• Title/Summary/Keyword: 유-무기 하이브리드 페로브스카이트

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Slot-die Coating Method for Manufacturing Large-area Perovskite Solar Cell (대면적 페로브스카이트 태양전지 제작을 위한 슬롯-다이코팅 방법)

  • Oh, Ju-young;Ha, Jae-jun;Lee, Dong-geun
    • The Journal of the Korea Contents Association
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    • v.21 no.12
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    • pp.918-925
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    • 2021
  • The perovskite solar cell is a next-generation solar cell that replaces the existing silicon solar cell. It is a solar cell device using an organic-inorganic hybrid material having a perovskite structure as a photoactive layer. It has advantages for the process and has shown rapid efficiency improvement over the past decade. In the process of commercialization of such perovskite solar cells, research and development for a large-area coating method should be carried out. As one of the large-area perovskite solar cell large-area coating methods, the slot-die coating method was studied. By using a meniscus to pass over the substrate and coating the solution, the 3D printer was equipped with a meniscus so that it could be coated. Variables that act during coating include bed temperature, coating speed, N2 blowing interval, N2 blowing height, N2 blowing intensity, etc. By controlling these, the perovskite absorption layer was manufactured and the coating conditions for manufacturing large-area devices were optimized.

A Study on Optimization of Perovskite Solar Cell Light Absorption Layer Thin Film Based on Machine Learning (머신러닝 기반 페로브스카이트 태양전지 광흡수층 박막 최적화를 위한 연구)

  • Ha, Jae-jun;Lee, Jun-hyuk;Oh, Ju-young;Lee, Dong-geun
    • The Journal of the Korea Contents Association
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    • v.22 no.7
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    • pp.55-62
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    • 2022
  • The perovskite solar cell is an active part of research in renewable energy fields such as solar energy, wind, hydroelectric power, marine energy, bioenergy, and hydrogen energy to replace fossil fuels such as oil, coal, and natural gas, which will gradually disappear as power demand increases due to the increase in use of the Internet of Things and Virtual environments due to the 4th industrial revolution. The perovskite solar cell is a solar cell device using an organic-inorganic hybrid material having a perovskite structure, and has advantages of replacing existing silicon solar cells with high efficiency, low cost solutions, and low temperature processes. In order to optimize the light absorption layer thin film predicted by the existing empirical method, reliability must be verified through device characteristics evaluation. However, since it costs a lot to evaluate the characteristics of the light-absorbing layer thin film device, the number of tests is limited. In order to solve this problem, the development and applicability of a clear and valid model using machine learning or artificial intelligence model as an auxiliary means for optimizing the light absorption layer thin film are considered infinite. In this study, to estimate the light absorption layer thin-film optimization of perovskite solar cells, the regression models of the support vector machine's linear kernel, R.B.F kernel, polynomial kernel, and sigmoid kernel were compared to verify the accuracy difference for each kernel function.

Properties of Perovskite Materials and Devices Fabricated Using the Solvent Engineered One-Step Spin Coating Method (단일 스텝 스핀 코팅 방법에서 증발 제어 공정 변경에 따른 페로브스카이트 박막 물성 및 태양 전지 소자 특성 변화에 관한 연구)

  • Oh, Jungseock;Kwon, Namhee;Cha, DeokJoon;Yang, JungYup
    • New Physics: Sae Mulli
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    • v.68 no.11
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    • pp.1208-1214
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    • 2018
  • The one-step spin coating method is reported as an excellent thin film process because it can be easily used to fabricate high-quality methyl-ammonium lead tri-iodide ($MAPbI_3$) perovskite layers. One of the important things in the one-step spin coating method towards obtaining high-quality $MAPbI_3$ layers is the anti-solvent (AS) engineering, which consists of an one-step deposition of the $MAPbI_3$ film and dripping of the AS. The properties of the $MAPbI_3$ layer were found to be strongly influenced by the amount, dispensing speed, and spraying time of the AS solution. The $MAPbI_3$ solution was prepared by dissolving lead iodide and methyl-ammonium iodide in N,N-dimethylformamide and adding N,N-dimethyl sulfoxide. Diethyl ether (DE) was used for the AS solution. The results indicate that a $MAPbI_3$ layer appropriately sprayed with DE is beneficial for improving film quality and device efficiency because nucleation of $MAPbI_3$ layer is affected by the characteristics of DE, which affect the film's crystallinity, density, and surface morphology. The $MAPbI_3$ layer, which was optimized by using 0.7 mL of DE, a 3.03 mL/sec dispensing speed, and a 7 second time to spray after spinning showed the best efficiency of 13.74%, which was reproducible.