• Proceedings of the Korean Environmental Sciences Society Conference
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• 2003.05a
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• pp.332-333
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• 2003

졸참나무와 상수리나무를 대상으로 계절에 따른 지역(금성산, 지리산 지역)별 이소프렌 배출특성이 비교되었다. 여름철의 지역적 차이는 졸참나무의 경우 다소 약하게 나타났으며, 상수리나무의 경우에는 거의 비슷하게 나타났다. 그러나, 가을철 졸참나무의 경우에는 금성산 지역이 지리산 지역보다 높은 배출속도를 보이는 것을 알 수 있었다. 이러한 지역적 차이가 나타난 것은 성장조건, 기후, 토질 등의 요인이 이소프렌 배출특성에 영향을 주었기 때문인 것으로 사료된다.

• Analytical Science and Technology
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• v.14 no.4
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• pp.300-305
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• 2001

The impurities in isoprene were determined using GC/MS. There were good linearities (above $R^2=0.996$) in the range of the $1.0-50{\mu}g/mL$ and 0.5-5.0%, and the detection limits of the method were below $0.1{\mu}g/mL$ for each impurities. Reagent-grade isoprene contained isopropenyl acetylene and 2-butyne at $10-50{\mu}g/mL$ and the concentrations of cis-piperylene, trans-piperylene, cyclopentadiene and dicyclopentadiene were below $1{\mu}g/mL$. The analysis confirmed that the reagent grade isoprene could be obtained from the distillation of C5 fractions.

• Clean Technology
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• v.16 no.4
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• pp.272-276
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• 2010

Adsorption process for the removal of acetylene, especially 2-butyne, from isoprene was studied with zeolite as an adsorbent. In this work, zeolite 5A was selected to investigate the effects of various regeneration conditions by repeated adsorption experiments. The effect of regeneration temperature and desorption pressure was investigated to identity the optimum regeneration conditions. Repeated adsorption and desorption experiments were carried out for 10 cycles to confirm the efficiency of regeneration process under temperature of 423 K and desorption time of 16 h.

• Korean Journal of Agricultural and Forest Meteorology
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• v.17 no.3
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• pp.217-226
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• 2015

To investigate the distributions of BVOCs (Biogenic Volatile Organic Compounds) from mountain near mega city and their role in forest atmospheric, BVOCs and their oxidized species were measured at a 41 m tower in Mt. Taehwa during May, June and August 2013. A proton transfer reaction-mass spectrometer (PTR-MS) was used to quantify isoprene and monoterpenes. In conjunction with BVOCs, $O_3$, meteorological parameters, PAR (Photosynthetically Active Radiation) and LAI (Leaf Area Index) were measured. The average concentrations of isoprene and monoterpenes were 0.71 ppbv and 0.17 ppbv, respectively. BVOCs showed higher concentrations in the early summer (June) compared to the late summer (August). Isoprene started increasing at 2 PM and reached the maximum concentration around 5 PM. In contrast, monoterpenes concentrations began to increase 4 PM and stayed high at night. The $O_3$ maximum was generally found at 3 PM and remained high until 5 PM or later, which was concurrent with the enhancement of $O_3$. The concentrations of BVOCs were higher below canopy (18 m) than above canopy, which indicated these species were produced by trees. At night, monoterpenes concentrations were negatively correlated with these of $O_3$ below canopy. Using MEGAN (Model of Emissions of Gases and Aerosols from Nature), the emissions of isoprene and monoterpenes were estimated at 1.1 ton/year and 0.9 ton/year, respectively at Mt. Taehwa.

• Elastomers and Composites
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• v.28 no.3
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• pp.212-222
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• 1993

• Rubber Technology
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• v.23 no.2
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• pp.109-120
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• 2022

• The tire
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• s.61
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• pp.16-19
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• 1975

무우니이점도 30에서 70까지의 천연고무(이하 NR이라고 약)와 합성 시스-1,4-포리이소프렌(이하 IR이라고 약)의 완화탄성률에 대해서 검토했다. 완화탄성률은 -50℃로부터 90℃이며 시간 3초로부터 3,000초에 긍해서 측정했다. 동일한 무우니이점도로서 어느 온도에 있어서도 IR의 완화탄성률은 NR에 비하면 작으며 따라서 IR은 부드럽게 촉감된다고 생각된다. NR과 IR의 각종온도에서의 완화탄성률과 시간의 관계는 같은 환산계수를 사용해서 중합이 가능했었다. 얻어진 합성곡선에 대해서 특히 종단역에 있어서 NR의 완화탄성률이 IR에 비해서 크다. 이것은 같은 무우니이점도로서 NR쪽이 IR에 비하여 높은 평균분자량과 넓은 분자량분포를 가지기 때문이라고 생각된다.

• Elastomers and Composites
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• v.49 no.3
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• pp.210-219
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• 2014

In this study, the acrylic pressure sensitive adhesive (PSA) for the optical functionality sheet was prepared by blending liquid isoprene rubber. The acrylic PSA was synthesized with butyl acrylate, acrylic acid, 2-ethylhexyl acrylate and 2-hydroxyethyl methacrylate. Toluene was used to a solvent for polymerization. Liquid isoprene rubber (LIR-50) was blended with the acrylic PSA and blend ratio was 0 ~ 50 wt%. According to the results, the adhesive transfer, which was the big problem of acrylic adhesive, was reduced with the addition of LIR-50. The secondary bonding of LIR-50 with substrate did not occurred due to absence of polar group in LIR-50. The peel strength and adhesive transfer were decreased by UV curing and the degreed of decrease depended on the amounts of photoinitiator and UV irradiation time. On the other hand holding power increased drastically by increasing amounts of photoinitiator and UV irradiation time.

• Korean Journal of Agricultural and Forest Meteorology
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• v.24 no.1
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• pp.48-61
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• 2022

South Korea is quite vegetation rich country which has 63% forests and 16% cropland area. Massive NOx emissions from megacities, therefore, are easily combined with BVOCs emitted from the forest and cropland area, then produce high ozone concentration. BVOCs emissions have been estimated using well-known emission models, such as BEIS (Biogenic Emission Inventory System) or MEGAN (Model of Emission of Gases and Aerosol from Nature) which were developed using non-Korean emission factors. In this study, we ran MEGAN v2.1 model to estimate BVO Cs emissions in Korea. The MO DIS Land Cover and LAI (Leaf Area Index) products over Korea were used to run the MEGAN model for June 2012. Isoprene and Monoterpenes emissions from the model were inter-compared against the enclosure chamber measurements from Taehwa research forest in Korea, during June 11 and 12, 2012. For estimating emission from the enclosed chamber measurement data. The initial results show that isoprene emissions from the MEGAN model were up to 6.4 times higher than those from the enclosure chamber measurement. Monoterpenes from enclosure chamber measurement were up to 5.6 times higher than MEGAN emission. The differences between two datasets, however, were much smaller during the time of high emissions. More inter-comparison results and the possibilities of improving the MEGAN modeling performance using local measurement data over Korea will be presented and discussed.

• Applied Chemistry for Engineering
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• v.21 no.5
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• pp.548-552
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• 2010

This study focused on the development of effective adsorbent to remove acetylenes for the purification of isoprene. The adsorbents with various pore sizes from $4{\AA}$ to $5{\AA}$ were prepared to investigate the effect of pore size on selective adsorption of acetylene as an impurity. The pore size of zeolite A was adjusted by ion-exchange between Na and Ca ions. The pore size of adsorbents has affected the removal of acetylenes selectively because of the kinetic diameter of acetylenes, such as 2-methyl-1-butyne-3-yen (IPA) and 2-butyne. In a batch adsorption experiment, 5A zeolite with pore size of $5{\AA}$ showed the highest removal capacity of 2-butyne. However, IPA was hardly removed from isoprene by the A-type zeolites. For the adsorption isotherm, modified Langmuir model was well fitted with 2-butyne adsorption. Moreover, the regeneration of adsorbent was carried out to determine optimum method. The adsorbent heated for 12 h at $300^{\circ}C$ was regenerated significantly.