• Composites Research
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• 제25권2호
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• pp.46-53
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• 2012

펄트루젼 공정에 의해 생산된 FRP 부재는 길이에 제한이 없이 임의의 단면형상으로 제작할 수 있기 때문에 건설 구조용 부재로 사용하기 적합하며, 특히, 각종 화학적 유해환경 등에서 그 성능이 우수하기 때문에 습윤환경 및 해양환경 등의 부식환경에서 그 활용이 두드러지고 있다. 그러나 설계를 위한 관련 규준이 마련되어 있지 않아 이에 대한 연구가 시급한 실정이다. FRP 구조재는 대부분 단면의 효율적 사용을 위해 판요소로 구성된 박판부재를 사용하고 있으며, 이러한 부재를 압축재로 사용할 경우 강도한계상태는 주로 좌굴거동에 의해 결정된다. 이 연구에서는 FRP I형 단면 압축재에 대한 좌굴거동을 이론적으로 해석하였고, 기존 실험적 연구결과와 비교, 분석하여 설계방법 및 설계흐름도를 제안하였다. 제안된 설계방법은 ANSI/AISC 360-10의 방법과 유사한 형태로서 설계자의 편의를 도모하였으며, 비교적 간단한 방법에 의해 PFPR I형 단면 압축재의 설계를 수행할 수 있도록 하였다.

• 대한기계학회논문집A
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• 제34권4호
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• pp.407-412
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• 2010

새로운 티타늄기 MMCs(W/ Ti-6Al-4V)에 대한 기계적 특성에 대한 연구를 행하여 평가한 결과를 나타내었다. HIP(hot isostatic pressing) 제조법과 RS(Rotary Swaging) 2 차 가공을 통하여 텅스텐 섬유 함유율이 각각 6, 9, 12 vol%인 W/Ti-6Al-4V MMCs 를 제작하였으며, 경도는 기존의 Ti-6Al-4V 합금과 비교하여 20-30%, 인장강도는 50%(비강도-38%) 높은 값을 얻었다. 섬유 함유율 9vol.% 에서 가장 높은 인장 값을 나타내었으며, MMCs 에서 메트릭스와 계면 사이에 생성된 확산상에 의해서 경도 및 인장강도가 향상되었다. 또한 피로 강도를 향상 시키기 위한 방법으로 메트릭스의 질적 향상을 위한 HIP 제작조건에 대한 추가적인 연구가 필요하다.

• Korean Chemical Engineering Research
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• 제56권6호
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• pp.798-803
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• 2018

Si을 리튬이온전지 음극활물질로 사용하기 위해 입도를 $0.5{\mu}m$ 보다 작은 크기로 제어하였고 표면에 탄소를 약 10 nm 두께로 코팅하였다. 그 위에 탄소섬유를 50~150 wt% 양으로 성장시키고 다시 한 번 탄소코팅을 진행하였다. 이렇게 만들어진 Si 합성물질은 전기전도성을 높이기 위한 공정으로 이종 금속을 혼합하였으며 수명 특성을 개선하기 위해 흑연과 복합화하였다. 실험 변수에 따른 재료들의 물리화학적 특성을 XRD, SEM 및 TEM을 사용하여 측정하였고 코인셀을 제조하여 전기화학적 특성을 평가하였다. Si/PC (Pyrolytic Carbon)/CNF (Carbon Nano Fiber)보다 Si/PC/CNF/PC가 전체적으로 Si 함량이 줄어 방전용량은 상대적으로 낮게 나타났지만 전지평가에서 중요한 수명특성에서는 좋은 결과를 보여주었다. 0.2 C rate에서 $1512mA\;h\;g^{-1}$의 초기 방전 용량과 78%의 초기 효율을 나타내었고 10 싸이클에서 94%의 용량 보존율을 보여주었다.

• 한국염색가공학회지
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• 제34권2호
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• pp.117-126
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• 2022

In this study, thermoplastic composites were manufactured using ABS(acrylonitrile butadiene styrene), PC(polycarbonate), and POE(polyolefin elastomer), which are thermoplastic plastics. Twin screw extruder and injection molding were used to manufacture thermoplastic composites. When the ABS/PC/POE thermoplastic composite material was manufactured, the POE mass fraction was set to 1 to 5 wt.%, and the thermal and mechanical properties according to the POE mass fraction were analyzed. Based on the physical properties of ABS/PC/POE, a 3D model in the form of an e-bike frame was created. After setting the boundary conditions, when an external load is applied, geometry simulation was performed to predict product performance. The ABS/PC/POE thermoplastic composite material exhibited the best physical properties when the mass fraction of POE was 3 wt.%. In the simulation results for the physical properties of the 3D model in the form of an e-bike frame, the best physical properties were shown when the mass fraction of POE was 2 ~ 3 wt.%. As a result, the manufacturing conditions for ABS/PC/POE thermoplastic composite materials were set, and research was conducted to reduce product development costs and development time.

• 한국재료학회지
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• 제24권10호
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• pp.556-564
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• 2014

To synthesize a high-performance photocatalyst, N doped $TiO_2$ nanotubes deposited with Ag nanoparticles were synthesized, and surface characteristics, electrochemical behaviors, and photocatalytic activity were investigated. The $TiO_2$ nanotubular photocatalyst was fabricated by anodization; the Ag nanoparticles on the $TiO_2$ nanotubes were synthesized by a reduction reaction in $AgNO_3$ solution under UV irradiation. The XPS results of the N doped $TiO_2$ nanotubes showed that the incorporated nitrogen ions were located in interstitial sites of the $TiO_2$ crystal structure. The N doped titania nanotubes exhibited a high dye degradation rate, which is effectively attributable to the increase of visible light absorption due to interstitial nitrogen ions in the crystalline $TiO_2$ structure. Moreover, the precipitated Ag particles on the titania nanotubes led to a decrease in the rate of electron-hole recombination; the photocurrent of this electrode was higher than that of the pure titania electrode. From electrochemical and dye degradation results, the photocurrent and photocatalytic efficiency were found to have been significantly affected by N doping and the deposition of Ag particles.

• 한국재료학회지
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• 제29권12호
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• pp.790-797
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• 2019

To improve photocatalytic performance, CdS nanoparticle deposited TiO₂ nanotubular photocatalysts are synthesized. The TiO₂ nanotube is fabricated by electrochemical anodization at a constant voltage of 60 V, and annealed at 500 for crystallization. The CdS nanoparticles on TiO₂ nanotubes are synthesized by successive ionic layer adsorption and reaction method. The surface characteristics and photocurrent responses of TNT/CdS photocatalysts are investigated by scanning electron microscopy (SEM), X-ray diffraction (XRD), UV-Vis spectrometer and LED light source installed potentiostat. The bandgaps of the CdS deposited TiO₂ photocatalysts are gradually narrowed with increasing of amounts of deposited CdS nanoparticles, which enhances visible light absorption ability of composite photocatalysts. Enhanced photoelectrochemical performance is observed in the nanocomposite TiO₂ photocatalyst. However, the maximum photocurrent response and dye degradation efficiency are observed for TNT/CdS30 photocatalyst. The excellent photocatalytic performance of TNT/CdS30 catalyst can be ascribed to the synergistic effects of its better absorption ability of visible light region and efficient charge transport process.

• 한국철도학회:학술대회논문집
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• 한국철도학회 2010년도 춘계학술대회 논문집
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• pp.1964-1969
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• 2010

최근 건설시장 규모가 확대되고 교통산업이 발전하면서 지하철 및 터널 등과 같은 개착형 Box 혹은 Shield형 터널 구조물 등 지하구조물의 건설이 다양화되고, 그 수요도 점차 급증하고 있는 실정이다. 그러나 주로 지하에 건설되는 콘크리트 구조물은 시공시 신축이음 및 시공 조인트 등과 같은 다양한 형태의 조인트 발생과 구조물의 수축팽창에 따른 거동, 부동침하, 과다하중, 진동발생에 의한 균열로 인하여 누수가 발생되고 있다. 이에 다양한 방수공법 및 재료들이 현장에 적용되고는 있지만 지하철도, 지하철 등과 같은 진동 및 구조물의 거동이 상시적으로 발생되는 환경조건에서는 방수층의 성능이 저하되어 균열, 침식, 들뜸 등으로 물이 확산되어 재누수가 되는 악순환을 겪고 있는 실정이다. 따라서 본 연구에서는 진동 및 구조물의 거동에 대응 가능한 점착 유연형 복합방수공법을 대상으로 구조물의 거동 대응성 시험을 평가하고, 거동 및 진동이 상시적으로 발생되는 지하철, 터널 등을 대상으로 실제 현장에 적용 후 사례를 통해 구조물 거동에 대응 가능한 방수기술을 검토하였다. 이러한 거동 대응 특성을 검토한 결과 방수재가 기건 및 수중환경에서도 재료의 유연성과 부착성을 유지하여 물의 침투를 방지하고, 거동폭 $5.0mm({\pm}0.5)$ 범위에서도 거동에 대응 가능함을 알 수 있었다.

• 한국재료학회지
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• 제27권7호
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• pp.374-380
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• 2017

Properties of coatings produced by warm spray were investigated in order to utilize this technique as a repair method for Al tire molds. $Al-(0-10%)Al_2O_3$ composite powder was sprayed on Al substrate by warm spraying, and the microstructure and mechanical properties of the composite coating layer were investigated. For comparative study, the properties of the coating produced by plasma spray, which is a relatively high-temperature spraying process, were also investigated. The composite coating layers produced by the two spray techniques exhibited significantly different morphology, perhaps due to their different process temperatures and velocities of particles. Whereas the $Al_2O_3$ particles in the warm sprayed coating layer maintained their initial shape before the spray, flattened and irregular shape $Al_2O_3$ particles were distributed in the plasma sprayed coating layer. The coating layer produced by warm spray showed significantly higher adhesive strength compared to that produced by plasma spray. Hardness was also higher in the warm sprayed coating layer compared to the plasma sprayed one. Moreover, with increasing the fraction of $Al_2O_3$, hardness gradually increased in both spray coating processes. In conclusion, an $Al-Al_2O_3$ composite coating layer with good mechanical properties was successfully produced by warm spray.

• 한국재료학회지
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• 제22권11호
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• pp.604-608
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• 2012

Recently, inorganic-organic hybrid materials have attracted much attention not only for their excellent thermal conductivity but also for their flame retardant properties. In this study, the properties of organic-inorganic hybrid insulating materials using inorganic fillers and polyurethane foam with different foaming conditions have been investigated. The addition of 1.5 wt% water to polyurethane as foaming agent shows the best foaming properties. The pore size was decreased in the foaming body with increasing of the $CaCO_3$ addition. The apparent density and thermal conductivity were increased by increasing the $CaCO_3$ addition. With an increasing amount of $CaCO_3$ powder, the flame retardant property is improved, but the properties of thermal conductivity and apparent density tend to decrease. When the addition of fine particles of $CaCO_3$, the apparent density and thermal conductivity were increased and, also, with the addition of coarse particles over $45{\mu}m$ in size, the apparent density and thermal conductivity were increased as well. In this study, the adding of $CaCO_3$ with average particle size of $27{\mu}m$ led to the lowest thermal conductivity and apparent density. After evaluation with different inorganic fillers, $Mg(OH)_2$ showed the highest thermal conductivity; on the other hand, $CaCO_3$ showed the lowest thermal conductivity.

• 한국재료학회지
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• 제12권1호
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• pp.48-53
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• 2002

$Al_2O_3-SiC$ and $Al_2O_3-SiC$-TiC composite powders were prepared by SHS process using $SiO_2,\;TiO_2$, Al and C as raw materials. Aluminum powder was used as reducing agent of $SiO_2,\;TiO_2$ and activated charcoal was used as carbon source. In the preparations of $Al_2O_3-SiC$, the effect of the molar ratio in raw materials, compaction pressure, preheating temperature and atmosphere were investigated. The most important variable affecting the synthesis of $Al_2O_3-SiC$ was the molar ratio of carbon. Unreactants remained in the product among all conditions without compaction. The optimum condition in this reaction was $SiO_2$: Al: C=3: 5: 5.5, 80MPa compaction pressure under Preheating of $400^{\circ}C$ with Ar atmosphere. However there remains cabon in the optimum condition. The effect of $TiO_2$ as additive was investigated in the preparations of $Al_2O_3-SiC$. As a result of $TiO_2$ addition, $Al_2O_3-SiC$-TiC composite powder was prepared. The $Al_2O_3$ powder showed an angular type with 8 to $15{\mu}m$, and the particle size of SiC powder were 5~$10{\mu}m$ and TiC powder were 2 to $5{\mu}m$.