• Title/Summary/Keyword: 인화성

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A Study on the Estimation Model of Liquid Evaporation Rate for Classification of Flammable Liquid Explosion Hazardous Area (인화성액체의 폭발위험장소 설정을 위한 증발율 추정 모델 연구)

  • Jung, Yong Jae;Lee, Chang Jun
    • Journal of the Korean Society of Safety
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    • v.33 no.4
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    • pp.21-29
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    • 2018
  • In many companies handling flammable liquids, explosion-proof electrical equipment have been installed according to the Korean Industrial Standards (KS C IEC 60079-10-1). In these standards, hazardous area for explosive gas atmospheres has to be classified by the evaluation of the evaporation rate of flammable liquid leakage. The evaporation rate is an important factor to determine the zones classification and hazardous area distance. However, there is no systematic method or rule for the estimation of evaporation rate in these standards and the first principle equations of a evaporation rate are very difficult. Thus, it is really hard for industrial workplaces to employ these equations. Thus, this problem can trigger inaccurate results for evaluating evaporation range. In this study, empirical models for estimating an evaporation rate of flammable liquid have been developed to tackle this problem. Throughout the sensitivity analysis of the first principle equations, it can be found that main factors for the evaporation rate are wind speed and temperature and empirical models have to be nonlinear. Polynomial regression is employed to build empirical models. Methanol, benzene, para-xylene and toluene are selected as case studies to verify the accuracy of empirical models.

A Study on the Response Characteristics of the Residential Smoke Detector Depending on Controlled Fire Tests (화재실험을 통한 주택용 연기감지기 응답특성에 관한 연구)

  • SaKong, Seong-Ho;Kim, Shi-Kuk;Lee, Chun-Ha;Jung, Jong-Jin
    • Fire Science and Engineering
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    • v.23 no.4
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    • pp.98-103
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    • 2009
  • In this paper, in order to analyze the response characteristics of the smoke detectors which is suitable with the residential fire detector, the paper fire and flammable liquid fire experiment came to be accomplished according to UL Standard for safety for smoke detector for fire alarm signaling systems, UL 268. Also Photoelectric smoke detector, the Analog smoke detector and the single station alarm device came to be used with the specimen and the response characteristics of the smoke detectors which follows in these two types(paper, flammable liquid) test fire came to be analyzed. As a result, according to test fire there was some difference to response characteristics of the smoke detectors.

A Study on the Risk of Organic Solvents for Underground Area under Construction Site through a Fire Accident Case (화재사고사례를 통해서 본 건설현장 지하공간에서의 유기용제의 위험성에 대한 연구)

  • Ahn, Byung-Joon;Jung, Ki-Hyuk;Lee, Jung-Suk;Rhim, Jong-Kuk
    • Journal of the Korean Institute of Gas
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    • v.22 no.1
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    • pp.9-17
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    • 2018
  • In the consideration of the working conditions, which have several kinds of works operating at the same time, at construction sites, it is difficult to prevent industrial accidents. There are a number of works to employ flammable materials and hot works simultaneously operated without fire protection systems. It causes a huge fire and casualties. In this research to analyze an accident case, the reasonable prevention methods are suggested throughout the property tests for the organic solvents and the analysis of the behavior for vapour cloud in the underground area of the construction site.

Measurement of Lower Flash Point for Ternary Mixture, n-Nonane+n-Decane+n-Dodecane System (삼성분계 혼합물인 n-Nonane+n-Decane+n-Dodecane 계의 하부인화점 측정)

  • Ha, Dong-Myeong;Lee, Sungjin
    • Journal of the Korean Institute of Gas
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    • v.20 no.6
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    • pp.31-36
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    • 2016
  • The flash point is one of the most important indicators of the flammability of liquid solutions. The flash point is the lowest temperature at which there is enough concentration of flammable vapor to form an ignitable mixture with air. In this study the flash points of ternary liquid solutions, n-nonane+n-decane+n-dodecane system, were measured using Seta flash closed cup tester. The measured values were compared with the calculated values using Raoult's law and empirical equation. The calculated data by empirical equation described the measured values more effectively than those calculated by Raoult's law.

안전관리 - 용접공사 중 화재.폭발 등 안전사고 예방대책(1)

  • 대한설비건설협회
    • 월간 기계설비
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    • s.266
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    • pp.49-57
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    • 2012
  • 지난 8월 13일 서울 종로구 소격동 국립현대미술관 서울관 공사현장에서 화재 발생으로 4명이 숨지고 18명이 중경상을 입는 등 많은 인명피해를 냈다. 이처럼 인명피해가 컸던 것은 우레탄 공사를 하던 밀폐공간에서 불이 나면서 발생한 유독가스 때문에 사람들이 제대로 대피하지 못했기 때문이다. 사고발생 원인으로 '용접공사' 여부를 놓고 공방을 벌였으나 경찰은 '전기합선'이라는 잠정 결론을 내렸다. 지난 2008년 1월에 발생한 경기도 이천 냉동창고 화재는 40명의 목숨을 앗아갔다. 화재 원인은 냉동배관을 설치하면서 전기 용접을 하기 위해 불을 붙였다가 이것이 공기 중에 차 있던 유증기(기름증기)와 만나면서 폭발이 일어난 것이었다. 올 여름처럼 기온이 높고 건조한 날이 지속되면서 인화성 액체(유기용제)를 취급하는 건설현장에서는 다량의 유증기가 발생할 수 있을 뿐만 아니라 건조한 조건에서 정전기에 의한 화재 폭발 누출사고의 발생 위험이 높아지고 있다. 기계설비공사에서 화재, 폭발 위험성이 가장 큰 공사는 용접공사이기에 용접공사를 할 때 화재, 감전의 위험성을 배제한 후 공사에 들어간다. 용접으로 인한 사망사고의 유형으로는 용접 중 추락사고와 더불어 용접 불꽃이 가연성 물질에 옮겨 붙어 화재 발생으로 인한 질식사, 용접작업 중 절연체가 파손된 용접기 홀더 충전부의 접촉으로 인한 감전사 등이 있다. 본지는 용접으로 인한 화재 감전 등의 사고발생을 미연에 방지하기 위해 안전작업 수칙 및 안전수칙 체크리스트, 재해사례를 시리즈로 연재한다.

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Combustion Characteristics of Pool Fire by Height of Fire Source (화점높이 변화에 따른 Pool Fire의 연소특성)

  • Park, Hyung-Ju;Cha, Jong-Ho
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.11 no.11
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    • pp.4671-4676
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    • 2010
  • This study is intended to understand flame behavior of the pool fire by height of fire source. Liquid fuels were methanol and n-Heptane which are used in many studies of pool fire. Size of vessel was $100mm{\times}100mm{\times}50mm$ and the vessel was made by stainless steel. Combustion time, mass loss rate, flame temperature, flame height and air entrainment rate from the outside to flame were measured, and flame behavior was visualized with video camera. Based on the experiment, it was found that combustion characteristics of pool fire was decreased according to increase of height of fire source because entrainment volume of relative cold air was increased from the outside to flame.

Fate and Toxicity of Spilled Chemicals in Groundwater and Soil Environment II: Flammable (사고 누출 화학물질의 지하수 및 토양 환경 내 거동 및 환경 독성 특성 II: 인화성 물질을 중심으로)

  • Jho, Eun Hea;Shin, Doyun
    • Journal of Soil and Groundwater Environment
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    • v.23 no.6
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    • pp.1-8
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    • 2018
  • In this study, formaldehyde and benzene were selected as the arbitrary chemicals in accidental leakage to environment, and their physicochemical and biological characteristics and toxicity were studied. Also, the fate of these chemicals in soil and groundwater was studied based on the results of previous studies. They can be released into the atmosphere as gas or vapor phase, which then can be photochemically degraded. Since they have relatively high water solubility, they are likely to have high mobility in water and soil. Volatilization of these chemicals from soil is affected by the soil moisture content. Biodegradation of formaldehyde and benzene is one of the important pathways as well. Therefore, it is necessary to study the environmental impacts of leakage accidents of flammable chemicals such as formaldehyde and benzene. Further research on the fate of flammable chemicals in the environment is needed to take appropriate response actions to leakage accidents of flammable chemicals, and this will contribute to the development of practical guidelines to cope with leakage accidents.

A Study on the Method to Avoid the Gas Group IIC Equipment of Explosion Proof Electrical Equipment Adjacent to the Source of Release of Hydrogen Handling Facility (수소 취급설비의 누출원에 인접한 방폭전기기기의 가스그룹 IIC 기기 회피 방안에 관한 연구)

  • BYUN, YOON SUP
    • Journal of Hydrogen and New Energy
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    • v.33 no.4
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    • pp.383-390
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    • 2022
  • Appropriate explosion proof electrical equipment should be installed in hazardous areas. In areas where hydrogen is handled, explosion proof electrical equipment adjacent to the hydrogen handing facility must be reviewed for selection of gas group IIC (or IIB+H2) equipment. When selecting explosion proof electrical equipment for the flammable substance handling facility in areas where hydrogen and flammable substance are handled, the method to avoid gas group IIC (or IIB+H2) equipment has been suggested by using the operating pressure of the hydrogen handling facility. When the operating pressure of the outdoor hydrogen handling facility is 1.065 MPa or less, it has been confirmed that there is no need to install gas group IIC (or IIB+H2) equipment for the flammable substance handling facility adjacent to the hydrogen handling facility. And the method of selecting explosion proof electrical equipment for the flammable substance handling facility has been suggested as a flowchart, so it will be able to be utilized when selecting appropriate explosion proof electrical equipment.

Design of Rule-based Inference Engine for the Monitoring of Harmful Environments in Workplace

  • Ahn, Yoon-Ae
    • Journal of Korea Society of Industrial Information Systems
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    • v.14 no.4
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    • pp.65-74
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    • 2009
  • The risk of health impairment due to poor ventilation, fire and explosion by inflammable materials, and other unintended occurrences is always present in dangerous workplaces such as manholes, underground septic tanks, storage tanks and confined areas. Therefore, it a system which can monitor harmful working environment through sensors in workplace on a realtime basis and keep workers safe from the risk is needed. This paper has attempted to design an inference engine to monitor harmful environments in the workplace. The proposed inference engine has a rule-based system structure using JESS. This system is not confined to a particular computing platform and is easily interlocked with OSGi-based middleware.

A Study for Key Points of PSM to Guarantee the Safety of Liqufied Hydrogen Storage Tank (액화수소 저장탱크 안전성 확보를 위한 PSM 중점사항에 관한 연구)

  • Myoung Sun Wu;Chang Jun Lee
    • Korean Chemical Engineering Research
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    • v.61 no.1
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    • pp.74-79
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    • 2023
  • As the demand for hydrogen increases, the facilities for storing hydrogen has been important, and a few laws for hydrogen facilities should be complied. According to the Occupational Safety and Health Act in Korea, in case liquid hydrogen with a storage capacity of 5 tons or more is handled, a Process Safety Management (PSM) system should be complied. However, there are some standards which are not proper for flammable low-temperature liquefied substances on the current Occupational Safety and Health Act. In this study, 7 key points in process safey information and safety operation procedures among PSM components are suggested and how these key points should be improved is derived based on scientific analysis.