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열 화학기상증착법을 이용한 BCN 박막의 합성과 전기적 특성 분석

  • Jeon, Seung-Han;Song, U-Seok;Jeong, Dae-Seong;Cha, Myeong-Jun;Kim, Seong-Hwan;Kim, Yu-Seok;Lee, Su-Il;Park, Jong-Yun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.388.2-388.2
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    • 2014
  • 최근 그래핀 연구와 더불어 2차원 구조의 나노소재에 대한 관심이 급증하면서 육각형의 질화붕소(hexagonal boron nitride; h-BN) 박막(nanosheet) [1]이나 붕소 탄화질화물(boron caronitride; BCN) 박막 [2,3]와 같은 2차원 구조체에 대한 연구가 활발히 진행되고 있다. 그 중 BCN은 반금속(semimetal)인 흑연(graphite)과 절연체인 h-BN이 결합된 박막으로 원소의 구성 비율에 따라 전기적 특성을 제어할 수 있다는 장점이 있다. 따라서 다양한 나노소자로의 응용을 위한 연구가 활발히 진행되고 있다. 본 연구에서는 폴리스틸렌(polystyrene, PS)과 보레인 암모니아(borane ammonia)를 고체 소스로 이용하여 열화학기상증착법을 이용하여 BCN 박막를 SiO2 기판 위에 직접 합성하였다. SEM과 AFM 관측을 통해 합성된 BCN 박막을 확인하였으며, RMS roughness가 0.5~2.6 nm로 매우 낮은 것을 확인하였다. 합성과정에서 PS의 양을 조절하여 BCN 박막의 탄소의 밀도를 성공적으로 제어하였으며, 이에 따라 전기적인 특성이 제어되는 양상을 확인하였다. 또한 합성온도 변화에 따른 BCN 박막의 전기적인 특성이 제어되는 양상을 확인하였다. 추가적으로 같은 방법을 이용하여 BCN 박막을 Ni 위에서 합성하여 SiO2 기판위에 전사 하였다. 합성된 BCN 박막의 구조적 특징과 화학적 조성 및 결합 상태를 투과전자현미경(transmission electron microscopy), X-선 광전자 분광법(X-ray photoelectron spectroscopy)을 통해 조사하였다.

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A Study on Performance of Water Curtain Nozzles for Protection of Wooden Cultural Properties from Forest Fire (산불로부터 목조문화재 보호를 위한 수막노즐의 성능에 관한 연구)

  • Kim, Kyoung-Jin;Song, Dong-Woo;Lee, Su-Kyung
    • Fire Science and Engineering
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    • v.26 no.3
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    • pp.8-13
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    • 2012
  • This study suggests the water curtain nozzles as the way to protect important wooden cultural properties from an adjacent building fire or a forest fire. They are designed to block off the pyrolysis of timbers which occurs at $200{\sim}250^{\circ}C$ by forming a water curtain with the flow of water that spouts over a certain pressure from the bottom. The existing water curtain nozzles installed at the following sites were examined: NakSan-sa (Temple) in Gangwon-do (Province) and in Muwisa (Temple) in Jeollanam-do (South Province). As a way to improve and complement the system, this study designed nozzles with covers in order not to disrupt the landscape. Connected pipes are elevated and jet water when they are in use. Possible ways to install the connected elevating pipes to jet water effectively were investigated.

은 도핑 효과를 이용한 그래핀 투명 전도성 필름의 전기적 특성 향상

  • Jeong, Sang-Hui;Lee, Su-Il;Kim, Yu-Seok;Song, U-Seok;Kim, Seong-Hwan;Cha, Myeong-Jun;Park, Sang-Eun;Min, Gyeong-Im;Park, Jong-Yun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.566-566
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    • 2012
  • 그래핀(Graphene)은 모든 탄소 동소체의 기본구성 요소로 2 차원 결정구조를 가지며, 양자홀 효과(quantum Hall effect), 뛰어난 열 전도도, 고 탄성, 광학적 투과성 등과 같은 탁월한 물리적 성질을 보이는 물질이다. 이러한 그래핀의 우수한 특성은 전계 효과 트랜지스터(field effect transistor), 화학/바이오 센서, 투명 전극(transparent electrode) 등의 다양한 전자소자를 개발하는 응용 가능하다. 그 중, 그래핀 투명전극의 제조는 가장 응용가능성이 높은 분야이다. 현재 투명전극 물질로는 인듐-주석 산화물(indium tin oxide; ITO)가 널리 이용되고 있으나, 인듐의 고갈로 인한 공급부족 문제 및 고 생산비용, 휘어지지 않는 취성 등의 단점을 지니고 있다. 따라서, 우수한 광학적 투과성과 전기전도성을 지닌 그래핀이 ITO의 대체 물질로서 각광받고 있다.[1-5] 본 연구에서는 그래핀의 투명전도필름의 응용을 위해 면저항을 낮추기 위한 방법으로 화학적 도핑(doping)을 이용하였다. 그래핀은 구리(copper; Cu) 호일을 촉매로 사용하여 열 화학증착법(Thermal Chemical Vapor Deposition)을 이용하여 합성하였다. 합성된 그래핀은 PMMA(Poly(methyl methacrylate)) 전사법을 이용하여 산화실리콘(SiO2) 기판에 전사 후, 염화은(AgCl)과 클로로벤젠(C6H5Cl)으로 만든 콜로이드(colloid) 용액에 디핑(dipping)하여 그래핀에 은 입자를 도핑 하였다. 그 결과, 은 입자 도핑 농도에 따라 면저항이 감소하는 양상을 보였다. 제작된 그래핀 투명전도성 필름의 투과도는 자외선-가시광선-근적외선 분광법(UV-Vis-NIR spectroscopy)를 이용하여 측정하였고, 라만 분광법(Raman spectroscopy)을 통해 그래핀 필름의 질적 우수성과 성장 균일도를 조사하였다.

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Thermo-Mechanical Stress Analysis of Power Generation Turbine Blades (발전용 터빈 블레이드의 열기계 응력 해석)

  • Kim, Jong-Un;Lee, Soo-Yong;Park, Jung-Sun;Lee, An-Sung
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.30 no.6
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    • pp.84-91
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    • 2002
  • Temperature distribution in the GTD111 turbine blade used in power plaints is calculated by heat transfer analysis. Linear stress analysis of the turbine blade is also carried out under thermal loads and centrifugal forces. The numerical results of steady state heat transfer analysis slow that high temperature distribution occurs at the leading edge and tip section of the blade. The thermal stress result indicates that the equivalent stress at the tip of the pressure surface is higher than other sections of the blade. Maximum centrifugal stresses without the thermal effect occurs at the front of the fir tree. From the thermal-centrifugal stress analysis, maximum equivalent stress occurs at the fir tree. Stresses applied by the thermal loads and centrifugal forces are less than the yield stress. The GTD111 turbine blade is safe to be used in the power plants.

A Study on Field Application of 150MPa Ultra Strength Surface-Exposed Concrete (150MPa급 초고강도 노출콘크리트의 현장적용에 관한 연구)

  • Kong, Tae-Woong;Lee, Soo-Hyung;Jang, Jae-Hwan;Lee, Han-Baek
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.989-992
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    • 2008
  • In this paper, we are presenting a case that integrates ultra high strength concrete(150MPa) with surface-exposed concrete. Ahead of the field application, we carried out laboratory experiment and B/P Test for a basic property of concrete(slump flow, air content, 50cm flow time, elapse time change and compression strength) and productivity. The next, we conducted Mock-up Test using simulation specimen to evaluate infilling, surface-finishing and hydration heat of concrete. We had satisfactory results for a basic property and hydration heat of concrete. However at the time of field application, it was occurred rupture of formwork because of high lateral pressure of concrete, and then formwork was reinforced and case-in-place time was adjusted. And regardless of low and high frequency vibration, it occurred to surface-pockmark. In case that applies ultra high strength concrete to surface-exposed concrete, we estimate that it is important of systematic management and improvement of construction.

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A Study on Erosion Structure Properties for Thermal Insulation Materials on Carbon-Carbon Composites and Graphite Nozzle Throat (C-C 복합재료와 Graphite 노즐목 내열재의 침식조직 특성에 대한 연구)

  • Kim, Young In;Lee, Soo Yong
    • Journal of Aerospace System Engineering
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    • v.11 no.5
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    • pp.42-49
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    • 2017
  • The solid rocket motor(SRM) consists of a motor case, igniter, propellants, nozzle, insulation, controller, and driving device. The liquid rocket propulsion systems(LRPSs) cools the nozzle by the fuel and oxidizer but SRM does not cool the nozzle. The nozzle of SRM is high temperature condition and high velocity condition so occurs the erosion by combustion gas. This erosion occurs the change of nozzle throat and reduces thrust performance of rocket. The material of Rocket nozzle is minimization of erosion and insulation effect and endure the shear force, high temperature and high pressure. The purpose of this study is to investigate the erosion characteristics of solid rocket nozzles by each combustion time. Through the structure inspection of Graphite and C-C composite, identify the characteristics of the microstructure before and after erosion.

Time-Temperature Curve for Fire Safety Assessment of Metropolitan Transit Tunnels (도시철도 터널구조체의 내화안정성 평가를 위한 표준시간-온도곡선 적용)

  • Won, Jong-Pil;Choi, Min-Jung;Lee, Su-Jin;Lee, Sang-Woo
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.14 no.3
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    • pp.118-122
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    • 2010
  • The study presents a standard time-temperature curve to evaluate the fire performance of subway tunnel structures. The central subway section is 135km long in Korea, the fourth longest in the world. The number of subway tunnels has been increasing rapidly and fire risk is proportional to the tunnel length. However, an adequate time-temperature curve for subway tunnel fires does not exist. Therefore, we studied a proposed foreign fire design model for which the heat rate is based on the traffic, and we present an appropriate time-temperature curve for Korean subway tunnels. The ISO 834 curve was used as a fire design model and the temperature distribution in the tunnel was estimated using numerical analysis. This led to a proposal for effective measures against subway tunnel fires.

Standard Proposed for Fire Safety Evaluation of Railway Tunnels and Evaluation of Fire Temperature (철도터널내 화재시 내화성능 평가를 위한 기준 제안 및 화재 온도 평가)

  • Won, Jong-Pil;Choi, Min-Jung;Lee, Su-Jin;Lee, Sang-Woo
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.14 no.3
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    • pp.196-200
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    • 2010
  • The number of railway tunnels has been increasing rapidly. Although fires in long railway tunnels are rare, the consequences can be devastating. Prior to this study, there were no adequate time-temperature curves for the fire safety assessment of Korean railway tunnels. We studied a standard foreign time-temperature curve for which the heat rate is based on the traffic and the types of vehicles. We then proposed a hydrocarbon curve as a fire design model for railway tunnels in Korea. We examined the implications of this proposed model on railway tunnel structures using numerical analysis.

Comparison of the Internal Pressure Behavior of Liquid Hydrogen Fuel Tanks Depending on the Liquid Hydrogen Filling Ratio (액체수소 충전 비율에 따른 액체수소 연료탱크의 내부 압력 거동 비교)

  • Dongkuk Choi;Sooyong Lee
    • Journal of Aerospace System Engineering
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    • v.18 no.3
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    • pp.8-16
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    • 2024
  • Because hydrogen has very low density, a different storage method is required to store the same amount of energy as fossil fuel. One way to increase the density of hydrogen is through liquefaction. However, since the liquefied temperature of hydrogen is extremely low at -252 ℃, it is easily vaporized by external heat input. When liquid hydrogen is vaporized, a self-pressurizing phenomenon occurs in which the pressure inside the hydrogen tank increases, so when designing the tank, this rising pressure must be carefully predicted. Therefore, in this paper, the internal pressure of a cryogenic liquid fuel tank was predicted according to the liquid hydrogen filling ratio. A one-dimensional thermodynamic model was applied to predict the pressure rise inside the tank. The thermodynamic model considered heat transfer, vaporization of liquid hydrogen, and fuel discharging. Finally, it was confirmed that there was a significant difference in pressure behavior and maximum rise pressure depending on the filling ratio of liquid hydrogen in the fuel tank.

3-D Near Field Localization Using Linear Sensor Array in Multipath Environment with Inhomogeneous Sound Speed (비균일 음속 다중경로환경에서 선배열 센서를 이용한 근거리 표적의 3차원 위치추정 기법)

  • Lee Su-Hyoung;Choi Byung-Woong
    • The Journal of the Acoustical Society of Korea
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    • v.25 no.4
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    • pp.184-190
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    • 2006
  • Recently, Lee et al. have proposed an algorithm utilizing the signals from different paths by using bottom mounted simple linear array to estimate 3-D location of oceanic target. But this algorithm assumes that sound velocity is constant along depth of sea. Consequently, serious performance loss is appeared in real oceanic environment that sound speed is changed variously. In this paper, we present a 3-D near field localization algorithm for inhomogeneous sound speed. The proposed algorithm adopt localization function that utilize ray propagation model for multipath environment with linear sound speed profile(SSP), after that, the proposed algorithm searches for the instantaneous azimuth angle, range and depth from the localization cost function. Several simulations using linear SSP and non linear SSP similar to that of real oceans are used to demonstrate the performance of the proposed algorithm. The estimation error in range and depth is decreased by 100m and 50m respectively.