• Title/Summary/Keyword: 유기도막

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A Study on the Aging Behavior of Ship Organic Coating by the Flow Induced Shear Stress (유동 전단응력에 의한 선박 유기도막의 열화거동 연구)

  • Park Hyun;Park Jin-Hwan;Ha Hyo-Min;Chun H.H.;Lee In-Won
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.12 no.1 s.24
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    • pp.9-14
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    • 2006
  • Analysis has been made of the anti-corrosive property of organic coating under the shear stress of the flow by means of AC impedance method. Marine anti-corrosive painted panels were placed in the water channel with varying flow rate, thereby experiencing varying flow shear stress on the surfaces. The velocities of the salt water were ranged from 1.48 to 5.2 m/s and the coating thickness of from $70{\mu}m\;to\;140{\mu}m$. For all coating thicknesses investigated, the poorer anti-corrosive property and the lower adhesion strength have been found for the higher shear stress. It has been found that the shear stress accelerates the aging of organic marine coatings.

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$O_2$ 플라즈마 처리에 따른 ITO 투명전도막의 특성변화

  • Yu Jae-Hyeok;Gong Su-Cheol;Sin Sang-Bae;Sin Ik-Seop;Yang Sin-Hyeok;Jang Ji-Geun;Jang Ho-Jeong
    • Proceedings of the Korean Society Of Semiconductor Equipment Technology
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    • 2006.05a
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    • pp.259-264
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    • 2006
  • ITO 투명전도막은 현재 FPD(flat panel display)소자의 전극으로 사용되고 있다. 특히 근래에 많은 연구가 진행되고 있는 유기발광다이오드(organic light emitting diode: OLED) 소자의 제작에 투명전도막으로 많은 응용이 되고 있다. ITO 를 이용한 디스플레이 소자는 ITO 의 계면 상태와 전기적 특성에 따라 그 특성이 크게 변한다. 본 연구에서는 $O_2$ 플라즈마 처리를 통하여 ITO 투명전도막의 전기적 특성 및 표면상태의 변화에 대하여 조사하고, 이러한 특성 변화에 따라 현재 많은 연구가 진행되고 있는 OLED 소자의 제작에 응용하기 위하여 유기용액을 이용한 접촉각 측정을 통하여 $O_2$ 플라즈마 처리에 따른 ITO 투명전도막과 유기용액의 접착력에 대하여 고찰하였다.

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A Study on Curing of Commercially Available Chines Urushiol (옻칠의 경화에 관한 연구)

  • Kim, Young-Baek;Park, Deok-Soo
    • The Journal of Natural Sciences
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    • v.8 no.2
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    • pp.21-26
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    • 1996
  • Commercially available Chines oriental lacquer was treated to get two fractions, hexane soluble fraction and hexane insoluble fraction. Hexane soluble fraction was subjected to thermal curing process. Films obtained from the lacquer under normal conditions and obtained from thermal curing were compared. The compounds in hexane soluble fraction were copolymerized with 1,6-diisocyanohexane, and toluendiisocyanate(TDI). Films obtained by thermal curing were highly brittle and hydrophobic while the films obtained under normal conditions were hydrophilic. Curing reaction did not occur when oxygen was not available.Some of the major component in the lacquer was isolated by HPLC and UV spectrum of each compound was recorded.

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Evaluation of Anticorrosive Performance of Organic Coatings Subjected to Cyclic Wet-dry Exposure (흡 .탈수 반복 환경하에서의 유기도막의 방식성 평가)

  • 박진환;이근대;전호환
    • Journal of Ocean Engineering and Technology
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    • v.18 no.1
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    • pp.75-79
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    • 2004
  • Organic coatings are widely used to control of the corrosion of a steel structure. The water in coatings may cause the coatings to swell, leading to the degradation of the coatings. In addition, water affects the permeation of oxygen and other corrosive agents, and consequently, the presence of such substances at coating-metal interface promotes corrosion of the metal substrate. In this study, the anticorrosive properties of 4 types of coating, such as epoxy-epoxy, epoxy-urethane, urethane-epoxy, urethane-urethane, were evaluated. The evaluation tests were conducted under cyclic water-absorption/desorption conditions, consisting of alternative exposure to diluted 0.001M-LiCl(a$H_2O$≒1) and concentrated 10M-LiCl(a$H_2O$≒0.15). The anticorrosive performance of coatings was found to decrease in the order of urethane-urethane > urethane-epoxy > epoxy-epoxy coating.

Dissolution Resistance Property of Modified Asphalt Waterproofing Sheet Coated with Polyamide Film by SEM-EDX Analysis (폴리아마이드 필름이 코팅된 개량 아스팔트 방수시트의 SEM-EDX 분석을 통한 유기용제 저항성 확인)

  • An, Ki-Won;Yoo, Jae-Yong;Oh, Sang-Keun
    • Journal of the Korea Institute of Building Construction
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    • v.17 no.5
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    • pp.437-444
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    • 2017
  • In the composite waterproofing method in which a polyurethane coating waterproofing material is applied on the modified asphalt waterproofing sheet, the organic solvent is diluted in the coating waterproofing material in order to improve the workability. However, since the organic solvent is not volatilized before the curing of the polyurethane coating waterproofing material, the organic solvent causes dissolution of asphalt layer, thereby causing oil leakage. As a result, a polyamide film having a high dissolution resistance property was laminated on modified asphalt sheet, and through testing the dissolution resistance was visually confirmed and quantitative analysis of the polyamide film by SEM-EDX analysis was also used to confirmed the dissolution resistance of the polyamide film.

The Properties of PLED by Pre-treatment (Plasma and heat treatment) on ITO surface (ITO 표면 전처리에 따른 PLED 소자의 특성 연구)

  • Gong, Su-Cheol;Sin, Sang-Bae;Sin, Ik-Seop;Yu, Byeong-Cheol;Lee, Hak-Min;Jeon, Hyeong-Tak;Park, Hyeong-Ho;Jang, Ho-Jeong
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2007.11a
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    • pp.89-90
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    • 2007
  • 본 연구에서는 ITO/PEDOT:PSS/PFO-poss/LiF/Al 구조를 갖는 고분자 유기발광다이오드(PLED)를 제작하여 ITO 투명 전도막의 전처리 효과가 유기발광 다이오드의 특성에 미치는 영향에 대하여 조사하였다. 최적의 전처리 조건을 찾기 위하여 다양한 플라즈마 처리 조건에 다른 ITO 투명전도막의 표면형상의 변화와 전기적 특성을 관찰하였다. 또한 ITO 투명전도막에 플라즈마 처리와 열처리를 실시하여 PLED 소자를 제작하고 전기 광학적 특성을 조사하여 ITO 투명 전도막의 전처리가 소자의 특성에 미치는 영향을 조사하였다.

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Preparation of UV Cured Hard Coating Films Using Polysilazane on Plastic Substrates (플라스틱 기재 위에 polysilazane을 이용한 UV 경화형 하드코팅 도막 제조)

  • Yang, Jun Ho;Cho, Yong Ju;Song, Ki Chang
    • Korean Chemical Engineering Research
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    • v.56 no.2
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    • pp.162-168
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    • 2018
  • UV-curable hard coating solutions were prepared by mixing organic or inorganic polysilazane with urethane acrylate. UV-cured hard coating films were also obtained by flow coating, subsequently UV-curing on polymethylmethacrylate (PMMA) sheets. The effect of types and amounts of polysilazane was investigated on properties of obtained coating films. As a result, the coatings obtained by using organic polysilazane showed a high hydrophobic property with water contact angle of $95^{\circ}$, pencil hardness of 7H and high transparency of 92% in the visible wavelength range. On the other hand, the PMMA sheets made by using inorganic polysilazane exhibited a pencil hardness of as high as 8H, good adhesion to the substrate and water contact angle of $82^{\circ}$.

Electrochemical Characteristics of Marine Anti-Corrosive Coating under Shear Flows (전단유동 하에서의 선박용 방식도막의 전기화학 특성)

  • Park, Hyun;Park, Jin-Hwan;Ha, Hyo-Min;Chun, Ho-Hwan;Lee, In-Won
    • Journal of the Society of Naval Architects of Korea
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    • v.43 no.2 s.146
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    • pp.268-274
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    • 2006
  • Analysis has been made of the anti-corrosive property of organic coating under the shear stress of the flow by means of AC impedance method. Marine anti-corrosive painted panels were placed in the water channel with varying flow rate, thereby experiencing varying flow shear stress on the surfaces. The velocities of the salt water were ranged from 1.48 to 5.2 m/s and the coating thickness of from $70{\mu}m\;to\;140{\mu}m$. For all coating thicknesses investigated, the poorer anti-corrosive property and the lower adhesion strength have been found for the higher shear stress. It has been found that the shear stress accelerates the aging of organic marine coatings.

Characteristics of Heat Curable Polyorganosiloxane Coating Materials (페닐기 함유 열경화성 폴리유기실록산 코팅제 특성)

  • Lee, Jin Hyouk;Kang, Doo Whan;Kang, Ho-Jong
    • Polymer(Korea)
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    • v.39 no.3
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    • pp.499-505
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    • 2015
  • Polyorganosiloxane having controlled cross-linking density and phenyl group content were prepared by dimethyldimethoxysilane (DMDMS), methyltrimethoxysilane (MTMS) and phenyltrimethoxysilane (PTMS). The effect of cross-linking density and phenyl group content on the physical properties of siloxane resin and its coated film have been invetigated. Si-NMR results confirmed that synthesized siloxane resins have equivalent D $T^{Me}$ $T^{Ph}$ structures according to applied mole ratios of DMDMS, MTMS and PTMS. Polyorganosiloxane having higher cross-linking density with high phenyl content showed the high molecular weight and increasing phenyl content resulted in higher refractive index as well as better thermal stability. Cross-linking density is more important factor than phenyl content to obtain higher pencil hardness of coated film on the glass. Our results concluded that even polyorganosiloxanes having similar siloxane structures show different physical properties as function of cross-linking density and phenyl content in polyorganosiloxane.