• Journal of Energy Engineering
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• v.6 no.1
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• pp.77-86
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• 1997

In this study, numerical computations were performed to scrutinize the effect of the size of coal particles on reactive flow fields and concentration distribution of product gases for five cases with four different particle sizes (40 $\mu\textrm{m}$, 60 $\mu\textrm{m}$, 100 $\mu\textrm{m}$, 120 $\mu\textrm{m}$, 140 $\mu\textrm{m}$) in an axisymmetric cylindrical coal gasifier in which Alaska Usibelli subbituminous coals were gasified. Predictions showed that coal particle size affected the concentration distribution of product gases. When coals of 100 $\mu\textrm{m}$ were gasified, the maximum average concentrations of major products, H$_2$and CO, were predicted at the exit of the gasifier. The average mole fractions of CO and H, were shown to be 0.62, and 0.16 (dry basis, inert free), respectively. The cold gas efficiency of 83% was also predicted for the same particle size of 100 $\mu\textrm{m}$.

• Membrane Journal
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• v.20 no.2
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• pp.87-96
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• 2010

We prepared spherical silica particles by controlling various conditions of emulsion-gel procedure using a lab-scale membrane emulsification system equipped with SPG (Shirasu porous glass) membrane having pore size of 2.6 ${\mu}m$. We determined the effects of process parameters of membrane emulsification (dispersed phase pressure, stabilizer and emulsifier concentration in continuous phase, $H_2O$/TEOS ratio, ratio of dispersed phase to continuous phase) on the mean size and size distribution of silica particles. The increase of the dispersed phase pressure and ratio of dispersed phase to continuous phase led to the increase in the mean size of silica particles. On the contrary, the increase in stabilizer and emulsifier concentration and $H_2O$/TEOS ratio caused the reduction of the mean size of particles. Through controlling these parameters, monodisperse spherical silica particles with about 3 ${\mu}m$ of the mean size were finally prepared.

• Proceedings of the Korean Quaternary Association Conference
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• 2004.11a
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• pp.4-13
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• 2004

제주도 북제주군 한림읍 협재리에는 대부분 탄산염퇴적물로 이루어진 해안사구가 분포하고 있다. 사구를 이루는 탄산염퇴적물은 연체동물과 홍조류의 조각이 약 80% 이상을 차지하며 그 외에 저서성 유공충, 성게류와 태선동물의 조각, 그리고 화산암편으로 이루어져 있어, 제주도에 분포하는 여러 탄산염 해빈퇴적물의 입자조성과 매우 유사한 경향을 나타낸다. 이러한 탄산염 입자들은 천해에 서식하던 해양생물들에 의해 생성되며, 그 각질이 해빈으로 운반되고 바람에 의해 재동되어 사구를 형성하였다. 특히 이 연구지역의 사구가 분포하는 지점에서 북쪽으로 약 1km 떨어져 있는 협재 해수욕장에는 현재에도 천해에서 생성된 많은 양의 탄산염 해빈퇴적물이 퇴적되어 있으며, 제주도의 타 지역에 비해 매우 빠른 북동${\sim}$북서방향의 바람이 불고 있어, 퇴적물을 해빈에서부터 사구형성지점으로 운반시키는 데 효과적인 역할을 했을 것으로 판단된다. 사구를 절개하여 그 단면을 관찰한 결과, 전반적으로 희미한 수평층리와 사층리가 발달하고 있으며, 그 외의 다른 뚜렷한 퇴적구조는 관찰되지 않는다. 퇴적물의 입자들은 주로 직경이 $0.27{\sim}0.40mm$로 중립질 모래에 해당한다. 이 크기의 입자들은 가장 침식이 잘 될 수 있는 입자크기에 해당하는 것으로 알려져 있으며, 따라서 해빈으로부터 퇴적물이 운반될 때에 특히 이 크기의 입자들이 차별적으로 더 많이 운반되었을 것이라고 생각된다. 또한 퇴적물 입자의 크기와 구성성분의 함량은 각 사구의 전 층준에서 크게 변화하지 않는 것으로 나타나며, 이는 사구가 형성되는 기간 동안 탄산염퇴적물을 운반한 바람의 세기가 어느 정도 일정하였음을 지시한다. 해안사구의 형성시기를 알아보기 위하여 사구의 기반을 이루는 고토양층과 사구 최하부와 최상부의 탄산염퇴적물에 대해 방사성탄소연대측정을 실시하였다. 그 결과, 사구의 형성시기를 지시하는 고토양의 연령은 $680{\sim}720\;BP\;(1,200{\sim}1,300\;AD)$로 측정되었으며, 사구를 이루는 탄산염퇴적물의 연령은 전 층준에서 모두 약 3,500 BP로 측정되었다. 따라서 약 3,500 BP에 천해에서 생성된 탄산염퇴적물이 해빈에 분포하다가 $1,200{\sim}1,300\;AD$에 바람에 의해 재동되고 현재의 위치에 쌓여 사구를 형성한 것이라고 해석할 수 있다. 사구가 형성되기 시작하던 시기는 전세계적으로 춥고 바람이 세었던 Little Ice Age ($1,300{\sim}1,820\;AD$)에 해당하며, 따라서 해빈에 분포하던 많은 양의 탄산염퇴적물이 이 시기에 집중적으로 운반된 것으로 사료된다.

• Applied Chemistry for Engineering
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• v.19 no.1
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• pp.98-104
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• 2008

This research was performed to evaluate the extraction characteristics of heavy metals for soil washing of mine tailings-contaminated soil according to particle size distribution and the chemical distributional existence of the metals. As the soil particle size was decreased, the extracted concentrations of heavy metals was increased except Fe and Mn. Most of all heavy metals were extracted within 6 h by soil washing with 0.05 M EDTA. Extraction efficiency of metals was decreased for Pb, Cu, and Zn with decreasing of particle size. Significant difference was not observed in extraction efficiency for Cd according to particle size distribution. Extraction efficiency for Cd was the highest as 86~91%, while the lowest as 5~14% for Fe. Most metals of the soil without soil washing was distributed as reducible, oxidizable, and residual fractions. Pb, Zn, and Cd existed as reducible (Fe/Mn oxide) and residual fractions and Cu existed as oxidizable and residual fractions after soil washing treatment with 0.05 M EDTA. As the soil particle size was decreased, residual fraction was increased for Pb and Cu. About 90% of reducible fraction in Pb, Zn, and Cd was removed by soil washing with 0.05 M EDTA. As the results, it was founded that soil particle size was the important parameter to effect on distributional fraction and extraction efficiency of metals in mine tailings-contaminated soil.

• Journal of the Korean Geotechnical Society
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• v.19 no.2
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• pp.199-206
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• 2003

Particle-size distribution in soils is one of the most fundamental physical properties of soils. One of the latest developments in the study of particle-size distributions has focused on the use of fractal theories. In this study, the fragmentation fractals were used for determining the characteristics of the particle-size distribution curve. It was shown that the mass-size distribution method was more practical than the cumulative number-size distribution method. From the co-relation between fractal dimensions($D_{tot}$) and the coefficient of uniformity($C_{u}$), there was a sharp increase in fractal dimensions for $C_{u}$<4, but fractal dimension converged the single value for $D_{u}$$\geq$6. Fractal dimensions were affected by small sized particles for $C_{c}$$\geq$3 and large sized particles for $C_{c}$/<3. As a result of the analysis of the influence of the effective size($D_{10}$), it was observed that the changes of $D_{tot}$/ were nominal beyond the effective size.

• Korean Journal of Materials Research
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• v.6 no.11
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• pp.1090-1098
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• 1996

개조한 가스 금속 아아크 용접공정을 이용하여 SiC/AI 금속기 복합재료를 제조하고 그 특성을 조사하였다. AI 모재위에 강화입자의 크기와 부피분율을 변화하여 다양한 SiC/AI 복합재료층을 제조하였고, 만들어진 복합재료층의 특성은 미세조직관찰과 미소경도시험을 통하여 이루어졌다. 복합재료층의 두께는 약 7-8mm로 측정되었고 균일한 강화입자의 분포도를 얻을 수 있었다. 분산입자의 부피분률은 Ar가스의 유량에 의하여 조절하였고 분산입자의 부피분률이 증가하고 크기가 작아짐에 따라 기지의 수지상 응고조직은 더욱 미세화되었다. 복합재료의 부피경도는 분산입자의 부피분률이 감소함에 따라 낮아졌으나 입자 크기에는 크게 변화가 없는 것으로 나타났다.

• Journal of the Korean Magnetics Society
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• v.24 no.1
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• pp.11-17
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• 2014

We measured the ferromagnetic resonance (FMR) signal using the monodisperse iron oxide nanoparticles with size D=4.67 nm, 5.64 nm and 6.34 nm synthesized by using the thermal decomposition method, respectively. The measured ferromagnetic resonance signals were compared with the calculated ones for superparamagnetic nanoparticles with lognormal volume distribution. The FMR linewidth broadening was propositional to tanh($V^2$), where V was volume of nanoparticles. The narrow linewidth of small size nanoparticles was due to the surface spins, while the broad linewidth of large size nanoparticles was due to the bulk spins affected by the crystalline structure of iron oxide nanoparticles. The superposition of surface and bulk effect was confirmed at D=5.64 nm nanoparticles, which was near the critical size for linewidth transition from surface effect to bulk effect.

• The Korean Journal of Quaternary Research
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• v.11 no.1
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• pp.39-56
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• 1997

한국남해에 위치한 광양만의 서북부 내만 해역에서 표층수와 저층수의 부유물질 (TSM)의 총함량과 분포의 계절적 변화양상 그리고 부유입자의 조지극성(입자의 크기)이 연 구되었다,. 연구기간중 부유물질 함량분포는 계절별로 매우 뚜렷한 특징을 보였다, 특히 여 름철 저층수의 부유물질 함량이 만조선 해역에서 높게 측정되었다. 이러한 계절별 부유물질 함량분포의 변화 원인은 얕은 수심, 해저의 표층 퇴적상 그리고 조류의 동력적 조건(최고속 도)에 기인하는 것으로 사료된다.

• Journal of the Korean Chemical Society
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• v.50 no.6
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• pp.440-446
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• 2006

ZnO nanoparticles were prepared by laser ablation of the ZnO powder dispersed in deionized water and surfactant solutions, and characterized using UV-VIS absorption spectroscopy, X-ray diffractometer and Transmission electron microscopy(TEM). ZnO nanoparticles produced show the pure ZnO crystal state without mixed state with Zn(OH)2 or Zn, and have the band gap energy of 3.35 eV, which is comparable to that of bulk ZnO. While ZnO nanoparticles prepared in SDS solution have the average diameter of 28nm with near spherical shape, those prepared in CTAB solution have the average size of 40 nm with mainly rod-like shape. ZnO colloidal solution of CTAB is more stable than that of SDS. These difference according to surfactants can be explained by difference of electrostatic interaction between surface charge of ZnO and surfactant molecules and by solvation effect in solution.

• Journal of the Korean Ceramic Society
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• v.35 no.5
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• pp.499-504
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• 1998

ZnO varistors having a composition of 98.0 mol% ZnO 1.0 mol% $Bi_2O_3$ 0.5 mol% $MnO_2$ were prepared by the Pechini process and the sintering behavior and electrical characteristics were studied. ZnO varis-색 powder with $1.5\mu\textrm{m}$ mean diameter and narow particle size distribution was obtained using the Pechni pro-cess. Typical intermediate stage grain growth of liquid phase sintering was observed by sintering at $1100^{\circ}C$ At this temperature ZnO varistors having uniform grain size and Bi-rich liquid phase distributed uniformly along grain boundaries were prepared. The nonlinear coefficients of the ZnO varistors were in the range of 40-60 The breakdown voltages of the varistors were nearly inversely propeortional to the grain size which reflects that ZnO varistors prepared by the Pechini process have uniform distribution of Bi-rich liquid phase along grain boundaries It is believed that the microstructures of ZnO varistors can be controlled effectively by using the Pechini process which makes the control of the electrical properties of ZnO varistors possible.