• Title/Summary/Keyword: 용융 탄산염

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Enhancement of Mechanical Strength Using Nano Aluminum Reinforced Matrix for Molten Carbonate Fuel Cell (용융탄산염 연료전지를 위한 나노 알루미늄을 이용한 강화 매트릭스의 기계적 강도 증진)

  • Kim, Hyung-Suk;Song, Shin-Ae;Jang, Seong-Cheol;Park, Dong-Nyeock;Ham, Hyung-Chul;Yoon, Sung-Pil;Oh, Seong-Geun;Han, Jong-Hee;Kim, Sung-Hyun
    • Journal of Hydrogen and New Energy
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    • v.23 no.2
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    • pp.143-149
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    • 2012
  • 용융탄산염 연료전지 상용화를 위해서 40,000 시간이상 장기 운전이 가능해야 한다. 장기운전을 위해 크랙 발생이 적고 기계적 강도가 높은 강화 매트릭스의 개발이 절실히 요구되고 있다. 본 연구에서는 $LiAlO_2$에 알루미늄 나노입자를 첨가하여 매트릭스의 기계적 강도를 향상시키는 연구를 수행하였다. 나노 알루미늄 첨가 $LiAlO_2$ 그린 시트를 수소 분위기에서 열처리한 결과, 공기 분위기에서 열처리한 매트릭스에 비해 기계적 강도가 1.5배 증가함을 확인하였다. 이는 환원분위기에서 열처리를 할 경우, 알루미늄의 입자간의 소결으로 인한 neck이 형성 되어 $LiAlO_2$ 입자 간에 다리를 만들어주는 효과가 나타나 매트릭스의 기계적 강도가 크게 증진되었으리라 판단된다.

Thermodynamic Analysis on Hybrid Molten Carbonate Fuel Cell - Turbo Expander System for Natural Gas Pressure Regulation (용융탄산염연료전지와 터보팽창기를 이용한 천연가스 정압기지의 열역학적 분석)

  • Sung, Taehong;Kim, Kyung Chun
    • Journal of the Korean Institute of Gas
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    • v.18 no.2
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    • pp.28-34
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    • 2014
  • In the natural gas pressure regulation station, high pressure natural gas is decompressing using pressure regulation valves. Waste pressure occurred in the pressure regulation process can be recovered through adopting turbo expanders. However, in the waste pressure recovery process, Joule Thompson effect causes below $0^{\circ}C$ and this low temperature freezes outside land of pipeline or generates methane hydrate in the pipeline which can block the pipeline. Therefore, turbo expander systems are accompanying with a boiler for preheating natural gas. Molten carbonate fuel cell (MCFC), one of the high temperature fuel cell, can use natural gas as a direct fuel and is also exhausting low emission gas and generating electricity. In this paper, a thermodynamic analysis on the hybrid MCFC-turbo expander system is conducted. The fuel cell system is analyzed for the base load of the hybrid system.

Study on the NiAl Coating for Corrosion Resistance of Stainless Steel in Molten Carbonate Salt (용융탄산염에 대한 스테인레스강의 내식성 향상을 위한 NiAl 피복에 관한 연구)

  • Hwang, Eung-Rim;Gang, Seong-Gun
    • Korean Journal of Materials Research
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    • v.7 no.1
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    • pp.76-80
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    • 1997
  • '4 NiAl coating process was applied on 316 stainless steel to retard the corrosion of the wet- seal area of separator for the molten carbonate fuel cell. The Nit11 phasc on the stainless steel substrate could be formed by pre-coating with Ni, plated with A1 and ther, heat treated at $800^{\circ}C$ for 3 hr in $H_2/N_2$ gas atmosphere. The corrosion protection behavior of YiAl coating layer was stuilied under immersion condition in molten cxhonate salt($62^{m}/_{o}Li_2CO_3-38^{m}/_{o}/K_{2}CO_{3}$) at $650^{\circ}C$. The NiAl coating layer ticposited on the AiSi 316 stainless steel had high corrosion resistance in molten carbor. dte salt. The corrosion resistance of XiAl (~~jpoared to be associated with the .A1 oxide formed on the surface of coating layer.

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