• 제목/요약/키워드: 유리탄소

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Pigment production in Monascus anka (Monascus anka의 균주선발 및 색소생성 조건)

  • Kim, Soo-Un;Kim, Jeong-Gu
    • Applied Biological Chemistry
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    • v.33 no.3
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    • pp.239-246
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    • 1990
  • Monascus anka strains with higher pigment production were developed using UV mutation and natural selection. To obtain organic solvent soluble pigments from Monascus anka, the following culture conditions were compared : standing and shaking culture with Nishikawa's medium, and shaking culture with Lin's medium. Shaking culture in Lin's medium exhibited decrease in solvent-soluble intracellular pigments after initial increase. The decrease was accompanied by the increase in water-soluble extracellular pigments. Monascus anka preferred sucrose and ethanol among 7 carbon sources tested. Treatment of sterol biosynthesis inhibitors, $({\pm})$-miconazole and chlorocholine chloride(CCC) , directed carbon pool to the biosynthetic pathway leading to the pigments with CCC's more pronounced effect. Two dimensional TLC revealed at least 7 yellow pigments suggesting existence of hereto unreported pigment. One of the most abundant yellow pigments was isolated and found to be ankaflavin by NMR and MS analysis.

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Using a Bismuth-film Glassy Carbon Electrode Based on Anodic Stripping Voltammetry to Determine Cadmium and Lead in a Standard Rice Flour (양극벗김전위법 비스무스막 유리탄소전극을 이용한 표준 쌀 분말 내 카드뮴과 납 측정)

  • Kim, Hak-Jin;Son, Dong-Wook;Mo, Chang-Yeon;Han, Jae-Woong;Kim, Gi-Young;Park, Sang-Won;Om, Ae-Son
    • Journal of Biosystems Engineering
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    • v.34 no.5
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    • pp.377-381
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    • 2009
  • Excessive presence of heavy metals in environment may contaminate plants and fruits grown in that area. Rapid on-site monitoring of heavy metals can provide useful information to efficiently characterize heavy metal-contaminated sites and minimize the exposure of the contaminated food crops to humans. This study reports on the evaluation of a bismuth-coated glassy carbon electrode for simultaneous determination of cadmium (Cd) and lead (Pb) in a NIST-SRM 1568a rice flour by anodic stripping voltammetry (ASV). The use of a supporting electrolyte 0.1 M $HNO_3$ at a dilution ratio (sample pretreated with acid digestion in a microwave oven: supporting electrolyte) of 1:1 provided well-defined, sharp and separate peaks for Cd and Pb ions, thereby resulting in strongly linear relationships between Cd and Pb concentrations and peak currents measured with the electrode ($R^2\;=\;0.97$, 0.99 for Cd and Pb, respectively). The validation test results for spiked standard solutions with different concentrations of Cd and Pb gave acceptable predictability for both spiked Cd and Pb ions with mean prediction errors of 6 to 30%. However, the applicability of the electrode to the real rice flour sample was limited by the fact that Cd concentrations spiked in the rice flour sample were overly estimated with relatively high variations even though Pb ion could be quantitatively measured with the electrode.

Optical properties of diamond-like carbon films deposited by ECR-PECVD method (ECR-PECVD 방법으로 증착한 Diamond-Like carbon 박막의 광 특성)

  • Kim, Dae-Nyoun;Kim, Ki-Hong;Kim, Hye-Dong
    • Journal of Korean Ophthalmic Optics Society
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    • v.9 no.2
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    • pp.291-299
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    • 2004
  • DLC films were deposited using the ECR-PECVD method with the fixed deposition condition, such as ECR power, methane and hydrogen gas-flow rates and deposition time, for various substrate bias voltage. We have investigated the ion bombardment effect induced by the substrate bias voltage on films during the deposition of film. The characteristic of the films were analyzed using the FTIR, Raman, and UV/Vis spectroscopy analysis shows that the amount of dehydrogenation in films was increased with the increase of substrate bias voltage and films thickness was decreased. Raman scattering analysis shows that integrated intensity ratio(ID/IG) of the D and G peak was increased as the substrate bias voltage increased and films hardness was increased. Optical transmittances of DLC film were decreased with increasing deposition time and substrate bias voltage. From these results, it can be concluded that films deposited at this experimental have the enhanced characteristics of DLC because of the ion bombardment effect on films during the deposition of film.

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An Experimental Study on Bond Characteristics of FRP Reinforcements with Various Surface-type (다양한 표면형상에 따른 FRP 보강재의 부착특성 실험연구)

  • Jung, Woo Tai;Park, Young Hwan;Park, Jong Sup
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.31 no.4A
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    • pp.279-286
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    • 2011
  • FRP (Fiber Reinforced Polymer) tendons can be used as an alternative to solve the corrosion problem of steel tendons. Material properties of FRP tendons-bond strength, transfer length, development length-must be determined in order to apply to concrete structures. First of all, in case of application for pretension concrete members with CFRP tendons, transfer length is an important characteristic. The bond of the material characteristics should be demanded clearly to apply to PSC structures prestressed with FRP tendons. This paper investigated on the bond characteristics of FRP reinforcements with various surface-type. To determine the bond characteristics of FRP materials used in place of steel reinforcement or prestressing tendon in concrete, pull-out testing suggested by CAN/CSA S806-02 was performed. A total of 40 specimens were made of concrete cube with steel strands, deformed steel bar and 6 different surface shape FRP materials like carbon or E-glass. Results of the bonding tests presented that each specimen showed various behaviors as the bond stress-slip curve and compared with the bond characteristic of CFRP tendon developed in Korea.

Biodiesel Production Using Castor Oil and Quality Analysis (피마자유로부터 바이오디젤 생산을 위한 물성 분석)

  • Kim, Deogkeun;Lee, Joonpyo;Park, Soonchul;Lee, Jinsuk
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.05a
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    • pp.176.2-176.2
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    • 2011
  • 피마자유(Castor oil)는 합성수지, 그리스, 유압용 오일, 윤활기유 등의 다양한 용도로 쓰이는 오일로서 점도가 높고 무색에서 황갈색을 띈다. 피마자유 추출은 압착 착유 또는 용매 추출로 얻게 되며 본 실험에 사용된 오일은 압착 착유한 것으로 매우 진한 갈색을 띄는 정제전 오일을 이용하였다. 실험에 사용된 피마자유의 초기 산가는 1mgKOH/g 이하로 낮은 유리지방산 함량을 보였으며 수분은 0.3%로 전이에스테르화 반응을 위해서는 수분 증발이 필요했다. 피마자유의 바이오디젤 생산을 위해 진행된 물성 분석 항목은 산가, 수분, 인함량, 황함량, 점도, 고형물이며 원료유와 그 바이오디젤에 대해 각각 물성 분석을 실시하였다. 피마자유의 가장 큰 특징은 다른 식물성 오일과는 다르게 오일이 알코올에 녹는 특성이 있으며 이런 이유로 전이에스테르화 반응 후 바이오디젤과 글리세롤이 분리되지 않는 문제점을 갖고 있다. 피마자유를 이용해 제조한 바이오디젤, 즉 지방산메틸에스터의 함량을 분석한 결과 약 90%의 메틸에스터화 반응 전환율을 나타내었으나 국내외 품질규격상의 탄소수 C14~C24:0의 지방산 에스터(fatty acid methyl esters)로 검출되는 바이오디젤의 함량은 10% 미만으로 나타났으며 나머지 90%는 라이신올레익산메틸에스터(ricinoleic acid methyl ester)로 분석되었다. 따라서, 기존의 대두유, 유채유, 팜유, 폐식용유로부터 제조한 바이오디젤과 물성이 매우 상이하고 특히 끊는점(boiling point)과 점도가 높아 경유 대체연료로는 활용이 불가능할 것으로 판단된다. 하지만 기존의 다양한 용도의 오일로 사용하기 위해 정제하는 과정에서 전체 착유 오일중의 약 10%만을 선택적으로 분리하여 바이오디젤 원료로 활용하는 방안은 가능할 것으로 판단된다.

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Behavior of Stress and Deformation Generated by Repair Welding under Loading (공용중 보수용접에 의한 용접부의 응력 및 변형의 거동 - 인장력 작용중 균열보수용접에 의해 생기는 응력 및 변형의 거동 -)

  • Chang, Kyong-Ho;Lee, Sang-Hyong;Jeon, Jun-Tai
    • Journal of Korean Society of Steel Construction
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    • v.12 no.3 s.46
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    • pp.269-279
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    • 2000
  • It is much expected that steel bridges, which have been damaged by increase of vehicle load and corrosion, need repair or strengthening. In this paper, the stress generated by repair welding under loading are analyzed by three dimensional elasto-plastic analyses. The longer and deeper repair weld line bocemes, the larger the magnitude of transient stress becomes. The magnitude of transient stress generated by repair welding under loading $({\sigma}_y/3,\;{\sigma}_a)$ is similar to summation of stresses generated by repair welding and loading. The longer repair weld line ratio(1/b) becomes, the larger the magnitude of transient stress generated by repair welding under loading bocomes. And, the longer repair weld line ratio(1/b) becomes, the larger the magnitude of in-plane displacement generated by repair welding under loading$({\sigma}_y/3,\;{\sigma}_a)$.

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Forming Process of Surface Contaminants on Ten-story Stone Pagoda of Wongaksa Temple, Seoul (서울 원각사지 십층석탑의 표면오염물 형성과정)

  • Chun, Yu Gun;Lee, Myeong Seong;Kim, Yuri;Lee, Sun Myung;Lim, Bo A
    • Journal of Conservation Science
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    • v.32 no.3
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    • pp.365-375
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    • 2016
  • This study was interpreted the forming process of surface contaminants on ten-story stone pagoda of Wongaksa temple, Seoul. Results of research, we estimated that black contaminants were formed by graphite stuck carbon in air pollution substance after that gypsum was generated by chemical weathering on stone pagoda. White contaminants were built by recrystallization of calcite that were made by decomposition of finishing materials and structure on the stone surface. To preserve a long-term of stone pagoda in Wongaksa temple, there were required that continuous monitoring, anticorrosion treatment and contaminants cleaning of protective facilities.

A Study on Electromagnetic Wave Absorbing Sandwich Structures (샌드위치 구조를 갖는 전자기파 흡수체에 관한 연구)

  • Park, Ki-Yeon;Lee, Sang-Eui;Kim, Chun-Gon;Lee, In;Han, Jae-Hung
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.32 no.6
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    • pp.64-71
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    • 2004
  • The object of this study is to design the Radar Absorbing Structures (RAS) having sandwich structures in the X-band ($8.2{\sim}12.4GHz$) frequencies. Glass fabric/epoxy composites containing conductive carbon blacks and carbon fabric/epoxy composites were used for the face sheets. Polyurethane(PU) foams containing multi-walled carbon nanotube (MWNT) were used for the core. Their permittivities in the X-band were measured using the transmission line technique. The reflection loss characteristics for multi-layered sandwich structures were calculated using the theory of transmission and reflection in a multi-layered medium. Three kinds of specimens were fabricated and their reflection losses in the X-band were measured using the free space technique. Experimental results were in good agreements with simulated ones in 10dB absorbing bandwidth.

The Fruit-body Formation and Properties of Pholiota sp. (비늘버섯속균(Pholiota sp.)의 특징과 자실체 형성)

  • Sung, Jae-Mo;Lee, Jae-Keun;Park, Dong-Soo
    • The Korean Journal of Mycology
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    • v.26 no.2 s.85
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    • pp.194-199
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    • 1998
  • Pholiota sp. were collected from the forest of Kangwon province (Mt. Samak, Mt. Odae and Kangwon National University Forest Experimentation) from the early of August to the end of October 1997. Among these fungi, Poliota adiposa was selected for culture experiment because it is suitable for edible mushroom. The Optimal temperature for the mycelial growth of Pholiota adiposa was in the range of $28^{\circ}C$ while that of fruit body formation was $15{\pm}1^{\circ}C$. Brown sugar as carbon source and soybean flour as nitrogen source were good for mycelial growth in commercial liquid culture. The fruit bodies of Pholiota adiposa were artifitially produced on plastic bottle including poplar sawdust and rice bran (4:1).

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Optical Properties of Aspheric Glass Lens using DLC Coated Molding Core (성형용 코어면 DLC 코팅에 의한 비구면 Glass렌즈 광학적 특성에 관한 연구)

  • Kim, Hyun-Uk;Cha, Du-Hwan;Lee, Dong-Gil;Kim, Sang-Suk;Kim, Hye-Jeong;Kim, Jeong-Ho;Jeong, Sang-Hwa
    • Korean Journal of Optics and Photonics
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    • v.18 no.5
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    • pp.362-366
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    • 2007
  • In this research, the optimal grinding condition has been obtained by design of experiment (DOE) fur the development of aspheric lens for the 3 Mega Pixel, 2.5x optical zoom camera-phone module. Also, the tungsten carbide (WC) mold was processed by the method of ultra precision grinding under this optimal grinding condition. The influence of diamond-liked carbon (DLC) coating on form accuracy (PV) and surface roughness (Ra) of the mold was evaluated through measurements after DCL coating using ion plating on the ground mold. Also, aspheric glass lenses were molded, some before DLC coating of the mold and some after the DLC coating. The optical characteristics of each sample, molded by the different molds, were compared with each other.