits a superior capacitance of $46Fg^{-1}$ at $20mVs^{-1}$. It seems that this is due to fast kinetics of ion conduction by sufficient film flexibility, which can be allowed by comparatively weak ultraviolet curing of small anount of the PEGDA.

• International Journal of Highway Engineering
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• v.11 no.3
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• pp.23-32
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• 2009

In this paper an experimental program was launched to determine the mechanical and durability properties of spall repair materials (RCC: 3 items, PCC: 2 items, PC: 3 items). Test items were mechanical property tests such as setting times, strengths, modulus of elasticity, plastic shrinkage, and durability tests such as dynamic modulus ratio, bond property with freeze-thaw, water absorption, chemical resistance, ultraviolet exposure. Modulus of the PC products exhibits ductile while the modulus is in the order of RCC > PCC > PC. At early ages the PC products experience higher plastic shrinkage than others, henceforth stable at 28 days. Other test results such as dynamic modulus ratio, absorption, and chemical resistance show that the PCs are superior to the PCCs and the RCCs. Except for PC-2, all patch materials had bond strength more than 1.3MPa after freeze-thaw cycles of 200~300 while the PCs and the PCCs seem to be better than the RCCs. With 500 hours of ultraviolet exposure, all patch materials showed to have no crack or deterioration at the surface.

• Journal of the Microelectronics and Packaging Society
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• v.24 no.2
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• pp.29-35
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• 2017

In this paper, we investigated a manufacturing process of metal micro-wire interconnection on submillimeter diameter catheter. Over the years, flexible electronic researches have focused on flexible plane polymer substrate and micro electrode manufacturing on its surface. However, a curved polymer substrate, such as catheter, is very important for medical application. Among many catheters, importance of submillimeter diameter steerable catheter is increasing to resolve the several limitations of neurosurgery. Steering actuators have been researched for realizing the steerable catheter, but there is no research about practical wiring for driving these actuators. Therefore we developed a new manufacturing process for metal micro-wire interconnection on submillimeter diameter catheter. We designed custom jigs for alignment of the metal micro-wires on the submillimeter diameter catheter. An UV curing system and commercial products were used to reduce the manufacturing time and cost; Au micro-wire, UV curable epoxy, UV lamp, and submillimeter diameter catheter. The assembled catheter was characterized by using an optical microscope, a resistance meter, and a universal testing machine.

• Applied Chemistry for Engineering
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• v.22 no.6
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• pp.610-616
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• 2011

A series of polyurethane acrylate/ZnO (PUA/ZnO) nanocomposite films with different ZnO contents were successfully prepared via a UV-curing system. The synthesis and physical properties including morphological structure, thermal properties, barrier properties and optical properties, and antimicrobial properties were investigated as a function of ZnO concentration. FTIR and SEM results showed that these PUA/ZnO nanocomposite films did not have a strong interaction between PUA and ZnO, which may lead to no increase in thermal stability. By incorporating ZnO nanoparticles, the UV blocking and antibacterial properties increased as the content of ZnO increased. Specially, the oxygen permeability in composite films changed from $2005cc/m^2/day$ to $150cc/m^2/day$ by adding the ZnO nanoparticle, which indicates that the PUA/ZnO nanocomposite films can be applied as good barrier packaging materials. Physical properties of the UV-cured PUA/ZnO nanocomposite film are strongly dependent upon the dispersion state of ZnO nanoparticles and their morphology in the films.

• International Journal of Highway Engineering
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• v.13 no.2
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• pp.1-8
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• 2011

The objective of this paper is to evaluate the performance of low $CO_2$ asphalt binder properties using LEADCAP$^{(R)}$(Low Energy and Carbon Asphalt Pavement) additive as function of various aging methods such as RTFO(Rolling thin film oven), Ultraviolet(UV) lay. In order to simulate the short-term aging of asphalt binder that occurs during the hot-mixing asphalt process, the Rolling Thin Film Oven(RTFO) was used. Asphalt binder using LEADCAP$^{(R)}$ is prepared by addition of a photoinitiator activated by ultraviolet lay. The mechanical and rheological properties of the asphalt binder were estimated using UTM(Universal Testing Machine) and DSR(Dynamic Shear Rheometer). The test results showed that the asphalt binder using LEADCAP$^{(R)}$ additive was improved the rutting resistance at testing temperature ($70^{\circ}C$) and increased tensile strength at low temperature. Also, Thermal analysis shows that the Melting Point(Tm) of asphalt binder using LEADCAP$^{(R)}$ additive was constant although the asphalt binder was aged by Ultraviolet.

• Applied Chemistry for Engineering
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• v.9 no.4
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• pp.579-584
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• 1998

Polymer dispersed liquid crystal(PDLC) composite films were made by polymerization induced phase separation method using UV-curing to investigate the effect of fabrication conditions, such as photoinitiator concentration, film thickness, polymerization temperature, and electric field during polymerization, etc., on the electro-optic properties. As the amount of photoinitiator increased, the driving voltage of PDLC device increased due to the increase of small-size liquid crystal phases. This was considered as the results from the increased interfacial area between liquid crystal (LC) and polymer matrix, since LC molecules at the interfacial regions were relatively difficult to response for the applied electric field. When the higher molecular weight oligomer (PTDA-1000) was used as matrix, the initial transmittance was observed to be relatively higher than that for the lower molecular weight oligomer (PTDA-250). Saturation transmittance for PTDA-1000 was observed at relatively lower voltage than that for PTDA-250, of which transmittance was not saturated even at 60 V. As polymerization temperature increased, the initial transmittance of resulting PDLC film increased due to the larger LC droplets formation and the more matched refractive index between LC and matrix than those cases for the lower polymerization temperature. Though driving voltage decreased for the thinner film, it was considered that optimum thickness of the film should be maintained to get some practical contrast, which is the ratio of off- and on-state transmittance. Furthermore, electro-optic properties such as initial transmittance, driving voltage, and response time were observed to be considerably affected by application of external field during polymerization.