• Applied Chemistry for Engineering
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• v.10 no.4
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• pp.502-508
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• 1999

We prepared non-porous membrane on the $Al_2O_3$ substrate with the different pore by the size by the plasma polymerization of $CHF_3$. We studied the permeability characteristics of membrane by Ar treatment and the effect of substrate pore size on gas permeation mechanism. The selectivity was increased with Ar plasma treatment time and rf-power near the substrate to the cathode while the permeability was decreased. It was observed that the solution-diffusion model would be applied to non-porous layers while it is applied Knudsen diffusion model to the substrate. From the experimental observation, it could be concluded that the pore size of $Al_2O_3$ membrane influenced on the permeability and the selectivity.

• Proceedings of the Korean Environmental Sciences Society Conference
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• 2006.11a
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• pp.516-518
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• 2006

생분해성 고분자 재료들은 지구환경 보호측면에서 다양한 분야, 즉, 1회용 재료, 농업용 필름 및 생체적합성 재료(약물 방출, 봉합사) 등에서 실용화되거나 활발한 연구가 진행되고 있다. 이들 재료의 상업적응용은 물성, 분해능, 제조가격, 대량생산 등에 의해 좌우 될 수 있다. 이들 중 특히, 분해 속도의 측정 및 조절은 본질적인 응용에서 가장 중요한 위치를 차지 하고 있다. 분해 속도의 규명 및 조절은 제품의 수명을 제어할 수 있고 응용분야를 넓힐 수 있다. 본 연구에서는 단분자 막장치를 이용하여 생분해성 고분자의 분해 속도 및 이성질체간의 complex 형성을 통한 분해속도의 제어를 연구하였다. complex의 형성은 분해성 고분자의 분해속도를 현저히 감소시키는 것으로 나타났다.

• Proceedings of the Membrane Society of Korea Conference
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• 1997.04b
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• pp.32-33
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• 1997

중공사막은 제조과정인 wet spining의 과정에서 defect가 형성될 수 있어 분리선택도에 큰 영향을 미친다. 이러한 defect의 처리 방법으로는 dipping method등의 방법이 현재 널리 쓰이고 있다. dipping method는 제조된 중공사막을 PDMS 등의 고분자용액 속으로 통과시켜 결과적으로 중공사막 표면에 얇은 고분자막이 형성되도록 하는 방법이다. 그러나 이러한 방법으로 중공사 막을 처리할 경우 고분자 용액이 pore내로 침입하거나 중력으로 인하여 용액이 아래쪽으로 몰려 하반부의 두께가 두꺼워진다는 단점이 있다. 본 연구에서는 플라즈마 반응기 내의 전극사이의 공간에서 substrate의 위치를 변화시켜가면서 thickness를 측정하여 중공사막의 plasma coating을 위한 기초 자료를 정립하여 중공사막 plasma 표면처리 장치 개발에 기여하고자 한다.

• 한국신재생에너지학회:학술대회논문집
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• 2007.11a
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• pp.213-216
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• 2007

PEMFC의 전기화학적 반응은 촉매, 이오노머, 기공이 만나는 삼상계면에서만 일어나므로, 전극 구조의 최적화가 성능 향상 및 장기안정성 확보에 있어 매우 중요하다. 본 연구에서는 전극 미세구조를 실시간으로 분석하기 위해 임피던스 복소캐패시턴스법을 도입하고자 하였다. 즉, PEMFC의 양극에 질소를 공급하면 0.4 V 부근에서 전기이중층 형성 반응만이 일어나는 것을 확인하였으며, 이때 음극에는 수소를 공급하여 기준전극 및 반대전극으로 사용하였다. 측정된 임피던스를 복소캐패시턴스로 변환하고 허수부를 주파수에 대해 도시하면 피크 형태의 곡선이 얻어지는데, (1) 피크 면적은 전극/전해질의 계면면적, (2) 피크 위치는 이오노머 네트워크에 의한 수소이온 전도 특성, (3) 피크 폭은 다공성 구조의 균일도를 각각 나타내므로, 피팅 없이 직접적인 해석이 가능하다는 장점을 가진다. 반면, 기존의 Nyquist 도시법은 피팅에 의한 분석이 필요하며, 전극층의 불균일한 구조로 인해 단순한 등가회로 구성이 어려운 문제점을 가진다. 최종적으로, MEA 제작 조건 및 운전 조건을 변수로 하여 임피던스를 측정하고 복소캐패시턴스 분석을 수행하여, 퇴화 경로를 규명하고 운전 조건을 최적화하고자 하였다.

• Journal of the Korean Chemical Society
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• v.37 no.7
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• pp.642-647
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• 1993

Monolayers of pure surfactant squaraine, DSSQ(4-distearyl amino phenyl-4'-dimethylaminophenylsquaraine), were deposited on $SnO_2 $ electrodes by the Langmuir-Blodgett film technique. The DSSQ film exhibits ${\lambda}_{max}$ at ∼530 nm. The absorption is significantly red-shifted from the solution of DSSQ (633 nm in chloroform), suggesting that the squaraine chromophores form aggregates in the LB film. The photogeneration of the squaraine aggregates is studied by measuring the photocurrents in photoelectrochemical cells consisting of the squaraine of the aggregates is found to parallel its absorption spectrum and quantum efficiency as high as 0.3% has been observed. While the photocurrent was attenuated exponentially when stearic acid layers (up to 8 layers) are inserted between the squaraine layer and the electrode, it is nearly extinguished when the squaraine layer is over-coated with 2 layers of stearic acid. A model for the observation is proposed and the roles of the electrolytes and oxygen on the photogeneration process will be discussed.

• Korean Chemical Engineering Research
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• v.46 no.2
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• pp.286-290
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• 2008

Small amounts of CO in reformate fuel gas effectively block platinum catalysts by strong adsorption on the platinum surface at the operation temperature of $60{\sim}80^{\circ}C$ in PEMFC. To oxidate CO, Ru/C layer (CO filter) was placed between Pt/C layer and GDL (gas diffusion layer) in this study. Ru/C filter provided good CO-tolerant PEMFC anode, but decreased the performance of unit cell about 10% at 0.6 V due to mass transfer resistance from Ru/C filter thickness and increase of charge transfer resistance. Membrane degradation is one of the most important factors limiting the life-time of PEMFCs. Membrane durability would be dependent on the electrode catalyst type. It seemed that Ru catalyst layer would shorten the life time of PEMFC as enhanced the fluoride emission rate of membrane in acceleration test.

• Journal of the Korea institute for structural maintenance and inspection
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• v.20 no.5
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• pp.58-65
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• 2016

Recent frequent occurrence of urban sinkhole serves as a momentum of the periodic inspection of sewer pipelines. Sewer inspection using a CCTV device needs a lot of time and efforts. Many of previous studies which reduce the laborious tasks are mainly interested in the developments of image processing S/W and inspection H/W. However there has been no attempt to find meaningful information from the existing CCTV images stored by the sewer maintenance manager. This study adopts a cross-correlation based image processing method and extracts location data of sewer inspection device from CCTV images. As a result of the analysis of time-location relation, it shows strong correlation between the device's stand times and the sewer damages. In case of using this method to investigate sewer inspection CCTV images, it will save the investigator's efforts and improve the sewer maintenance efficiency and reliability.

• Cartoon and Animation Studies
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• s.33
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• pp.363-382
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• 2013

Up until about ten years ago, the use of typography played only an auxiliary role on broadcast television programs, primarily by transmitting information in order to facilitate a basic understanding of content. Recently, however, kinetic typography has become an important component in broadcast production. In fact, kinetic typography has developed into a visual language and a means of artistic expression, one that is increasingly used in the production of entertainment programs on television. This paper analyzes six aspects of kinetic typography: manner of development, location, intent, expressive techniques, color and font selection. Particular attention is placed on their use in three highly rated television entertainment programs: "2 Days & 1 Night", "Running Man", and "Infinite Challenge". The development way consists of the technique : starts off with cut and ends with cut. While, other techniques show conversation and situation representation using Z axis : zoom-in, zoom-out in , X axis : pan in <2 Days & 1 Night>. and Y axis : tilt in . Typographic design elements, expression technique, color, font are shown up according to the feature of each program. The resulting analysis suggests new ways for motion arts designers and the broadcast media to use kinetic typography in the development of television programs.

• Archives of design research
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• v.20
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• pp.253-262
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• 1997

The era of film has begun as a few media critics had anticipated already. The interestings of visual designers has asked to being with images in the processing and changing of varied image culture are different from the era of print media. It is reason to being with images that are generalizing of video culture. Now the film of images that made from popular advertisings and goods influenced by films has come. At first to being with image to visual designers need to understand films and to join making films. In films, visual designers make strengthen in part of credit titles. Credit titles are elements in films with the form of text to help understanding in the beginning and closing part of films. Credit title design has begun first by American visual designer Saul Bass as p pioneer position and have made to be varied film credit technics of computer. The advanced of technics have to think aspects of meaning of titles in the film of '007' movie series through 60s &70s. In 80s more technics have developed to being varied credits to films. And after all, in 90s there are films with almost varied titles. In Korean films ars less varied than that of Amenrican's and of French, in this study I hope to develope more varied Korean credit titles in near future.

• Journal of Broadcast Engineering
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• v.14 no.6
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• pp.661-675
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• 2009

The carelessly and illegally copied contents are raising serious social problem as internet and multimedia technologies are advancing. Therefore, development of video copy detection system must be settled without delay. In this paper, we propose the hierarchical video copy detection method that estimates similarity using statistical characteristics between original video and manipulated(transformed) copy video. We rank according to luminance value of video to be robust to spacial transformation, and choose similar videos categorized as candidate segments in huge amount of database to reduce processing time and complexity. The copy videos generally insert black area in the edge of the image, so we remove rig black area and decide copy or not by using statistical characteristics of original video and copied video with center part of frame that contains important information of video. Experiment results show that the proposed method has similar keyframe accuracy to reference method, but we use less memory to save feature information than reference's, because the number of keyframes is less 61% than that of reference's. Also, the proposed method detects if the video is copied or not efficiently despite expansive spatial transformations such as blurring, contrast change, zoom in, zoom out, aspect ratio change, and caption insertion.