• Journal of Korean Society of Environmental Engineers
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• v.22 no.10
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• pp.1893-1904
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• 2000

Nitrogen compounds are one of the major pollutants which cause eutrophication problems of the river or lake and red tides problems of the ocean. Currently available technologies for the removal of nitrogen compounds are mostly biological treatment. However, biological treatment is only effective for the wastewater which contains low concentration of nitrogen compounds. Leachate from solid waste landfill or industrial wastewater which contains high concentration of nitrogen can not be effectively treated by most of the currently available biological treatment technologies. With this connection. the objective of this study is to examine the applicability of ammonia stripping technology for the removal of high concentration of ammonia nitrogen compounds of the leachate from solid waste landfill. It can be concluded that ammonia stripping technology which was placed before the biological treatment process was very effective for the removal of high concentration of ammonium compounds. The chemical cost for the ammonia stripping was 16 percent higher than MLE process, so other methods like sludge recycling are needed for the reduction of operation cost. Further details are discussed in this paper.

• Journal of the Korea Organic Resources Recycling Association
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• v.14 no.1
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• pp.139-150
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• 2006

Landfilling is one of the most widely used methods for the final disposal of solid wastes. Landfilled wastes are degraded by residing microorganisms and the microbial degradation is affected by many factors such as moisture, oxygen, pH, alkalinity, sulphate, nutrient, temperature, and so on. Especially among these factor, oxygen and moisture within aerobic landfill play a major role in microbial degradation. In this study, 1) the effects of oxygen on the velocity of waste degradation and 2) the effect of moisture on the degradation of municipal solids waste (MSW) in aerobic condition were investigated. It was found that the BOD and CODcr concentration from the leachate of aerobic lysimeters dropped faster by 80 days after the start of the test compared to those from the anaerobic lysimeters. To see the effect of moisture, four aerobic lysimeters filled with MSW and four different levels of moisture (20, 30, 40, and 50%) were installed. From this test, higher moisture in MSW produced higher $CO_2$ concentration, meaning moisture was effective for the microbial degradation. thus, we concluded that higher moisture level in the aerobic landfill might help early-stabilization microbial degradation.

• Journal of the Korea Organic Resources Recycling Association
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• v.12 no.3
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• pp.76-85
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• 2004

Anaerobic decomposition of municipal solid waste (MSW) had potential adverse impacts such as the production of methane and long-term post closure on human health and the environment. It was demonstrated that aerobic degradation of MSW resulted in the reduction of a methane yield and the enhancement of stabilization of MSW. Excavated solid wastes were both aerobically and anaerobically treated in order to evaluate the effects of air injection on the stabilization of landfill site. The municipal solid waste (MSW) samples were excavated from a 10-year old landfill (operation period: 1991. 11~1994. 11), Jeonju, Korea. Excavated municipal solid wastes are primarily composed of soils and vinyl/plastics. For the two aerobic simulated lysimeters, the levels of $O_2$ ranged 1.6~23.1% and the levels of $CO_2$ ranged 1.5~15.1%, which confirmed the aerobic decomposition. Aeration did prevent methane formation. For the anaerobic simulated lysimeter, the $CO_2$ rose as $O_2$ was consumed and low levels of CH4 were produced. The pH levels ranged from 7.7 to 8.9 for anaerobic lysimeter and from 7.3 to 8.5 for aerobic lysimeters. As expected, aerobic treatment proved to enhance the removal of biodegradable materials in the excavated solid wastes when monitoring the concentration of BOD, COD, $NH_4-N$, and $NO_3-N$ in the leachate.

• Journal of Korea Soil Environment Society
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• v.2 no.1
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• pp.99-107
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• 1997

In this study, a series of batch-scale tests were conducted to optimize the design parameters for the application of soil washing techniques to the hydrophobic organic compounds(HOCs)-contaminated soil and to find the effective methods for the recovery of surfactants from washing effluent by using solvent. Several nonionic surfactants (polyoxyethylene oleyl ester) and sophorolipid were applied to the artificially contaminated soil (4,000 mg n-dodecane/kg dry soil). The effects of washing time, concentration of surfactant solution, dilution ratio, and temperature on washing efficiencies were examined. Hydrophile-liphophile balance (HLB) number was proven to be one of the important parameters for soil washing. The HLB numbers of OA-5 and sophorolipid are too low to form a stable soil-water emulsion. They showed very low washing efficiencies less than 10e1o. If HLB number is in the proper range to form a stable soil-water emulsion, surfactant having higher solubility for HOCs shows higher washing efficiency. OA-14 having higher HLB number than OA-9 formed more stable soil-water emulsion. But its washing efficiency was about 20% due to a lower molar solubility ratio (MSR) than OA-9. OA-9, which forms a stable soil-water emulsion and has comparatively high sotubility for HOCs, showed about 60% washing efficiency by itself. To recover anthracene effectively from OA-9 washing effluent by using benzene as an organic solvent, desirable temperature and pH were $30^{\circ}C$ and 2, respectively.

• Journal of Life Science
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• v.15 no.1 s.68
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• pp.9-14
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• 2005

Batch enzymatic hydrolysis of egg yolk protein by protease was carried out at laboratory scale coupled to an ultrafiltration module. Effect of ethanol concentrations on the performance of enzymatic hydrolysis was studied to determine the optimum condition of recovery of hydrolysate. The enzymatic hydrolysis was conducted stepwise with following conditions, $50^{\circ}C$, pH 10.0 and pH 6.5. Ethanol concentration was changed from 10 to $40\%$ (w/w). As ethanol concentration was increased, the recovery yield of total solid and protein in enzymatic hydrolysate was also increased. The content of sialic acid and protein in hydrolysate was independent of ethanol concentration. We also investigated the effect of ethanol concentration on the performance of ultrafiltration. As the concentration of ethanol in yolk protein was increased, the recovery yield of product was increased. Ultra­filtration of egg yolk protein hydrolysate was conducted to increase the content of sialic acid. Four ultrafiltation modules were used in this study, and we evaluated the performance of the UF modules. When Amicon module was used, the recovery percentage of total solid in retentate was $6.0\%$, which is the highest among the modules used. In spite of the difference in the recovery yield of total solid, the purity of sialic acid in retentate was about $2.0\%$, which was 5 times higher than that in feed. It was concluded that the recovery yield and the purity of sialic acid did not correlate with the types of modules and the size of MWCO.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.8 no.3
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• pp.627-631
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• 2007

The factors affecting on sludge sedimentation are reported as F/M ratio, ingredient, composition of influent substrate, dissolved oxygen concentration, temperature, pH, filamentous bacteria and SRT. Aeration tank applying Bacillus sp. has an important role for maintaining the dominant microorganism species to make steady progress for spore growth affecting sedimentation. This research aims to investigate the affecting factor for the sedimentation in B3 system and RABC system with aeration tank applying tapered aeration. Extracellular polymeric substances(EPS), protein and carbohydrate can be produced for the extreme condition, that is down to 0.2 mg/L of dissolved oxygen in the aeration tank. This research found out the relation between the sedimentation and the EPS production, especially the ratio of protein/carbohydrate. The spore of Bacillus sp. was formed at the low DO then microorganisms produced EPS. The results showed that the production of EPS was 109.95 mgEPS/gSS at 1.6 mg/L of DO, however it was 131.77 mgEPS/gSS at 0.5 mg/L of DO. The sedimentation was affected by protein content in EPS and the ratio of protein and carbohydrate. The settleability of sludge was not affected by the ratio of protein/carbohydrate in B3 process, meanwhile settleability was affected by the ratio of it in RABC process, respectively.

• Journal of Energy Engineering
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• v.25 no.3
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• pp.104-113
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• 2016

This study analyzes correlation between methane gas production and injection of food waste water to motivate to expand renewable energy as a way of GHG (Green House Gas) mitigation to achieve the national GHG target proposed for the climate agreement in Paris last year. Pretreatment of food waste water was processed with pH 6 at $35^{\circ}C$ and used the fixed-bed upflow type reactor with the porous media. As a result of operation of pilot-scaled bioreactor with food waste water, the methane gas production was 6 times higher than the methane gas production of control group with rain water. The average production of methane was $56{\ell}/day/m^3$ which is possible to produce $20m^3$ of methane in $1m^3$ of landfill. As a way of energy source, when it is applied to the landfill over $250,000m^3$, it is also able to achieve financial feasibility along with GHG reduction effect. GHG reductions of $250,000m^3$ scale landfill were assessed by registered CDM project and the annual amount of reductions was 40,000~50,000 $tCO_2e$.

• Applied Chemistry for Engineering
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• v.3 no.4
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• pp.730-738
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• 1992

Filtration characteristics according to membrane materials were studied In the ultrafiltration of anaerobic digestion broth as a post treatment method. A series of resistances for different membranes were quantitatively assessed on the basis of the resistance-in-series model. Flux behavior observed with the digestion broth was irrelevant to initial water permeabilities of each membrane. The fluoro polymer membrane showed the most significant improvement of flux with increase of cross-flow velocity, which suggests that the cake layer formed on this membrane is more weakly attached to the membrane surface than those on the other membranes. Flux reduction during longtime running was attrib-used to the polarization layer resistance ($R_p$) as well as the fouling layer resistance($R_f$). Continuous increase of $R_p$ may reflect the variation in the characteristics of cake layers, which could result from size, shape, and structure changes due to lysis and growth of biomass. Hydrophilic cellulosic membrane had a much lower fouling tendency than hydrophobic polysulfone membrane. The depressurization method induced a small increase in flux of $5-10L/m^2/h$. During washing and cleaning, filtrability of each membrane was rapidly recovered within 15 minutes until a stationary value was reached.

• Korean Journal of Microbiology
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• v.36 no.4
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• pp.279-284
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• 2000

Simultaneous reduction of Cr(VI) and degradation of phenol was observed in batch and bench-scale continuous stirred tank reactors using Rhodococcus sp. CP01 isolated from leachate. The strain CP01, which was capable of utilizing phenol as a sole source of carbon and energy, completely reduced added hexavalent chromium (0.25 mM) to its trivalent form during 60 hr batch assay under optimal conditions (pH 7.0 and 1,000 mg/L of phenol concentration). The rates of Cr(VI) reduction and phenol degradation were estimated as 4.17 $\mu$M Cr(VI) and 38.4 mg phenol.$L^{-1}{\cdot}hr^{-1}$, respectively. The continuous culture experiment was conducted for 46 days using synthetic feed containing different levels of chromate (0.0625 to 0.25 mM) and phenol(1,000 to 4,000 mg/L). With a hydraulic retention time of 100 hr, Cr(VI) reduction efficiency was mostly 100% for influent Cr(VI) and phenol concentrations of 0.125 mM and 3,000 mg/L, respectively. During quasi-steady-state operation, specific rate of Cr(VI) reduction was calculated as 0.34 mg Cr(VI).g $protein^{-1}{\cdot}hr^{-1}$ which was comparable to reported values obtained by using glucose as growth substrate. The results suggest the potential application of biological treatment for detoxification of wastewater contaminated simultaneously with Cr(VI) and pheonol.

• Journal of Korean Society of Environmental Engineers
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• v.33 no.11
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• pp.834-846
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• 2011

The objective of this study is to development of IDFIS system, that are consisted of hydrocyclone, rapid flocculation and inclined settler with chitosan coagulant. As the results of Jar test, a chitosan optimum dosage of 40 mg/L for river sediment, and 5 mg/L for tunnelling wastewater sediment, which these conditions leaves of residual turbidity of less than 5 NTU. Because of the effectiveness of chitosan in removing turbidity was independent on pH, the operation of IDFIS system would be simple. The synthesized turbidity was made with clay particles, river sediment, river suspended sediment, and tunnelling wastewater sediment. Results indicate that the mean overall removal efficiency of turbidity, SS, COD and TP were 98%, 99%, 85% and 95%, respectively. Chitosan is very efficient in removing turbidity in the entire turbidity range examined. IDFIS system would have possibility with compact design, because of the increase of floc size favours the floc settling speed and reduces the settling time.