• Title/Summary/Keyword: 육상기원 유기물

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Distribution of Dissolved and Particulate Organic Carbon in the East China Sea in Summer (하계 동중국해에서의 용존 및 입자유기탄소의 분포 특성)

  • Kim, Soo-Kang;Choi, Young-Chan;Kim, Jin-Seok
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.11 no.3
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    • pp.124-131
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    • 2008
  • This study was conducted around the southwest sea areas of Jeju and coastal sea areas of China in August 2003 and September 2004 to research distribution patterns of dissolved inorganic nutrients, dissolved and particulate organic carbon. Distribution patterns of nutrients in the East China Sea in summer were shown to be influenced by water masses and phytoplankton. Water masses in the East China Sea in summer, except for coastal sea areas of china, showed less vertical mixing process, causing decline in the inflow of nutrients to surface water. Bottom water, however, showed high concentration, since nutrients made by dissolved organic matters from surface water were accumulated at the bottom. Sea areas with high concentration of chlorophyll a showed low concentration of nutrients and vice versa, indicating biological activities control dissolved inorganic nutrients. The distribution of dissolved organic carbon didn't show any correlation with salinity, temperatures, and water masses. Areas around the river mouth of the Changjiang showed high concentration of dissolved organic carbon more than $100{\mu}M$, but relatively low concentration in the southwest sea areas of Jeju, indicating that the river mouth of the Changjiang coastal water has a great influence on dissolved organic carbon in the East China Sea. Distribution patterns of particulate organic carbon in the research areas showed the highest concentration of average $9.23{\mu}M$ in coastal areas of China influenced by the river mouth of the Changjiang coastal water. By comparison, the concentration was relatively low at $3.04{\mu}M$ in the southeast sea areas of Jeju on which the Taiwan warm current has influence, and was $7.23{\mu}M$ in the central sea areas of Jeju. Thus, there is much indication that the river mouth of the Changjiang coastal water serves as a supplier of particulate organic carbon along with autogenous source. In general, if particulate organic carbon has a high correlation with the concentration of Chlorophyll a, it is thought that it is originated from autogenous source. However, the southeast sea areas of Jeju shows low salinity below 30, therefore it is proper to think that its origin is terrestrial source rather than that of autogenesis.

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Diatom Assemblages and its Paleoceanography of the Holocene Glaciomarine Sediments from the Western Antarctic Peninsula shelf, Antarctica (남극반도 서 대륙붕의 빙해양 퇴적물의 규조군집 특성과 고해양 변화)

  • Shin, Yu-Na;Kim, Yea-Dong;Kang, Cheon-Yoon;Yoon, Ho-Il
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.6 no.3
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    • pp.152-163
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    • 2001
  • Based upon the sedimentological, geochemical and micropaleontological analyses of two sediment cores from the Antarctic Peninsula (AP), three distinct lithological units can be recognized: (1) ice-proximal an/or ice-distal diamictons in the lower part of the cores, accumulated just seaward of the grounding line of the ice shlef until 11,000 yrs BP; (2) diatomaceous mud between 6,000 and 2,500 yrs BP in the middle part, resulted from a large influx of organic materials by enhanced production of open marine condition; (3) diatomaceous sandy mud since 2,500 yrs BP, characterized by an increase in sand content and decrease in TOC and diatom abundance in the lower layers, which reflects the formation of more extensive and seasonally persistent sea ice. Based on the C-14 radiocarbon dating, the sub-ice shlef deposition of the diamicton on the AP western shelf completed around 11,000 yrs BP. Colder condition was reinstated between 12,800 and 11,600 BP with a dropin TOC content and diatom abundance, which is coincident with the Younger Dryas event in the North Atlanticregion. At this time, the ice shelf, that is now absent in the study area, appears to advance as evidenced by an abrupt increase in sea-ice taxa. A climatic optimum is recognized between 9,000 and 2,500 BP, coincide witha mid-Holocene climatic optimum 'Hypsithermal Warm Period' from the other Antarctic sites. During this time, diatomaceous mud accumulated by a large influx of organic materials by enhanced production occurred in openmarine condition. Around 2,500 BP, diatomaceous sandy mud reflects the formation of more extensive and seasonally persistent sea ice, coincident with the onset of the Neoglacial in the Antarctic. Our results provide evidence of climatic change from the Antarctic Peninsula`s western shelf that helps in determining the existence and timing of Holocene milennial-scale climatic events in the Southern Hemisphere.

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Distribution of Particulate Organic Matters along the Salinity Gradients in the Seomjin River Estuary (섬진강 하구역에서 염분경사에 따른 입자성 유기물질의 분포)

  • Kwon Kee Young;Moon Chang Ho;Kang Chang Keun;Kim Young Nam
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.35 no.1
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    • pp.86-96
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    • 2002
  • The distributions of suspended particulate matter (SPM), chlorophyll a, particulate organic carbon (POC) and nitrogen (PON) and particulate biogenic silica (PBSi) along the salinity gradient were investigated in the Seomjin River estuary from March 1999 to April 2001. Sampling sites were set based on the surface salinity during each cruise rather than geographic locations. Concentrations of SPM were less than 20 mg/L, suggesting relatively low input of terrestrial SPM despite large freshwater discharge through Seomiin River, Chlorophyll a peaks occurred at 5$\~$ 15 psu salinity zone (10$\~$20 km from Nan Cho Island) in November 1999, at 15$\~$25 psu (10$\~$20 km) salinity zone in April 2000 and at 1$\~$15 psu salinity zone (15$\~$20 km) in October 2000 (ca. 8$\~$58%\mu$g/L). Concentrations of POC, PON and PBSi were also high at the same zone. Relatively low ratios of POC to chlorophyll a in mid-salinity zone where POM peak occurred suggests high contribution of living phytoplankton to the total POC. On the other hand, relatively high ratios of POC to chlorophyll $\alpha$ in very low salinity zone and the mouth of estuary indicated relatively high portions of detrital POC. Consequently, the low concentrations of SPM in this estuary and the high concentrations of chlorophyll $\alpha$ and the low ratios of POC to chlorophyll $\alpha$ in the mid-salinity zone suggest that production of living phytoplankton is primary factor in controlling distribution of POM along the salinity gradients in the Seomjin River estuary.

Heavy Metals in Surface Sediments from Doam Bay, Southwestern Coast of Korea (한국 남서해안 도암만 표층퇴적물의 중금속 함량 및 분포 특성)

  • CHO, HYEONG-CHAN;CHO, YEONG-GIL
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.20 no.4
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    • pp.159-168
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    • 2015
  • Forty-four surface sediments from Doam Bay were analyzed for total organic carbon (TOC), total nitrogen (TN), total metal (Al, Fe, Mn, Cr, Cu, Ni, Pb, Zn) and further chemical partitioning of metals were carried out in some samples. The TOC (0.32~3.10%) and TN (0.03~0.26%) values of the samples were similar to those of other coastal area. The C/N ratios ranged from 7.9 to 11.9 with an average 9.3 which revealed that contribution of terrestrial organic matters was relatively rare. Contents of analysed metals showed a level lower than threshold effects level (TEL) in sediment quality guidelines. Based on the chemical speciation of metals, the lattice fractions were found in the order Cr > Cu > Ni > Zn > Pb > Mn, while Mn and Pb are the ratio of the non-lattice fractions accounted for more than 50%. The average baseline values were obtained relative cumulative frequency curves and linear regression analysis. The respective baseline concentrations for Cu, Ni, Pb, Zn, Cr and Mn were 11.8, 23.1, 26.8, 76.6, 56.7, 585 mg/kg, respectively. Based on geoaccumulation index ($I_{geo}$) with a baseline values of Mn showed that face the contamination phase from estuarine stations. However, in case of Zn and Pb, although there is no sign of contamination, it could be release from sediment when there is a change in the environment, which is caused from the high ratio of non-lattice fractions.

마지막 최대빙하기 이후 북극해 스발바드군도 Van Mijenfjorden의 고환경 변화

  • 남승일;김예동;윤호일;강천윤
    • Proceedings of the Korean Quaternary Association Conference
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    • 2004.06a
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    • pp.46-46
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    • 2004
  • Van Mijenfjorden은 스발바드 군도의 Spitsbergen 서부에 위치하는 두 번째로 큰 피오르드로 온난하고 염분도가 높은 북대서양의 표층수가 북극해로 유입되는 Gateway에 위치하기 때문에 전지구적이며 지역적인 기후변화의 영향을 받는 지역이다. 1999년 IMAGES 프로그램의 일환으로 프랑스 탐사선인 'R/V Marion Dufresne'을 이용하여 북극해의 스발바드 군도에 위치하는 Van Mijenfjorden (77$^{\circ}$ 46.87'N and 15$^{\circ}$ 17.81'E)에서 약 18m의 빙ㆍ해양 퇴적물 코아(MD99-2305)를 시추하여 마지막 최대 빙하기 이후의 고환경변화를 연구하였다. AMS 14C 연대 측정에 의하면 diamicton 층인 하부 2m를 제외한 16m의 퇴적층은 지난 12cal. ka BP경에 피오르드에 존재하던 조수빙하(tidewater glacier)가 해빙되기 시작한 이후에 퇴적되었다. 특히 유기지화학 자료와 부유성과 저서성 유공충의 산출양상 그리고 저서성 유공충인 C. reniforme의 산소ㆍ탄소 안정동위원소 비에 의하면 코아 MD99-2305에는 Van Mijenfjorden에서 홀로세 동안에 일어난 퇴적환경변화를 잘 기록하고 있다. 특히 홀로세 동안에 피오르드내의 퇴적환경 변화는 조수빙하의 확장과 후퇴와 밀접한 관계가 있으며, 유기물의 탄소동위원소(13Corg) 비는 -24에서 -22$\textperthousand$ 값의 변화를 보인다. 이는 Van Mijenfjorden 퇴적물에 공급된 유기물은 육상과 해양기원이 혼합되어 퇴적되었음을 지시한다. 지난 12 cal. ka BP 이후 13Corg 값이 뚜렷하게 변하는 것은 Van Mijenfiorden에서 조수빙하의 변동과 표층수에서의 생산력의 변화를 강하게 반영한다. 강하게 반영한다.53%가 이공계 출신, 100대 기업 CEO의 38.4%가 이공계 출신, 대입수능시험에서 자연계 지원비율이 감소 -40.1%('99)\$\longrightarrow$34.7%('00)\$\longrightarrow$29.4%('01)\$\longrightarrow$26.9%('02)\$\longrightarrow$30.3%('03)\$\longrightarrow$31.5%\$\longrightarrow$'04)필요성, 효과적인 운전자 교육 정책 등이 그것이다. 자동차 긴급 피난 차선은 유용한 시설로 여러곳에서 그 기능이 발휘되고 있으므로 많은 고속도로 관계자들은 설계, 시공 및 유지 관리 측면에서 유의해야 할 것이다.미세조직을 광학현미경으로 압출방향에 평행한 방향과 수직방향으로 관찰하였고, 열간 압출재 이방성을 검토하기 위하여 X선 회절분석을 실실하여 결정방위를 확인하였다. 전기 비저항 및 Seebeck 계수 측정을 위하여 각각 2$\times$2$\times$10$mm^3$ 그리고 5$\times$5$\times$10TEX>$mm^3$ 크기의 시편을 준비하였다.준비하였다.전류를 구성하는 주요 입자의 에너지 영역(75~l13keV)에서 가장 높은(0.80) 상관계수를 기록했다. 넷째, 회복기 중에 일어나는 입자들의 유입은 자기폭풍의 지속시간을 연장시키는 경향을 보이며 큰 자기폭풍일수록 현저했다. 주상에서 관측된 이러한 특성은 서브스톰 확장기 활동이 자기폭풍의 발달과 밀접한 관계가 있음을 시사한다.se that were all low in two aspects, named "the Nonsignificant group". And the issues were

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Characteristics of Geochemical Processes along the Salinity Gradient in the Han River Estuary (한강 기수역에서 염분구배에 따른 지화학적 특성 변화)

  • 김동화;박용철;이효진;손주원
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.9 no.4
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    • pp.196-203
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    • 2004
  • To understand the geochemical processes in the Han River Estuary, distributions and behaviors of nutrients, dissolved organic matters, and uranium were investigated and analyzed during estuarine tidal mixing in June 2000 and February 2001. The distribution of inorganic nutrients showed very dynamic distributional patterns implying an apparent nitrification process and a concave non-conservative mixing along the salinity gradient. Dissolved organic carbon was high in the upstream region and decreased sharply in the low salinity region of around 5 psu. The 3-D fluorescence characteristic of dissolved organic matter showed two distinct fluorophores in the study area. Biomacromolecules originated mainly from the indigenous biochemical processes and geomacromolecules from terrestrial humic materials. In the study area, the distribution of geomacromolecule showed a concave non-conservative property along the salinity gradient presumably due to the flocculation and removal processes in the estuary. Meanwhile, distribution of the dissolved uranium, mainly in the form of stable uranium carbonate complex, also showed a concave non-conservative property along the salinity gradient in the Han River Estuary. From this study, the removal rate of dissolved uranium in the Han River Estuary was estimated to be about 7.1 ton per year.

Isotopic Determination of Food Sources of Benthic Invertebrates in Two Different Macroalgal Habitats in the Korean Coasts (동위원소 분석에 의한 동해와 남해 연안의 상이한 해조류 군락에 서식하는 저서무척추동물 먹이원 평가)

  • Kang, Chang-Keun;Choy, Eun-Jung;Song, Haeng-Seop;Park, Hyun-Je;Soe, In-Soo;Jo, Q-Tae;Lee, Kun-Seop
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.12 no.4
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    • pp.380-389
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    • 2007
  • Stable carbon and nitrogen isotopes were analyzed in suspended particulate organic matter, macroalgae and macrobenthic invertebrates in order to determine the importance of primary organic matter sources in supporting food webs of rocky subtidal and intertidal macroalgal beds in the Korean coasts. Investigations were conducted at the inter tidal sites within Gwangyang bay, a semi-enclosed and eutrophicated bay, and the subtidal sites of the east coast, a relatively oligotrophic and open environment, in May and June 2005. Water-column suspension feeders showed more negative $\delta^{13}C$ values than those of the other feeding guilds, indicating trophic linkage with phytoplankton and thereby association with pelagic food chains. In contrast, animals of the other feeding guilds, including interface suspension feeders, herbivores, deposit feeders, omnivores and predators, displayed relatively less negative $\delta^{13}C$ values than those of the water-column suspension feeders and similar with that of macroalgae, indicating exclusive use of macroalgae-derived organic matter and association with benthic food chains. Most the macrobenthic species were considered to form strong trophic links with benthic food chains. In addition, the distribution of higher $\delta^{15}N$ values in macrobenthic consumers and macroalgae at the intertidal sites of Gwangyang Bay than those at the subtidal sites of the east coast suggests that anthropogenic nutrients may enhance the macroalgal production at the intertidal sites and in turn be incorporated into the particular littoral food web in Gwangyag Bay. These results confirm the dominant role of macroalgae in supporting rocky subtidal and intertidal food webs in the Korean coasts.

Environmental Characteristics of Seawater and Sediment in Mariculture Management Area in Ongjin-gun, Korea (옹진군 어장관리해역의 수질 및 퇴적물 환경 특성)

  • Kim, Sun-Young;Kim, Hyung-Chul;Lee, Won-Chan;Hwang, Dong-Woon;Hong, Sok-Jin;Kim, Jeong-Bae;Cho, Yoon-Sik;Kim, Chung-Sook
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.19 no.6
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    • pp.570-581
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    • 2013
  • To improve productivity of aquaculture animals with management of culturing grounds, survey of mariculture management area in Ongjin-gun about water quality and sedimentary environment had been conducted on June, August and November in 2011. Water temperature in surface and bottom waters ranged from 9.49 to $24.14^{\circ}C$. Salinity and dissolved oxygen concentrations were in the range of 23.19~31.49 and 5.48~9.36 mg/L, respectively, depending on the variation of water temperature. The average concentration of COD was 1.57 mg/L and the concentrations of DIN and DIP showed entirely low level. As the result of grain size analysis, sand(56.66 %) and silt(34.60 %) were predominated. The Mz of sediment showed a variation of 2.59 to $6.62{\O}$ and sorting appeared to be poorly sorted. The concentrations of COD and IL in surface sediment ranged from 1.00 to $11.03mg/g{\cdot}dry$ and 0.72 to 5.29 %, respectively, which showed relatively good positive correlations. On the environmental assessment of trace metals in surface sediment, geoaccumulation index ($I_{geo}$) class indicated that sediments were not contaminated by most of metallic elements except Cr and As. Our result implies that this study area showed good water quality and sediments were not polluted by organic matters and metallic elements.

Applications of Radiocarbon Isotope Ratios in Environmental Sciences in South Korea (방사성탄소동위원소비 분석을 적용한 우리나라 환경과학 연구)

  • Neung-Hwan Oh;Ji-Yeon Cha
    • Korean Journal of Ecology and Environment
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    • v.56 no.4
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    • pp.281-302
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    • 2023
  • Carbon is not only an essential element for life but also a key player in climate change. The radiocarbon (14C) analysis using accelerator mass spectrometry (AMS) is a powerful tool not only to understand the carbon cycle but also to track pollutants derived from fossil carbon, which have a distinct radiocarbon isotope ratio (Δ14C). Many studies have reported Δ14C of carbon compounds in streams, rivers, rain, snow, throughfall, fine particulate matter (PM2.5), and wastewater treatment plant effluents in South Korea, which are reviewed in this manuscript. In summary, (1) stream and river carbon in South Korea are largely derived from the chemical weathering of soils and rocks, and organic compounds in plants and soils, strongly influenced by precipitation, wastewater treatment effluents, agricultural land use, soil water, and groundwater. (2) Unprecedentedly high Δ14C of precipitation during winter has been reported, which can directly and indirectly influence stream and river carbon. Although we cannot exclude the possibility of local contamination sources of high Δ14C, the results suggest that stream dissolved organic carbon could be older than previously thought, warranting future studies. (3) The 14C analysis has also been applied to quantify the sources of forest throughfall and PM2.5, providing new insights. The 14C data on a variety of ecosystems will be valuable not only to track the pollutants derived from fossil carbon but also to improve our understanding of climate change and provide solutions.

Geochemistry and Water Quality in the Tidal Flat of Saemangum Area, West Sea of Korea in Summer (하계 새만금 갯벌의 수질 분포 및 지화학적 특성에 관한 연구)

  • Park, Gyung Soo;Park, Soung Yun;Lee, Sam Geun;Lee, Yoon
    • Journal of Wetlands Research
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    • v.6 no.1
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    • pp.133-147
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    • 2004
  • Environmental quality(water and sediment) was analyzed in the tidal flat of Saemangum of Jeonbuk Province, the west coast of Korea, using the 101 sediment samples and 69 water samples collected in September 4~13, 2001. Major water quality parameters with the means of 69 surface water samples are as follows; $25.51{\pm}0.68^{\circ}C$ for water temperature, $29.88{\pm}5.01$ for salinity, $1.40{\pm}0.78mg/L$ for COD, $0.352{\pm}0.417mg/L$ for DIN, and $0.027{\pm}0.023mg/L$ for phosphate, respectively. Higher values were found at the subestuary of Dongjin and Mangyung River, and lower values at the Saemangum embayment and Gomso Bay. There was a significant negative correlation between salinity and the other water quality parameters(p<0.0001) such as COD, nutrients, SS and N/P. This correlation suggested that the major pollution sources be from terrestrial inputs through tributaries in this area. Principal component analysis clearly revealed a spatial variation of water quality; stations with higher values of nutrients and COD located subestuary of tributaries. 14 sediment quality parameters including 8 trace metals were measured using the 101 surface sediment samples. Average values for the parameters are as follows; Al $2.28{\pm}0.92%$, Cd $0.61{\pm}0.27ppm$, Cu $8.95{\pm}4.06ppm$, Fe $1.19{\pm}0.37%$, Mn $182.31{\pm}77.45ppm$, Ni $10.83{\pm}4.97ppm$, Pb $15.20{\pm}4.35ppm$, Zn $41.34{\pm}34.62ppm$, COD $2.68{\pm}1.85mg/g\;dry$, AVS $0.04{\pm}0.08mg/g\;dry$, IL $1.29{\pm}1.08%$, water content $24.11{\pm}4.49%$, TN $0.02{\pm}0.02%$, TC $0.22{\pm}0.30%$. Spatial variations of sediment quality were not clear as water quality. Some higher values were found at the subestuary of Gum River and lower values at the other area. There was a significant positive correlation between the heavy metal concentrations and organic materials within the sediment(p<0.05). Enrichment factors showed the ranges of 1~2 for most of the metals in the sediment except zinc(1~6), indicating no serious exogenous input of heavy metals in the study area. Also, the heavy metal concentrations in the sediment were within the ranges found at the natural marine environments.

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