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http://dx.doi.org/10.5392/JKCA.2021.21.12.918

Slot-die Coating Method for Manufacturing Large-area Perovskite Solar Cell  

Oh, Ju-young (한양솔라에너지)
Ha, Jae-jun (한양솔라에너지)
Lee, Dong-geun (한양솔라에너지)
Publication Information
The Journal of the Korea Contents Association / v.21, no.12, 2021 , pp. 918-925 More about this Journal
Abstract
The perovskite solar cell is a next-generation solar cell that replaces the existing silicon solar cell. It is a solar cell device using an organic-inorganic hybrid material having a perovskite structure as a photoactive layer. It has advantages for the process and has shown rapid efficiency improvement over the past decade. In the process of commercialization of such perovskite solar cells, research and development for a large-area coating method should be carried out. As one of the large-area perovskite solar cell large-area coating methods, the slot-die coating method was studied. By using a meniscus to pass over the substrate and coating the solution, the 3D printer was equipped with a meniscus so that it could be coated. Variables that act during coating include bed temperature, coating speed, N2 blowing interval, N2 blowing height, N2 blowing intensity, etc. By controlling these, the perovskite absorption layer was manufactured and the coating conditions for manufacturing large-area devices were optimized.
Keywords
Perovskite Soalr Cell; Slot Die; Large Area; Commercialization; Stability;
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1 V. Gonzalez-Pedro, E. J. Juarez-Perez, W. S. Arsyad, E. M. Barea, F. F. Santiago, I. M. Sero, and J. Bisquert, "General working principles of CH3NH3PbX3 perovskite solar cells," Nano Lett., Vol.14, pp.888-893, 2014.   DOI
2 Xie Ziang, Liu Shifeng, Qin Laixiang, Pang Shuping, Wang Wei, Yan Yu, Yao Li, Chen Zhijian, Wang Shufeng, Du Honglin, Yu Minghui, and G. G. Qin, "Refractive index and extinction coefficient of CH3NH3PbI3 studied by spectroscopic ellipsometry," Opt. Mater. Express, Vol.5, pp.29-43, 2015.   DOI
3 정윤경, 태양광 산업 및 모듈가격 전망과 대내외 대응 전략 연구, 연구보고서 2013-21, 2013.
4 S. I. Seok, "Solvent-engineering for high performanceinorganic-organic hybrid perovskite solar cells," Nature Materials, Vol.13, pp.897-903, 2014.   DOI
5 A. Kojima, K. Teshima, Y. Shirai, T. Miyasaka, et al "Organometal Halide Perovskites as Visible-Light Sensitizers for Photovoltaic Cells," J. Am. Chem. Soc., Vol.131, No.17, pp.6050-6051, 2009.   DOI
6 J. Seo, S. Park, Y. C. Kim, N. J. Jeon, J. H. Noh, S. C. Yoon, and S. I. Seok, "Energy Environ," Sci., Vol.7, p.2642, 2014.
7 Q. Q. Lin, A. Armin, R. C. R. Nagiri, P. L. Burn, and P. Meredith, "Nat," Photonics, Vol.9, pp.106-112, 2015.   DOI
8 J. H. Heo, H. J. Han, D. S. Kim, T. K. Ahn, and S. H. Im, "Energy Environ," Sci., Vol.8, p.1602, 2015.
9 H. S. Kim, S. H. Im, and N. G. Park et al, "Effect of Different Hole Transport Materials on Recombination in CH3NH3PbI3 Perovskite-Sensitized Mesoscopic Solar Cells," J. Phys. Chem. Lett., Vol.4, No.9, pp.1532-1536, 2013.   DOI
10 M. A. Green, A. H. Baillie, and H. J. Snaith et al, "The emergence of perovskite solar cells," Nature Photonics, Vol.8, pp.506-514, 2014.   DOI
11 P. Loper, M. Stuckelberger, B. Niesen, J. Werner, M. Filipic, S. J. Moon, J. H. Yum, M. Topic, S. D. Wolf, C. Ballif, and J. Phys, "Chem," Lett, Vol.6, pp.66-71, 2015.
12 C. Wehrenfennig, M. Z. Liu, H. J. Snaith, M. B. Johnston, and L. M. Herz, "Charge-carrier dynamics in vapour-deposited films of the organolead halide perovskite CH3NH3PbI3-xClx," Energy Environ, Sci., Vol.7, pp.2269-2275, 2014.   DOI
13 H. S. Kim, C. R. Lee, J. H. Im, K. B. Lee, T. Moehl, A. Marchioro, S. J. Moon, R. H. Baker, J. H. Yum, J. E. Moser, M. Gratzel, and N. G. Park, "Lead Iodide Perovskite Sensitized All-Solid-State Submicron Thin Film Mesoscopic Solar Cell with Efficiency Exceeding 9%," Scientific Reports, Vol.2, No.591, 2012.
14 C. W. Chen, S. Y. Hsiao, C. Y. Chen, H. W. Kang, Z. Y. Huang, and H. W. Lin, "Optical properties of organometal halide perovskite thin films and general device structure design rules for perovskite single and tandem solar cells," J. Mater. Chem. A, Vol.3, pp.9152-9159, 2015.   DOI