• Korean Chemical Engineering Research
• /
• v.55 no.2
• /
• pp.270-274
• /
• 2017

Formic acid has been known as one of key sources of hydrogen. Among various monometallic catalysts, hydrogen can be efficiently produced on Pd catalyst. However, the catalytic activity of Pd is gradually reduced by the blocking of active sites by CO, which is formed from the unwanted indirect oxidation of formic acid. One of promising solutions to overcome such issue is the design of alloy catalyst by adding other metal into Pd since alloying effect (such as ligand and strain effect) can increase the chance to mitigate CO poisoning issue. In this study, we have investigated formic acid deposition on the bimetallic $Pd/Pd_3Fe$ core-shell nanocatalyst using DFT (density functional theory) calculation. In comparison to Pd catalyst, the activation energy of formic acid dehydrogenation is greatly reduced on $Pd/Pd_3Fe$ catalyst. In order to understand the importance of alloying effects in catalysis, we decoupled the strain effect from ligand effect. We found that both strain effect and ligand effect reduced the binding energy of HCOO by 0.03 eV and 0.29 eV, respectively, compared to the pure Pd case. Our DFT analysis of electronic structure suggested that such decrease of HCOO binding energy is related to the dramatic reduction of density of state near the fermi level.

• Journal of the Korean Magnetics Society
• /
• v.19 no.3
• /
• pp.113-119
• /
• 2009

$^{57}Fe_xCu_{1-x}O$(x = 0.0, 0.02) powders were prepared by sol-gel method and their crystallographic and magnetic hyperfine properties have been studied using X-ray diffraction and $M{\ddot{o}}ssbauer$ spectroscopy (MS). The crystal structure of the samples is found to be monoclinic without any secondary phases and their lattice parameters increase with increasing annealing temperature ($T_A$), which is attributed to an increase in oxygen-vacancy content. MS measurements at room temperature indicate that $Fe^{3+}$ ions substitute $Cu^{2+}$ sites and ferromagnetic phase grow with increasing $T_A$. Magnetic hyperfine and quadrupole interactions of $^{57}Fe_{0.02}Cu_{0.98}O$ ($T_A=500^{\circ}C$) in the antiferromagnetic state at 17 K have been studied, yielding the following results: $H_{hf}=426.94\;kOe$, ${\Delta}E_Q=-3.67\;mm/s$, I.S.=0.32 mm/s, ${\theta}=65^{\circ}$, ${\phi}=0^{\circ}$, and ${\eta}=0.6$.

• Journal of the Korean Crystal Growth and Crystal Technology
• /
• v.6 no.1
• /
• pp.32-43
• /
• 1996

A $CdIn_{2}Te_{4}$ single crystal was grown by modified veritical bridgman method. The $CdIn_{2}Te_{4}$ single crystal was evaluated to be tetragonal by the powder method. The $CdIn_{2}Te_{4}$ single crystal was confirmed to be grown with its c axis along the lengthe of the boule by the Laue reflection method. Hall effect of $CdIn_{2}Te_{4}$ single crystal was estimated by van der pauw method from 293 K to 30 K. Hall data of the sample perpendicular to c axis was $n=8.75{\times}10^{23}electrons/m^{3},\;R_{H}=7.14{\times}10^{-5}m^{3}/C,\;{\sigma}=176.40{\omega}^{-1}m^{-1},\;{$\mu}=3.41{\times}10^{-2}m^{2}/V.s$ and the sample parallel to c axis was $n=8.61{\times}10^{23}electrons/m^{3},\;R_{H}=7.26{\times}10^{-5}m^{3}/C,\;{\sigma}=333.38{\omega}^{-1}m^{-1}\;and\;{$\mu}=2.42{\times}10^{-2}m^{2}/V.s$ for room temperature. The value of Hall coefficient on sample perpendicular or parallel to c axis were positive. There $CdIn_{2}Te_{4}$ single crystal was p-type semiconductor.

• Journal of the Korean Magnetics Society
• /
• v.13 no.4
• /
• pp.165-170
• /
• 2003

M-type hexagonal BaFe$\sub$12/O$\sub$19/ ferrite powder was prepared by sol-gel process. The M-type hexagonal structure with ${\alpha}$ = 5.882 and c = 23.215 ${\AA}$ and its Curie temperature T$\sub$C/ was determined 780${\pm}$3 K. The isomer shifts of ,4f$_2$, 2a. 4f$_1$, 12k, and 2b were indicated 0.26, 0.24, 0.15, 0.25, and 0.24 mm/s, therefore, the valence states of the Fe ions were ferric (Fe$\^$3+/). By the law of approach to saturation (LAS), the effective anisotropy field H$\sub$A/ and crystalline anisotropy constant K$_1$ were estimated. The value of K$_1$ and H$\sub$A/ were K$_1$ = 2.5${\times}$10$\^6/erg/cm^3$ and H$\sub$A/ = 14 kOe, respectively.

• Journal of the Korean Magnetics Society
• /
• v.5 no.4
• /
• pp.281-286
• /
• 1995

In order to study the effect of additives $SiO_{2}$ on the magnetic properties of hexaferrite sheet magnet, we used X-ray diffractometer, Mossbauer spectrometer, and VSM magnetometer. We have prepared $Ba_{0.25}Sr_{0.75}Fe_{12}O_{19}$ green sheets by the Dr. Blade method. Most of samples have a magnetoplurnbite crystal structure of typical M-type hexaferrite. The lattice parameters are found not to be affected by the addition of $SiO_{2}$. ${\alpha}-Fe_{2}O_{3}$ phase develops above $SiO_{2}$ 2.0 wt.%. Isomer shifts indicate that the valence of Fe ions is trivalent. Curie temperatures decrease slightly with increasing $SiO_{2}$ concentrations. It means that the $Si^{4+}$ subsitution for 12k-site $Fe^{3+}$ has an effect on the superexchange interactions Fe-O-Fe, which change the distance and the angle between cations and anions. It was suggested that ${\alpha}-Fe_{2}O_{3}$ phase results from the excessive Fe produced by subsituting $Si^{4+}$ for $Fe^{3+}$. Based upon the results of $Ba_{0.25}Sr_{0.75}Fe_{12}O_{19}$ added with $SiO_{2}$, we concluded that $H_{c}$, $M_{s}$ and $M_{r}$ depend more strongly on the microstructure chracteristics than on the cation substitution.

• Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
• /
• v.34 no.5
• /
• pp.503-514
• /
• 2016

Delineation of accurate object boundaries is crucial to provide reliable spatial information products such as digital topographic maps, building models, and spatial database. In LiDAR(Light Detection and Ranging) data, real boundaries of the buildings exist somewhere between outer-most points on the roofs and the closest points to the buildings among points on the ground. In most cases, areas of the building footprints represented by LiDAR points are smaller than actual size of the buildings because LiDAR points are located inside of the physical boundaries. Therefore, building boundaries determined by points on the roofs do not coincide with the actual footprints. This paper aims to estimate accurate boundaries that are close to the physical boundaries using airborne LiDAR data. The accurate boundaries are determined from the non-gridded original LiDAR data using initial boundaries extracted from the gridded data. The similar method implemented in this paper is also found in demarcation of the maritime boundary between two territories. The proposed method consists of determining initial boundaries with segmented LiDAR data, estimating accurate boundaries, and accuracy evaluation. In addition, extremely low density data was also utilized for verifying robustness of the method. Both simulation and real LiDAR data were used to demonstrate feasibility of the method. The results show that the proposed method is effective even though further refinement and improvement process could be required.

• The Journal of the Korea institute of electronic communication sciences
• /
• v.15 no.4
• /
• pp.665-670
• /
• 2020

Buffer layer in CIGS thin-film solar cells improves energy conversion efficiency through band alignment between the absorption layer and the window layer. ZnS is a non-toxic II-VI compound semiconductor with direct-transition band gaps and n-conductivity as well as with excellent lattice matching for CIGS absorbent layers. In this study, the structural and optical properties of ZnS thin films, deposited by RF magnetron sputtering method and subsequently performed by the rapid thermal annealing treatment, were investigated for the buffer layer. The zincblende cubic structures along (111), (220), and (311) were shown in all specimens. The rapid thermal annealed specimens at the relatively low temperatures were polycrystalline structure with the wurtzite hexagonal structures along (002). Rapid thermal annealing at high temperatures changed the polycrystalline structure to the single crystal of the zincblende cubic structures. Through the chemical analysis, the zincblende cubic structure was obtained in the specimen with the ratio of Zn/S near stoichiometry. ZnS thin film showed the shifted absorption edge towards the lower wavelength as annealing temperature increased, and the mean optical transmittance in the visible light range increased to 80.40% under 500℃ conditions.

• Journal of the Korean Society of Radiology
• /
• v.9 no.7
• /
• pp.467-471
• /
• 2015

This study's purpose is improve image quality to keep accurate tube angle in order to recognize distortion degree conditions by patient's position or tube angle and to provide exact clinical informations when taking chest AP projection for patient which have L-tube in stomach. The experimental equipment was ELMO-T6S by SHIMADZU corporation, then we put L-tube which attached 1 mm gap scales ruler on chest phantom surface. The experiment set by 90 kVp, 4 mAs, 120 cm distance. Each phantom position which changed supine, 30degree, 45degree, 60degree on the table exposured direct, ${\pm}5degree$, ${\pm}10degree$, ${\pm}15degree$ to head and feet directions. As a result, L-tube tip's position was changed by patient's position and tube angle. When patient's position is supine, tip's position change was lower than 30degree, 45degree, 60degree. We have to adjust patient's position or tube angle in order to occur image distortion by fault tube angle when confirming correct position L-tube tip through chest x-ray. Also, Radiological technologist try to make accurate evaluation index for satisfied L-tube insertion.

• Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
• /
• v.26 no.1
• /
• pp.51-61
• /
• 2008

The determination of precise geoid model for the Jeju island is needed to minimize the effect of different vertical datums. This study describes the development of gravimetric geoid model referred to GRS80 reference surface for the area of Jeju island. We used ECM96 up to degree and order 360 as a reference model and added the terrain and the residual gravity effects to the reference model. After then 17 GPS/Levelling data were used to correct the difference between the GPS/Levelling-derived geoid heights and gravimetric geoid heights. The least square collocation was applied to derive the correction and the grid values. The final precise geoid model(Jeju_GEOID07) that consist of $0.75'{\times}1'$(about $1.4km{\times}1.5km)$ grid interval was obtained in the region of $33^{\circ}{\sim}33.8^{\circ}N$ and $125.8^{\circ}{\sim}127.2^{\circ}E$. Concerning this works, the precise geoid for the Korean peninsula should be determined by integrating the different geoid developed for the peninsula and Jeju island. It is also need to integrate the vertical datum using long-term tide and GPS observations.

• Journal of the Korean Magnetics Society
• /
• v.9 no.3
• /
• pp.136-142
• /
• 1999

$Ni_{0.65}Zn_{0.35}Cu_{0.3}Fe_{1.7}O_4$ has been studied with x-ray diffraction, Mossbauer spectroscopy, and vibrating sample magnetometer. The crystal structure is found to be a cubic spinel with the lattice constant $a_0=8.403{\AA}$. Mossbauer spectra of have been taken at various temperatures ranging from 12 K to 665 K. as the temperature increases toward $T_N$ a systematic line broadening effect in the Mossbauer spectrum is observed and interpreted to originate from different temperature dependencies of the magenetic hyperfine fields at various iron sites. Also, by using binomial distribution equation we obtained the hyperfine fields of tetrahedral[A] and octahedral sites[B], $H_{hf}(A)=470\;kOe,\; H_{hf}(B0)=495 \;kOe,\; H_{hf}(B1)=485\;kOe, \;H_{hf}(B2)=453\;kOe,\; H_{hf}(B3)=424\;kOe,\; H_{hf}(B4)=390\;kOe,\; H_{hf}(Bavr)=451\;kOe$ respectively at room temperature. The isomer shift indicates that the iron ions are ferric at tetrahedral[A] and octahedral sites[B], respectively. The Neel temperature is determined to be $T_N=665\;K$. The results of the VSM data gave the magnetic moment and coercivity values of $M_S=66\; emu/g\;and\;H_C=36\;Oe$.