• Title/Summary/Keyword: 유기용매

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DC conduction mechanism of PEDOT by adding organic solvents (PEDOT 합성시 유기용매 첨가에 따른 DC 전기전도 메카니즘)

  • Park, Chang-Mo;Kim, Tae-Young;Kim, Youn-Sang;Kim, Jong-Eun;Suh, Kwang-S.
    • Proceedings of the KIEE Conference
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    • 2004.07c
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    • pp.1709-1711
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    • 2004
  • 3,4-ethylenedioxythiophene(EDOT)을 ferric-toluenesulfonate(FTS)로 doping하여 합성하였다. 이때 다양한 유기용매를 함께 첨가하여 합성하였고, 온도에 따른 각각의 DC 전도도를 측정하였다. FTS로 dofing된 poly(3,4-ethylenedioxythiophene) (PEDOT)는 3-D variable range hopping model을 잘 따르며, alcohol류의 용매와 함께 합성한 경우는 상온의 DC 전도도가 2 S/cm로 0.4 S/cm의 reference 보다 전기전도를 증가시키는 반면, ketone류는 약 $10^{-11}$ S/cm로 전기전도를 감소시키는 경향을 보였다. 전도도의 증감과 doping level의 관계를 규명하기 위하여 X-ray 분석을 하였다.

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A study on Enhancement Effectiveness of Cyanoacrylate Fumed Fingermark by the Solvent of Rhodamine 6G (Rhodamine 6G 용매에 따른 CA 훈증 지문 증강 효과에 관한 연구)

  • Shim, Yea-Ra;Yu, Je-Seol
    • The Journal of the Korea Contents Association
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    • v.17 no.7
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    • pp.294-302
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    • 2017
  • In this study, latent fingermarks deposited in porous or non-porous surface was developed by cyanoacrylate fuming, and then the developed fingermark is enhanced by using Rhodamine 6G. Between water-based R6G and organic solvent-based R6G, author studied about which material have higher effectiveness in enhancing fingermark. In all seven types of surfaces depositing fingermark, water-based R6G have higher effectiveness in enhancing fingermark and lower surface coloring than organic solvent-based R6G. But because the surfaces found in crime scene have multicolor background and various quality, the additional study about various surfaces is needed.

Transport of Organic Acids through Porous Sulfonated Polystyrene Divinylbenzene Copolymer Membranes (다공성 술폰화 폴리스티렌-디비닐벤젠 공중합체 분리막을 통한 유기산의 이동)

  • 이광재;한정우;조영일
    • Membrane Journal
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    • v.1 no.1
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    • pp.44-54
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    • 1991
  • Sulfonated polystyrene-divinylbenzene(PS-DVB) copolymer membranes were prepared using different diluents (toluene, cyclohexane, cyclohexanol), various diluent ratio and DVB contents. And initial fluxes of organic acids were investigated by varying pH and initial concentration. As a results, water content and ion-exchange capacity decreased with increasing DVB concetration. Among used diluents, cyclohexanol was the most efficient for building up the highest water content and ion-exchange capacity. In the experiment of permeation, carboxylic acid such as formic acid and acetic acid showed higher fluxes when pH was lower than pKa and amino add such as L-alanine showed minimum flux when pH was isoelectric value. The relationaship between initial fluxes and initial concentrations has been expressed by saturation kinetics.

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Process for the Preparation of Conducting Polymer Composites (II) : The Effect of Polymerization Parameters on Conductivity (전도성 고분자 복합체 제조를 위한 신합성 연구(II) : 중합변수에 따른 전도성 고분자 복합체의 전도도 변화)

  • Son, Suk-Hye;Pak, Young-Jun;Kim, Jung-Hyun
    • Applied Chemistry for Engineering
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    • v.7 no.6
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    • pp.1061-1068
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    • 1996
  • The conducting polymer composites were prepared by imbibing the porous particle wish the $FeCl_3$ oxidant solution, drying the imbibed porous particle, and imbibing again with pyrrole solution for polymerization to take place in the pore of porous particles. The effect of synthesis conditions on the conductivity of composite polymers were investigated. It was found that the conductivity of composite polymers was dependant on the concentration of pyrrole monomer, nature of the oxidants and solvents used for the oxidant and pyrrole, which influence the degree of penetration/distribution of polyprrole in the composite and reaction of dopant with pyrrole.

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Comparison of Commercial Organic Solvent Nanofiltration (OSN) Membrane Performance (상용 유기용매 나노여과막 성능분석 및 비교)

  • Kim, Sumin;Song, Guntak;Kim, Jeong F.
    • Membrane Journal
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    • v.31 no.4
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    • pp.282-292
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    • 2021
  • In this work, we tested commercial organic solvent nanofiltration (OSN) membranes using both in-house dead-end and crossflow systems. Four different crosslinked polyimide Duramem (DM) OSN membranes with various MWCO (molecular weight cut off) values were tested in organic solvents such as ethanol, N,N-dimethylformamide, acetone and acetonitrile. The membranes exhibited more reliable and reproducible performance in the crossflow system, and the performance changed significantly depending in the physical properties of the testing solvent. This is due to the initial stabilization period via pressure-induced compaction phenomenon, which can be vastly different between membrane samples. Hence, to obtain reliable and reproducible results, crossflow system is the preferred choice.

Development of Porous Silicon Electro-osmotic Pumps for High Flow Rate Per Current Flow Delivery of Organic Solvents (단위전류당 고유량 유기용매 이송을 위한 다공성 실리콘막 전기침투 펌프의 개발)

  • Kwon, Kil-Sung;Kim, Dae-Joong
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.34 no.2
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    • pp.105-111
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    • 2010
  • Two types of electro-osmotic pumps were prepared: with anodized and DRIE porous silicon. The pump performance was characterized for both types in terms of flow rate and flow rate per current using organic solvents. Both types of electro-osmotic pumps showed a better performance compared to porous glass electro-osmotic pumps. The DRIE porous silicon electro-osmotic pump especially demonstrated an excellent flow rate and flow rate per current performance. The DRIE porous silicon electro-osmotic pump is expected to help in the development of electro-osmotic pumps and micropumps in general due to the recently widespread availability of DRIE processes.

Enantioselective Resolution for the Preparation of Chiral para-Nitrostyrene Oxide by Microbial Epoxide Hydrolase in an Organic Solvent (미생물 에폭사이드 가수분해효소 활성을 이용한 유기용매에서의 광학활성 para-Nitrostyrene Oxide 생산)

  • 배현철;김현숙;이수정;이은열;양승택;김희숙
    • Journal of Life Science
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    • v.12 no.4
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    • pp.423-426
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    • 2002
  • Enantioselective resolution of racemic para-nitrostyrene oxide was investigated using epoxide hydrolase activity of Aspergillus niger LK for the production of optically pure (S)-para-nitrostyrene oxide. To overcome the poor solubility of the substrate, enantioselective hydrolysis in an organic solvent was attempted under optimized reaction conditions including reaction temperature and water content. (S)-para-Nitrostyrene oxide with high optical purity (> 99% ee) was obtained at 37% yield using fungal epoxide hydrolase-catalyzed enantioselective resolution.

A Study on Curing of Commercially Available Chines Urushiol (옻칠의 경화에 관한 연구)

  • Kim, Young-Baek;Park, Deok-Soo
    • The Journal of Natural Sciences
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    • v.8 no.2
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    • pp.21-26
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    • 1996
  • Commercially available Chines oriental lacquer was treated to get two fractions, hexane soluble fraction and hexane insoluble fraction. Hexane soluble fraction was subjected to thermal curing process. Films obtained from the lacquer under normal conditions and obtained from thermal curing were compared. The compounds in hexane soluble fraction were copolymerized with 1,6-diisocyanohexane, and toluendiisocyanate(TDI). Films obtained by thermal curing were highly brittle and hydrophobic while the films obtained under normal conditions were hydrophilic. Curing reaction did not occur when oxygen was not available.Some of the major component in the lacquer was isolated by HPLC and UV spectrum of each compound was recorded.

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Reactivation of Horseradish Peroxidase in Organic Media Using Solvent Evaporation (용매 증발에 의한 유기용매내 Horseradish peroxidase의 재생)

  • Choe, Yu-Seong;Yu, Yeong-Je
    • KSBB Journal
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    • v.14 no.4
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    • pp.465-469
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    • 1999
  • Horseradish peroxidase(HRP) in organic solvent can be reactivated by evaporation. In order to measure the evaporation effect, the enzyme solutions were obtained by evaporation and dilution of organic solvent, respectively. Although two situations were thermodynamically identical, the activity from evaporation was higher than that from dilution. From the UV absorbance and the fluorescence intensity mesurements, it can be explained that reactivation of enzyme activity might be caused by reversible folding, and the enzyme obtained by evaporation was more refolded than that obtained by dilution.

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