• Title/Summary/Keyword: 이온 검출

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Analysis of Ammonia Gas Using Ion Chromatography (이온 크로마토그래피에 의한 기체상 암모니아의 분석법 확립)

  • Lee, Jong-Hae;Min, Byung-Hun;Jeon, Ryong;Kim, Jin-Seok;Kim, Yong-Du
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2003.11a
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    • pp.366-367
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    • 2003
  • 암모니아 가스는 무색의 기체이지만 자극성이 크면서 부식성이 있고 수용액이 알칼리성인 대표적인 악취물질이다. 보통의 경우는 굴뚝 등에서 배출가스의 형태로 대량 방출되기도 하지만 자연상태에서도 여러 가지 생물학적 또는 화학적 반응 등을 통하여 생성되므로, 일상적인 생활 공간에서도 쉽게 검출될 수 있는 물질이다. 대기 중 암모니아의 농도는 기체상 시료를 직접 분석하는 가스 크로마토그래피와 시료를 액체상으로 변환시킨 후 암모늄 양이온의 농도를 분광광도법이나 중화적정법으로 측정한다. (중략)

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Mercury ion detection technique using KPFM (KPFM을 통한 수은이온 검출 방법)

  • Park, Chanho;Jang, Kwewhan;Lee, Sangmyung;You, Juneseok;Na, Sungsoo
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2014.10a
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    • pp.358-360
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    • 2014
  • For the several decades, various nanomaterials are broadly used in industry and research. With the growth of nanotechnology, the study of nanotoxicity is being accelerated. Particularly, mercury ion is widely used in real life. Because the mercury is representative high toxic material, it is highly recommended to detect the mercury ion. In previous reported work, thymine-thymine mismatches (T-T) capture mercury ion and create very stable base pair ($T-Hg^{2+}-T$). Here, we performed the high sensitive sensing method for direct label free detection of mercury ions and DNA binding using Kelvin Probe Force Microscope (KPFM). In this method, 30 base pairs of thymine (T-30) is used for mercury specific DNA binding ($T-Hg^{2+}-T$). KPFM is able to detect the mercury ion because there is difference between bare T-30 DNA and mercury mediated DNA ($T-Hg^{2+}-T$).

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Pack and Battery Management System for Multiple Balancing of Li-ion Battery (리튬이온 배터리의 다중밸런싱 배터리팩 및 관리시스템)

  • Nam, Jong-ha
    • Proceedings of the KIPE Conference
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    • 2016.11a
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    • pp.81-82
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    • 2016
  • 최근 퍼스널 모빌리티 분야에 적용되는 배터리는 대부분 리튬계열 배터리가 차지하고 있다. 각광받는 이유로는 작은 부피, 무게에 비해 큰 용량을 가지는 장점이 있고 셀당 전압의 경우에도 기존 니켈수소 및 카드뮴 등과 같은 수계전해액의 전지에 비해 3배 정도 높다는 장점을 가진다. 이러한 리튬이온배터리를 제품에 적용하기 위해서는 직병렬 구조의 팩 단위로 구성하여야 하며, 단일 셀이 아닌 다수의 셀 조합이기 때문에 충방전을 진행하는 과정에서 직렬구성 셀의 특성이 달리지게 되어 최종적으로는 전압의 차로 검출되게 된다. 이러한 전압의 차는 배터리의 용량을 저감시키고 특정 셀에 스트레스를 가중시켜 셀의 수명을 단축시키는 요인으로 작용한다.

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Feasibility Study of the microDiamond Detector for Measurement of Small Field Photon Beam (광자선 소조사면 선량측정을 위한 microDiamond 검출기의 유용성 고찰)

  • Lee, Chang Yeol;Kim, Woo Chul;Kim, Hun Jeong;Ji, Young Hoon;Kim, Kum Bae;Lee, Sang Hoon;Min, Chul Kee;Jo, Gwang Hwan;Shin, Dong Oh;Kim, Seong Hoon;Huh, Hyun Do
    • Progress in Medical Physics
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    • v.25 no.4
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    • pp.255-263
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    • 2014
  • The dosimetry of very small fields is challenging for several reasons including a lack of lateral electronic equilibrium, large dose gradients, and the size of detector in respect to the field size. The objective of this work was to evaluate the suitability of a new commercial synthetic diamond detector, namely, the PTW 60019 microDiamond, for the small field dosimetry in cyberknife photon beams of 6 different collimator size (from 5 mm to 30 mm). Measurements included dose linearity, dose rate dependence, output factors (OF), percentage depth doses (PDD) and off center ratio (OCR). The results were compared to those of pinpoint ionization chamber, diamond detector, microLion liquid Ionization chamber and diode detector. The dose linearity results for the microDiamond detector showed good linearly proportional to dose. The microDiamond detector showed little dose rate dependency throughout the range of 100~600 MU/min, while microLion liquid Ionization chamber showed a significant discrepancy of approximately 5.8%. The OF measured with microDiamond detector agreed within 3.8% with those measured with diode. PDD curves measured with silicon diode and diamond detector agreed well for all the field sizes. In particular, slightly sharper penumbras are obtained by the microDiamond detector, indicating a good spatial resolution. The results obtained confirm that the new PTW 60019 microDiamond detector is suitable candidate for application in small radiation fields dosimetry.

Evaluation of mineral, heavy metal and phthalate contents in mudflat solar salt and foreign salt (국내산 갯벌천일염과 외국산 소금의 미네랄, 중금속 및 phthalate 함량 평가)

  • Kim, Hag-Lyeol;Lee, In-Seon;Kim, In-Cheol
    • Food Science and Preservation
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    • v.21 no.4
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    • pp.520-528
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    • 2014
  • The purpose of this study was to evaluated a phthalate, heavy metal contents and physicochemical quality properties in korean mudflat solar salt and foreign salts. DEHP in mudflat solar salt (MSS) was detected a low level (9.00~669.89 ppb), but it was shown a high level excess to 1.5 ppm criteria in the foreign solar salt (FSS) 5 type (3,440.64, 3,266.56, 2,189.65, 4,010.69, 4,554.20 ppb) and foreign large solar salt (FLSS) 1 type (1,983.27 ppb). Also, DEHP in FSS 2 type (930.15, 1,310.07 ppb) and FLSS 1 type (924.92 ppb) was detected a high level not excess to criteria. No detected DMP, DEP, DIBP, DBP, DAP, BBP, DCHP and DEHA contents in MSS and foreign salt (FS). Na ion was shown a significantly higher level (p<0.05) in FS (407,345.87~426,612.14 ppm) than in MSS (363,633.98 ppm), but it was shown a high level in Mg (p<0.01), K (p<0.05), Ca ion (p<0.05) of FSS compared to foreign refined salt (FRS). Cl ion (532,727.07 ppm) of MSS was the most low level (p<0.001) compared to FS, but it was shown a high level (p<0.001) in Br ion (625.07 ppm). $SO_4$ ion was not shown a significant difference in DS and FS. It was display a high level in Mn of MSS, and Al, Fe of FLSS. Heavy metal contents (As, Cd, Pb and Hg) in MSS and FS was not significant difference, it was safety level as edible salt.

A Study of Conservation and Desalination Methods for an Iron Stele of the Joseon Dynasty (조선시대 철비(鐵碑)의 보존처리와 탈염방법 비교 연구)

  • Lee, Hye-Youn;Cho, Nam-Chul
    • Journal of Conservation Science
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    • v.25 no.4
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    • pp.399-409
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    • 2009
  • Outdoor iron artefacts are easily corroded by affection of environmental pollutants directly. Especially they need to be removed $Cl^-$ ions, but outdoor iron artefacts are excluded for desalination owing to their special features. Therefore this study contains the conservation processes of an iron stele of the Joseon Dynasty as the sample as well as desalination experiments that were carried out the desalting method using spill pads and the immersion desalting method together in order to compare. Desalting methods were compared by analyses such as an optical and metallurgical microscope, SEM-EDS, pH meter, Ion Chromatography and X-ray diffraction. As a result of the analysis, the optical and metallurgical microscopy show that the corrosion products are constituted by the layers and the metallurgical microstructure is a white cast iron. The SEM-EDS results of corrosion products detected mainly Fe, O, and especially Cl upto 2.48wt%. The results of pH and anion analysis for the washing solution, the desalting method using spill pads shows the similar effect to the immersion desalting method. As a result of XRD analysis before and after desalting corrosion products, goethite, magnetite, lepidocrocite and akaganeite are detected before desalting, but akaganeite is not detected after desalting at the desalting methode using spill pads, which indicates to have an effect on desalination. Therefore the results show that the desalting method using spill pads has an effect on desalination similar to the immersing desalting method.

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Characteristics of Detectors for Measurements of Photon Depth Doses in Build-Up Region (선량보강(Build-up) 영역에서의 광자선 깊이선량률 측정을 위한 검출기의 특성 비교)

  • Kang Sei-Kwon;Park Suk Won;Oh Do Hoon;Park Hee Chul;Kim Su Ssan;Bae Hoonsik;Cho Byung Chul
    • Progress in Medical Physics
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    • v.16 no.2
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    • pp.77-81
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    • 2005
  • To determine the appropriate method out of various available methods to measure build-up doses, the measurements and comparisons of depth doses of build-up region including the surface dose were executed using the Attix parallel-plate ionization chamber, the Markus chamber, a cylindrical ionization chamber, and a diode detector. Based on the measurements using the Attix chamber, discrepancies of the Markus chamber were within $2\%$ for the open field and increased up to $3.9\%$ in the case of photon beam containing the contaminant electrons. The measurements of an cylindrical ionization chamber and a diode detector accord with those of the Attix chamber within $1.5\%\;and\;1.0\%$ and after those detectors were completely immersed in the water phantom. The results suggest that the parallel-plate chamber is the best choice to measure depth doses in the build-up region containing the surface, however, using cylindrical ionization chamber or diode detector would be a reasonable choice if no special care is necessary for the exact surface dose.

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B-site Cationic Ordering Structures of Donor-Doped Relaxor Ferroelectric $Pb({Mg_{1/3}}{Nb_{2/3})}O_3$ (전자 주게가 첨가된 완화형 강유전체 $Pb({Mg_{1/3}}{Nb_{2/3})}O_2$의 B자리 양이온 질서배열구조)

  • Cha, Seok-Bae;Kim, Byeong-Guk;Je, Hae-Jun
    • Korean Journal of Materials Research
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    • v.10 no.7
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    • pp.478-481
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    • 2000
  • Single phase $Pb(Mg_{1/3}Nb_{2/3})O_3$ ceramics doped by 10 mol% of electron donors such as $La^3,\; Pr^{3+,4+},\; Nd^{3+},\; Sm^{3+}$, were synthesized and their B-site cationic ordering structures were investigated by XRD and TEM. In the XRD patterns, only fundamental reflections were observed for the undoped $Pb(Mg_{1/3}Nb_{2/3})O_3$, while the (h/2 $\textsc{k}$/2ι/2)(h,$\textsc{k}$,ι all odd) superlattice reflections resulting from the 1:1 ordering induced unit cell doubling were also observed for the donor-doped $Pb(Mg_{1/3}Nb_{2/3})O_3$. In the TEM selected area diffraction patterns, the (h/2 k/2 l/2)(h,k,l all odd) superlattice reflection spots as well as the fundamental reflection spots were observed for all the samples, but the relative intensities of the superlattice reflection spots to the fundamental reflection spots were significantly enhanced by the donor-doping. In the TEM dark-field images, antiphase boundaries were observed only for the donor-doped $Pb(Mg_{1/3}Nb_{2/3})O_3$. It was therefore experimentally verified that doping by electron donors such as $La^3,\; Pr^{3+,4+},\; Nd^{3+},\; Sm^{3+}$, enhances the B-site cationic 1:1 ordering in $Pb(Mg_{1/3}Nb_{2/3})O_3$. These experimental results were interpreted in terms of the charge compensation mechanism.

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Studies on the Optimum Fermenting Conditions of Dongchimi for Production of Ion Beverage (이온음료 제조를 위한 동치미의 최적 담금 조건에 관한 연구)

  • Ko, Eun-Jung;Hur, Sang-Sun;Park, Man;Choi, Yong-Hee
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.24 no.1
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    • pp.141-146
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    • 1995
  • The study was conducted for optimum fermenting conditions of Dongchimi(pony tailed chinese radish kimchi) in production of ion beverage. The changes of pH and total acidity were increased as the temperature increased. Non-volatile organic acids, such as lactic acid, citric acid, malic acid and succinic acid were produced in Dongchimi fermentation. The amount of lactic acid was increased higher, followed by citric acid and malic acid. However succininc acid was produced a little of amount at $0^{\circ}C$. Lactic acid producing bacteria number increased in initial period and then decreased in last period of fermentation. During lactic acid producing bacteria was increased, the amouont of lactic acid was increased. The flavor components were tentatively identified as methyl pentane, ethyl thioethene 2, 3-diazaindolizine, dimethyl disulfide. The optimum fermenting conditions of Dongchimi for production of ion beverage were 24~29 days at $0^{\circ}C$, 9~12dyas at $5^{\circ}C$ and 16~22days at $10^{\circ}C$, respectively.

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New Analytical Methods for Separation and Identification of Heavy Metals (II). A Study on the Adsorption and Recovery of Cu(Ⅱ) ion by Amberlite XAD-7 Resins Impregnated with Chelating Agents (중금속의 분리 및 검출을 위한 분석화학적 연구 (제 2 보) 킬레이트제-Amberlite XAD-7 침윤수지에 의한 Cu(II) 이온의 흡착 및 회수에 관한 연구)

  • Dae Woon Lee;Chul Hun Eum;Tae Sung Kim;Doo-Soon Shin;Koo Soon Chung
    • Journal of the Korean Chemical Society
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    • v.31 no.4
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    • pp.308-314
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    • 1987
  • The adsorption behavior of some chelating agents on the Amberlite XAD-7 resin was studied to obtain the optimum conditions for the preparation of chelating agent-XAD-7 resins. The chosen chelating agents are cupferron (CP), diphenylcarbazone (DPC), salicylaldoxime (SAO), thiosalicylic acid (TSA), and dimethylglyoxime (DMG), which have been well known chelating agents to Cu(Ⅱ) and Ni (Ⅱ) ions. Among the chelating agent-XAD-7 resins, SAO-XAD-7 and DMG-XAD-7 resins were evaluated as appropriate impregnated resins by investigating their stabilities in the wide pH range and high abilities to adsorb Cu(Ⅱ) and Ni(Ⅱ) ions. The selective adsorption of Cu(Ⅱ) from Ni(Ⅱ) was possible by changing pH condition by SAO-XAD-7 resin. The adsorption capacities of SAO-XAD-7 and DMG-XAD-7 for Cu(Ⅱ) were $7{\times}10^{-3}mmol$ Cu(Ⅱ) per gram of resin and $2{\times}10^{-3}mmol$ Cu(Ⅱ) per gram of resin, respectively. The quantitative recovery of Cu(Ⅱ) adsorbed by the resin was demonstrated. The adsorption behavior of Cu(Ⅱ) and Ni(Ⅱ) by the single and mixed bed of chelating agent-XAD-7 resin was discussed.

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