• Title/Summary/Keyword: 운전 pH

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Effect of operational pH on anaerobic hydrogen fermentation of food waste (음식폐기물의 혐기성 수소 발효시 운전 pH의 영향)

  • Lee, Chae-Young;Lee, Se-Wook
    • Journal of the Korea Organic Resources Recycling Association
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    • v.19 no.3
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    • pp.73-78
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    • 2011
  • The pH is one of the most important factors affecting metabolism pathway and activity of hydrogen producing bacteria. The effect of operational pH on anaerobic hydrogen fermentation of food waste was evaluated at mesophilic condition. In this batch experiment, the initial pH was 8.0 and the operational pH was controlled at 4.7~7.0 by the addition of 5N KOH solutions. At the operational pH of 4.7, the lag phase and the maximum hydrogen production were 47.9h and 534.4 mL, respectively. The lag phase and the maximum hydrogen production were decreased as the operational pH increased. At the operational pH of 7.0, the lag phase and the maximum hydrogen production were 4.2 h and 213.8 mL, respectively.

A Technique for Reactor Water Chemistry to Reduce Radioactivity Build up (방사능 누적 저감을 위한 원자로 수질관리)

  • Lee, Yong-Woo;Kim, Hong-Tae
    • Journal of Radiation Protection and Research
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    • v.14 no.2
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    • pp.37-44
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    • 1989
  • An improved water chemistry technique was studied to reduce radioactivity build-up in reactor coolant system. The technique is convering the current coordinated lithium-boron chemistry regime to the elevated lithium chemistry regime in order to maintain high pH. Correlations between reactor coolant pH and radioactivity build-up were analized by using pH data from domestic PWRs. Consequently, it was founded that high pH chemistry was moer effective for radioactivity build-up reduction than current chemistry regime. This fact had revealed that much portion of reactor coolant corrosion products were nickel ferrite rather than magnetite, and that pH value ranging 7.0-7.4 was appropriate for high-pH chemistry operation.

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Variation of Optimum Operational pH in Partial Nitritation (암모니아 폐수의 부분아질산화에서 최적 운전 pH의 변동)

  • Bae, Wookeun;Khan, Hammad
    • Journal of Korean Society of Environmental Engineers
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    • v.38 no.5
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    • pp.228-235
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    • 2016
  • Nitrite accumulation is essential for constructing an anammox process. As the pH in the reactor exerts a complicated and strong influence on the reaction rate, we investigated its effects upon treatment of an ammonic wastewater (2,000 mgN/L) through modeling and experiment. The modeling results indicated that the reaction stability is strongly affected by pH, which results in a severe reduction of the 'stable region' of operation under alkaline environments. On a coordinate of the total ammonia nitrogen (TAN) concentration vs. pH, the maximal stable reaction rates and the maximal nitrite accumulation potentials could be found on the 'stability ridge' that separates the stable region from the unstable region. We achieved a stable and high ammonia oxidation rate (${\sim}6kgN/m^3-d$) with a nitrite accumulation ratio of ~99% when operated near the 'stability ridge'. The optimum pH that can be observed in experiments varies with the TAN concentrations utilized, although the intrinsic optimum pH is fixed. The direction of change is that the optimum operational pH falls as the TAN concentration increases, which is in excellent accordance with the observations in the literature. The optimum operational pH for 95% nitritation was predicted to be ~8.0, whereas it was ~7.2 for 55% partial nitritation to produce an anammox feed in our experimental conditions.

Desirable pH of Slurry in the Desulfurization Absorber for a 200 MW Anthracite Power Plant (200 MW급 무연탄 발전용 탈황 흡수탑에서 적정 슬러리pH)

  • Choi, Hyun-Ho;Yoo, Hoseon
    • Plant Journal
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    • v.16 no.1
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    • pp.38-43
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    • 2020
  • In this study, Seochon Thermal Power Plant No.1 for anthracite coal was tested to find the proper operation range of limestone slurry pH in the absorber tower which can be operated continuously in compliance with the Air Quality Preservation Act and Seocheon Thermal Power Division's internal regulation, sulfur dioxide average emission regulation. When operating the sulfur dioxide concentration [ppm] in the combustion gas flowing into the desulfurization absorption tower at 370, 400, 460 and 550 ppm while the main operating elements such as the flow rate of the combustion gas were fixed, the proper slurry pH Were 4.4, 4.5, 4.8 and 5.1, respectively. Therefore, it is recommended to operate with the correlation equation, RpH=0.004×Cin+2.93 derived using sulfur dioxide and the appropriate slurry pH.

Effect of pH on Hydrogen Fermentation of Food Waste with Livestock Wastewater (음식물쓰레기 수소발효 시 pH 영향 및 축산폐수와의 혼합 발효)

  • Jang, Hae-Nam
    • Journal of the Korea Organic Resources Recycling Association
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    • v.24 no.4
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    • pp.5-9
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    • 2016
  • In the modern industrial society, huge amount of organic wastes have exceeded the society's self-cleaning capability, caused pollution of the whole environment, including water quality, soil, and the air, and become a big burden of waste treatment. Moreover, the emission of green house gases brought by the continual combustion of fossil fuels has facilitated the global warming. The simultaneous effect of initial and operational pH on $H_2$ yield was expressed using mathematical equation and optimized. The optimal initial and cultivation pH was 7.50 and 6.01, respectively. Addition of livestock wastewater to food waste substantially decreased the amount of alkali requirement and also improved the $H_2$ fermentation performance.

PWR 원전 1차계통 방사선량 감소를 위한 수질관리

  • 송명재;정양근
    • Proceedings of the Korean Nuclear Society Conference
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    • 1995.10a
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    • pp.248-253
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    • 1995
  • 원자력발전소 1차 냉각재내 방사선량을 감소시키기 위한 효과적인 기술로 평가된 고pH기술을 국내에 적용하기 위해 고리1호기를 대상 발전소로 선정하여 11, 12 주기에 modified pH control mode를 이용한 고pH 운전을 수행하고 constant pH control mode로 운전한 10주기의 운전 결과와 비교, 평가함으로서 그 영향을 분석하였다. 종합 평가 결과, 고pH수질관리 기술을 적용함에 따라 1차 냉각재내와 증기발생기 수실내 선량은 평균적으로 약 20 ∼ 30% 정도 감소하였으며 일정 기간동안의 감소추세를 거친 후 안정화단계에 진입하게 될 것으로 평가되었다.

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Evaluation of Primary Coolant pH Operation Methods for the Domestic PWRs (국내 PWR의 일차냉각재 pH 운전방법의 평가)

  • Paek, Seung-Woo;Na, Jung-Won;Kim, Yong-Eak;Bae, Jae-Heum
    • Nuclear Engineering and Technology
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    • v.24 no.1
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    • pp.52-62
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    • 1992
  • Radioactive nuclides deposited on out-of-core surface after the radiation in the core by the transport of corrosion products (CRUD) through the primary coolant system in PWR which is the major plant type in Korea, are leading sources of radiation exposure to plant maintenance personnel. Thus, the optimal chemistry operation method is required for the reduction of radiation exposure by the corrosion products. This study analysed the actual water chemistry operation data of four operating domestic PWRs. And in order to evaluate the coolant chemistry operation data, a computer code which can calculate the activity buildup in the various chemistry conditions of PWR coolant was employed. Through the analysis of comparison between the activity buildup of actual water chemistry operation mode and that of assumed Elevated Li operation mode calculated by the computer code, it was found that the out-of core radioactivity can be reduced by diminishing the deposition of corrosion products on the core in case that the Elevated Li operation mode is applied to the coolant chemistry operation of PWR. And the higher coolant pH operation was shown to have the advantage of the reduction of out-of-core activity buildup if the integrity of system structural materials and fuel cladding is guaranteed.

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일체형원자로 SMART의 수화학 설계 특성

  • 최병선;김주평;조봉현;이영진;이두정
    • Proceedings of the Korean Nuclear Society Conference
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    • 1998.05a
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    • pp.411-416
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    • 1998
  • 출력운전 동안 원자로 냉각재의 정화 없이 운전하는 SMART원자로의 수화학 설계 요건을 정립하기 위하여 핵연료 피복관 및 계통재질의 부식을 최소화하고 부식 생성물의 방사화에 의한 방사선 준위의 상승을 억제하기 위한 수화학 운전 변수에 대한 정성적인 분석을 시도하였다. 원자로냉각재 의 pH 제어 계통을 구성하는 재질의 부식에 따른 건전성, 부식생성물의 거동 및 원자로 냉각재의 방사선 준위 측면에서 수화학 설계 요건이 적절한지의 여부를 살펴보았다 분석 결과, 원자로냉각재의 pH 제어는 암모니아를 이용하므로 높은 pH(= 9.5∼10.6)에서 운전이 가능하며, 계통재질의 부식을 최소화하며 방사선 준위의 상승을 억제할 수 있었다. 또한 SMART 증기발생기 튜브에 사용된 titanium 합금은 주어진 운전 조건하에서 Inconel-600보다 내 부식성이 매우(약 12 배) 우수하였다.

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Experimental Study on Cooling Performance of Multi-Heat Pump by Indoor-Unit Combination (실내기 조합에 따른 3실형 열펌프의 냉방성능 실험연구)

  • Kwon, Young-Chul;Chun, Chong-Keun;Park, Youn-Chang;Ko, Kok-Won;Seo, Dong-Nam
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.9 no.6
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    • pp.1487-1493
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    • 2008
  • In order to investigate the cooling capacity of multi-heat pump applying an inverter compressor, the experiment on the cooling performance characteristics of heat pump with 3 indoor units was performed under the cooling standard and cooling low-temperature conditions. The system data were measured by the psychrometric calorimeter. The operation characteristics and the behavior of the cooling cycle of the heat pump with 3 indoor units were understood from the cooling capacity, COP, and P-h diagram by indoor-unit combination. The operating load and performance of the multi-heat pump depends on the indoor-unit combination. The cooling capacity and COP of the low temperature condition were larger than those of the standard one. Also the cycle was analyzed by using P-h diagram.

Experimental Study on Heating Performance by Operation Combination of Heat Pump with 3 Indoor-Units (3실 열펌프의 운전조합에 대한 난방성능 실험연구)

  • Kim, Ju-Hyung;Kim, Ki-Young;Kwon, Young-Chul;Park, Seung-Chul
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.14 no.9
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    • pp.4197-4203
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    • 2013
  • In order to investigate the heating performance of multi-heat pump applying an inverter compressor, the experiment on heat pump with 3 indoor units was performed under the heating standard and heating low-temperature conditions. The performance data of heat pump with 3 indoor units were measured by the multi-psychrometric calorimeter. The operation characteristics and the behavior of the refrigerant cycle of the heat pump with 3 indoor units were understood from the heating capacity, heating COP, and P-h diagram by indoor-unit combination. The present experimental results show that the operating load and performance of the multi-heat pump depends on the indoor-unit combination. The heating capacity and heating COP of the low temperature condition were smaller than those of the standard one. Also the refrigerant cycles on indoor-unit combination were analyzed by using P-h diagram.