• Title/Summary/Keyword: 용해성

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Solubility of Hydrogen Sulfide and Methane in Ionic Liquids: 1-Ethy-3-methylimidazolium Trifluoromethanesulfonate and 1-Butyl-1-methylpyrrolidinium Trifluoromethanesulfonate (1-Ethyl-3-methylimidazolium trifluoromethanesulfonate와 1-Butyl-1-methylpyrrolidinium trifluoromethanesulfonate 이온성 액체에 대한 황화수소와 메탄의 용해도)

  • Lee, Byung-Chul
    • Korean Chemical Engineering Research
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    • v.54 no.2
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    • pp.213-222
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    • 2016
  • Solubility data of hydrogen sulfide ($H_2S$) and methane ($CH_4$) in two kinds of ionic liquids with the same anion: 1-ethyl-3-methylimidazolium trifluoromethanesulfonate ([emim][TfO]) and 1-butyl-1-methylpyrrolidinium trifluoromethanesulfonate ([bmpyr][TfO]) are presented at pressures up to about 30 MPa and at temperatures between 303 K and 343 K. The gas solubilities in ionic liquids were determined by measuring the bubble point pressures of the gas + ionic liquid mixtures with various compositions at different temperatures using a high-pressure equilibrium apparatus equipped with a variable-volume view cell. The $H_2S$ solubilities in ionic liquid increased with the increase of pressure and decreased with the increase of temperature. On the other hand, the $CH_4$ solubilities in ionic liquid increased significantly with the increase of pressure, but there was little effect of temperature on the $CH_4$ solubility. For the ionic liquds [emim][TfO] and [bmpyr][TfO] with the same anion, the solubility of $H_2S$ as a molality basis was substantially similar, regardless of the temperature and pressure conditions as a molar concentration basis. Comparing the solubilities of $H_2S$ and $CH_4$ in the ionic liquid [emim][TfO], the solubilities of $H_2S$ were much greater than those of $CH_4$. For the same type of ionic liquid, the solubility data of $H_2S$ and $CH_4$ obtained in this study were compared to the solubility data of $CO_2$ from the literature. When compared at the same pressure and temperature conditions, the $CO_2$ solubility was in between the solubility of $H_2S$ and $CH_4$.

Fibrinolytic Enzyme Activity of Extract from Camellia japonica L. (동백나무 추출물의 혈전용해 효소활성)

  • Lim, Chae-Young;Lee, Sook-Young;Pyo, Byeong-Sik;Kim, Sun-Min
    • Korean Journal of Medicinal Crop Science
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    • v.14 no.4
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    • pp.195-201
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    • 2006
  • The fibrinolytic activities of soluble proteins extracted from young leaves of Camellia japonica L. were studied. Fibrinolvity activity of extract from partitions of C. japonica L. showed 1.6-2.0 times higher than plasmin used as positive control. The fibrinolytic enzyme was confirmed directly from young leaves of C. japonica L. by a fibrin Plate and fibrin zymography. The protein was composed of a single polypeptide and its apparent molecular weight was found to be 45 kDa, as judged by SDS-polyacrylamide gel electrophoresis. The optimum pH and temperature for the fibrinolytic activity were pH 5.5 and $30^{\circ}C$, respectively. Also, the fibrinolytic activity was clearly inhibited by PMSF and TLCK, suggesting that it is a member of the trypsin-like serine protease. All these results suggest the protease is a fibrinolytic enzyme belong to a family of trypsin-like serine protease.

Selective Metal ion Transport of PET Non-woven Fabric Supported Carrier-Facilitated Transport Membrane (PET 부직포를 매트릭스로 이용한 Carrier-Facilitated Transport Membrane의 금속이온 투과성)

  • 김용일;마석일
    • Proceedings of the Korean Fiber Society Conference
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    • 2002.04a
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    • pp.462-465
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    • 2002
  • 물에 용해되어 있는 금속이온의 분리를 위한 선택성이 있는 분리 막의 개발은 환경오염이 날로 심각해지고 있는 오늘날에 환경오염의 개선, 에너지절약, 자원의 재활용 등 문제를 해결함에 있어서 아주 중요한 작용을 하게 될 것이다. 물에 용해되어 있는 금속이온을 선택적으로 분리하기 위해 일반적으로 캐리어(carrier)를 함유한 Carrier-Facilitated Transport Membrane (CFM)을 이용하게 되는데, 이 방면에 대한 연구는 주로 유기 상에 용해되어 있는 캐리어를 microporous한 필름에 지지하게 하는 방식으로 만들어진 Supported Liquid Membrane (SLM) 혹은 Elusion Liquid Membrance (ELM)의 개발에 대한 팽대한 연구가 이루어 졌다(1). (중략)

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Physical Properties of Granule Prepared by Ginseng Extracts and Selected Forming Agents (다양한 부형제 첨가에 따른 인삼분말 과립차의 물리적 특성)

  • Hur, Sang-Sun;Kim, Il-Chool
    • Journal of the Korean Applied Science and Technology
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    • v.35 no.3
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    • pp.683-694
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    • 2018
  • The ginseng extract was dried and added forming agents using lactose, glucose and arabic gum to enhance convenience and consumer acceptability. As the addition of lactose increased, the absorption of ginseng granule decreased and the solubility tended to increase as the amount of glucose added decreased. The amount of solubilized saponin from the ginseng granules was affected more by the addition amount of ginseng concentrate than by the kind and amount of the forming agents added. Absorption and solubility tended to increase with increasing amount of arabic gum, and there was no significant difference in color change(p<0.05). The optimal mixing ratio of ginseng granules according to addition of forming agents was 10% of ginseng concentrate, 80% of lactose, 5% of glucose and 5% of arabic gum.

Dissolution of vanadium pentoxide using microwave digestion system for determination of vanadium by ICP-AES (ICP-AES로 바나듐 측정을 위한 마이크로파 용해 장치를 이용한 오산화바나듐 용해)

  • Choi, Kwang-Soon;Park, Yang-Soon;Kim, Yeon-Hee;Han, Sun-Ho;Song, Kyu-Seok
    • Analytical Science and Technology
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    • v.23 no.6
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    • pp.511-517
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    • 2010
  • Dissolution procedure of vanadium pentoxide, which is widely used as a catalyst for production of sulfuric acid or an oxide reaction of the numerous organic compounds, was investigated. Reagent of vanadium pentoxide was completely dissolved in aqua regia-$H_2O_2$-HF solution, but plate type of vanadium pentoxide sample was not clearly dissolved with mixed acids. Thus, in order to establish the dissolution procedure for plate type of vanadium pentoxide, the solubility of vanadium pentoxide was investigated through comparison of acid treatment-fusion and microwave digestion methods. The optimized acid for dissolution of vanadium compound was found to be mixing acids of aqua regia, $H_2O_2$ and HF. Acid-fusion and microwave digestion methods have a similar property in the solubility of vanadium compound, but the latter was more quick and convenient procedure. The content of vanadium pentoxide was found to be $97.9{\pm}0.9%$ using an inductively coupled plasma atomic emission spectrometer after dissolution of a sample with the microwave digestion system.

Effect of Surfactant Molecules on the Aqueous Solubility of two PAHs (새로운 계면활성제들에 의한 두 PAH의 수중 용해도 증가)

  • 이진희;박재우
    • Journal of Korea Soil Environment Society
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    • v.5 no.1
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    • pp.65-73
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    • 2000
  • Surfactants have been extensively considered for decontamination of the subsurface polluted with hydrophobic organic compounds. In order to investigate the effect of molecular structures on the solubilization of hydrophobic organic compounds, solubility enhancement of two PAHs in solutions of three different surfactants-conventional, dianionic, and gemini. The batch experimental results showed that the gemini was the most effective and the dianionic was the least, indicating that organic carbon content of the surfactants was the major factor which determines the sorption capacity of surfactant aggregates in water, unlike some of the previous reports.

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Fibrinolytic Activities and Effects of Gamma-Irradiated on Seeds from Coix lacryma-jobi L. Carthamus tinctorius L. and Malva verticillata L. (율무, 홍화, 아욱종자의 혈전용해 효소활성 및 감마선 조사의 영향)

  • Kwon Su-Jung;Lim Chae-Young;Kim Jae-Sung;Park Min-Hee;Lee Sook-Young
    • KSBB Journal
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    • v.21 no.1 s.96
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    • pp.20-27
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    • 2006
  • The fibrinolytic activities of soluble proteins extracted from seeds of Coix lacryma-jobi L., Carthamus tinctorius L. and Malva venicillata L. were studied. Fibrinolytic activity of extract from C. lacryma-jobi L. showed 1.3 times higher than plasmin used as positive control. The fibrinolytic enzyme was confirmed and extracted directly from seed of C. lacryma-jobi L. by a fibrin zymography. The protein was composed of a single polypeptide and its apparent molecular weight was found to be 7.8 kDa, as judged by SDS-polyacrylamide gel electrophoresis. The effect of temperature for the proteolytic enzyme activity were stabilized above $50^{\circ}C$ and then dramatically decreased. Also, the enzyme activity was clearly inhibited by APMSF, PMSF and TPCK, suggesting that it is a member of the chymotrypsin-like serine pretense. In addition, effects of gamma-irradiated on seed of each plants were revealed that 8 Gy and 64 Gy were higher than others. This result shown that gamma-irradiation of seeds were capable to increase the fibrinolytic activity. All these results suggest the pretense is a fibrinolytic enzyme belong to a family of chymotrypsin-like serine pretense.