• Journal of the Korean Society for Marine Environment & Energy
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• v.17 no.2
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• pp.153-165
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• 2014

Carbon dioxide capture and storage (CCS) technology is recognizing one of method responding the climate change with reduction of carbon dioxide in atmosphere. In Korea, due to its geological characteristics, sub-seabed geological $CO_2$ storage is regarded as more practical approach than on-land storage under the goal of its deployment. However, concerns on potential $CO_2$ leakage and relevant acidification issue in the marine environment can be an important subject in recently increasing sub-seabed geological $CO_2$ storage sites. In the present study effect data from literatures were collected in order to conduct an effect assessment of elevated $CO_2$ levels in marine environments using a species sensitivity distribution (SSD) various marine organisms such as microbe, crustacean, echinoderm, mollusc and fish. Results from literatures using domestic species were compared to those from foreign literatures to evaluate the reliability of the effect levels of each biological group and end-point. Ecological effect guidelines through estimating level of pH variation (${\delta}pH$) to adversely affect 5 and 50% of tested organisms, HC5 and HC50, were determined using SSD of marine organisms exposed to the $CO_2$-induced acidification. Estimated HC5 as ${\delta}pH$ of 0.137 can be used as only interim quality guideline possibly with adequate assessment factor. In the future, the current interim guideline as HC5 of ${\delta}pH$ in this study will look forward to compensate with supplement of ecotoxicological data reflecting various trophic levels and indigenous species.

• Journal of the Korean Institute of Gas
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• v.25 no.4
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• pp.10-18
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• 2021

CO₂ storage technology in an aquifer is one of the most effective way to decrease global warming due to a high storage capacity and economics. A demonstration-scale offshore CO₂ storage project was performed in a geological deep aquifer in the Pohang Basin, Korea for a technological development of large-scale CO₂ storage. A challenging issue in the early design stage of the project was to establish the proper injectivity during CO₂ injection. To solve this issue, injection conditions were calculated by calculating injection rate, pressure, temperature, CO₂ phase change, and thermodynamic properties. For this study, we simulated and numerically analyzed CO₂ phase change from gas to supercritical phase and flow behavior in transport piping and injection tubing using OLGA program. Our results provide the injectivity conditions of CO₂ injection system combined with a bottomhole pressure of an aquifer.

• Journal of the Korean Society for Marine Environment & Energy
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• v.18 no.1
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• pp.15-21
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• 2015

This paper presents the feasibility study on $CO_2$ carrier for carbon dioxide marine geological storage. Conceptual design was carried out to acquire $CO_2$ carriers by retrofitting existing vessels and new ship-building. Based on conceptual design, the acquisition cost of $CO_2$ carriers was estimated. Finally, necessary expense and number of ships were estimated based on operational plans for the assumed scenario.

• Geophysics and Geophysical Exploration
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• v.14 no.1
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• pp.58-68
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• 2011

As part of basic studies of monitoring carbon dioxide ($CO_2$) storage using electrical and seismic surveys, laboratory experiments have been conducted to measure resistivity and P-wave velocity changes due to the injection of $CO_2$ into water-saturated sandstone. The rock sample used is a cylinder of Berea sandstone. $CO_2$ was injected under supercritical conditions (10 MPa, $40^{\circ}C$). The experimental results show that resistivity increases monotonously throughout the injection period, while P-wave velocity and amplitude decrease drastically due to the supercritical $CO_2$ injection. A reconstructed P-wave velocity tomogram clearly images $CO_2$ migration in the sandstone sample. Both resistivity and seismic velocity are useful for monitoring $CO_2$ behaviour. P-wave velocity, however, is less sensitive than resistivity when the $CO_2$ saturation is greater than ~20%. The result indicates that the saturation estimation from resistivity can effectively complement the difficulty of $CO_2$ saturation estimations from seismic velocity variations. By combining resistivity and seismic velocity we were able to estimate $CO_2$ saturation distribution and the injected $CO_2$ behaviour in our sample.

• Korean Chemical Engineering Research
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• v.52 no.5
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• pp.574-580
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• 2014

Storage tanks of Carbon dioxide ($CO_2$) carriers utilized for the purpose of carbon capture and storage (CCS) into subsea strata have to undergo a pre-cooling session before beginning to load cryogenic liquid cargos in order to prevent physical and thermal deterioration of tanks which may result from cryogenic $CO_2$ contacting tank walls directly. In this study we propose dynamic model to calculate the tank inflow of $CO_2$ gas injected for precooling process and its dynamic simulation results under proportional-integral control algorithm. We selected two cases in which each of them had one controlled variable (CV) as either the tank pressure or the tank temperature and discussed the results of that decision-making on the pre-cooling process. As a result we demonstrated that the controlling instability arising from nonlinearity and singularity of the mathematical model could be avoided by choosing tank pressure as CV instead of tank temperature.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.16 no.12
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• pp.8870-8878
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• 2015

During the carbon-dioxide capture and storage(CCS) process, $CO_2$ is captured from large point source, and then injected and stored in stable geological structure for thousands and more years. Inside the captured $CO_2$ flow, various impurities, such as $N_2$, $O_2$, argon, etc, are included inevitably. These impurities affect on the CCS process on various aspects. In this study, we designed and built experimental facility to evaluate the various impurity effect on the $CO_2$ pipeline flow, and analyzed the effect of argon ratio and pressure variation on the pressure drop of $CO_2$ flow. By comparing experimental data with 4 kinds of pressure drop model, we figured out and recommended the Cicchitti's model since it showed most accurate result among compared models in this study.

• Economic and Environmental Geology
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• v.53 no.2
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• pp.213-220
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• 2020

When CO₂ foam is injected into the saline aquifer, the relative permeability of CO₂ decreases and its viscosity increases, thereby reducing mobility in porous media and ultimately improving CO₂ storge with enhanced sweep efficiency. In general, surfactants were used to fabricate CO₂ foam. Recently, nanoparticles have been used to form stable foam than surfactant. This paper introduces CO₂ storage technology using nanoparticle stabilized CO₂ foam. If the surface of the hydrophilic nanoparticles is partially modified into a CO₂-philic portion, the particles have an affinity for CO₂ and water, thus forming a stable CO₂ foam even in deep saline aquifers under high temperature and high salinity conditions, thereby it can be stored in the pores of the rock. In terms of economics, injection method using nanopaticle-stabilized CO₂ foam is more expensive than the conventional CO₂ injection, but it is estimated that it will have price competitiveness because the injection efficiency is improved. From an environmental point of view, it is possible to inject chemical substances such as surfactants and nanomaterials into aquifers or reservoirs for specific purposes such as pollutant removal and oil production. However, some studies have shown that nanoparticles and surfactants are toxic to aquatic animals, so environmentally proven substances should be used. Therefore, further research and development will be needed to study the production and injection of nanoparticle-stabilized CO₂ foam that are environmentally safe and economically reasonable.

• Journal of the Korean Society for Marine Environment & Energy
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• v.19 no.1
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• pp.52-61
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• 2016

To inject huge amount of $CO_2$ for CCS application, high pressure pipeline transport is accompanied. Rapid depressurization of $CO_2$ pipeline is required in case of transient processes such as accident and maintenance. In this study, numerical analysis on the depressurization of high pressure $CO_2$ pipeline was carried out. The prediction capability of the numerical model was evaluated by comparing the benchmark experiments. The numerical models well predicted the liquid-vapor two-phase depressurization. On the other hands, there were some limitations in predicting the temperature behavior during the supercritical, liquid phase and gaseous phase expansions.

• Journal of Ocean Engineering and Technology
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• v.22 no.6
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• pp.88-94
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• 2008

The concentration of atmospheric carbon dioxide (CO2), which is one of the major greenhouse gases, continues to rise with the increase in fossil fuel consumption. In order to mitigate global warming the amount of CO2 discharge to the atmosphere must be reduced. Carbon dioxide capture and storage (CCS) technology is now regarded as one of the most promising options. To complete the carbon cycle in a CCS system, a huge amount of captured CO2 from major point sources such as power plantsshould be transported for storage into the marine or ground geological structures. Since 2005, we have developed technologies for marine geological storage of CO2,including possible storage site surveys and basic design of CO2 transport and storage process. In this paper, the design parameters which will be useful to construct on-shore and off-shore CO2 transport systems are deduced and analyzed. To carry out this parametric study, we suggested variations in thedesign parameters such as flow rate, diameter, temperature and pressure, based on a hypothetical scenario. We also studied the fluid flow behavior and thermal characteristics in a pipeline transport system.

• Journal of the Mineralogical Society of Korea
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• v.30 no.3
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• pp.113-126
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• 2017

In order to investigate the geological storage potential of $CO_2$, X-ray diffraction analysis were conducted for drilling core samples collected from the two drilling sites located in Yonil group of the Miocene Pohang Basin. As a result, various minerals were identified such as quartz, plagioclase, orthoclase opal-CT, smectite, mica, illite, kaolin mineral, chlorite, calcite, gypsum, pyrite, dolomite, and siderite. Smectite was detected in almost all of core samples, and relatively large amounts of smectite were observed in the cores from deeper strata. Opal-CT, mainly occurred in the upper interval of cores, was formed by diagenesis of amorphous diatoms. It shows a tendency that d101 value of cristobalite decreases with depth from $4.10{\AA}$ to $4.05{\AA}$. The almost identical variations in mineral composition with depth are observed at the two sites. This fact indicates that rocks distributed at the two sites were probably deposited in the similar depositional environments. It is determined that the strata in the study area can play roles of cap-rock for $CO_2$ storage, because the considerable amounts of smectite were contained in the rocks through the cores.