• Journal of the Korean Ceramic Society
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• v.40 no.10
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• pp.1015-1020
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• 2003

The Corrosion behavior of the matrix of the $\rho$-alumina bonded alumina vibrated castable was, on the basis of Jabsen's theory, elucidated by use of the Kingery's reaction mechanism. Corrosion of the matrix during induction period was controlled by the molecular diffusion. The temperature dependence of activation process is well established by the Arrhenius plots. The difference of Ca concentration between slag and interface is 23.2%, which causes a driving force of the materials transfer. The extent of the corrosion of the matrix is more deeper than that of the sintered mullite, but the corrosion mechanism can be well employed as the reaction mechanism proposed by the Kingery. The life time of the castable may be well estimated by the corrosion mechanism of Kingery.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2021.05a
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• pp.114-115
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• 2021

The research team conducted a series of studies to use CGS as fine aggregate for concrete. In this paper, through the adiabatic temperature rising test, CGS' hydration heating performance and its usability as a mass concrete hydration heating agent were reviewed. According to the analysis, the maximum temperature of the mix of OPC 100 was 53.7℃, and the temperature of CGS 50% was 45.2℃, which was 8.5℃ lower than the OPC 100.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2021.11a
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• pp.120-121
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• 2021

This study examines the performance of the pre-treatment process system to use CGS, a by-product generated in IGCC, as a concrete fine aggregate for construction materials, on the quality of CGS fine aggregate. As a result of the analysis, it is judged that the quality of fine aggregates of CGS can be improved at both density, absorption rate, and 0.08mm body passage amount after the hydroelectric screening process using water as a medium during the pretreatment process. It is believed that it can be used as basic data for national standard certification of CGS fine aggregates in the future.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2021.11a
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• pp.170-171
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• 2021

This study compared the characteristics of the newly established JISA 5011-5 coal gasification slag fine aggregate with the characteristics of CGS generated in Korean IGCC through microscopic analysis. As a result of the study, similar results to K_CGS and J_CGS were found

• Proceedings of the Korean Institute of Building Construction Conference
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• 2021.11a
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• pp.182-183
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• 2021

In this study, This is the result of thermal characteristics analysis to suggest an efficient method of using coal gasification slag(CGS) of byproduct from integrated gasification combined cycle(IGCC). In Specific Heat characteristics, CGS and CS showed similar values. Isothermal Conduction Calorimetry showed that the hydration reaction of cement was retarded when CGS was used. Therefore, it is expected that CGS will be used as an efficient alternative to reducing the hydration heat of mass concrete as a functional aggregate combination.

• Resources Recycling
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• v.21 no.5
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• pp.65-71
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• 2012

The equilibrium distribution of bismuth and lead between molten PbO-$SiO_2$ slag and bismuth phase was studied in the temperature range of $775^{\circ}C$ to $850^{\circ}C$ in a MgO crucible. The oxygen partial pressure of atmosphere was controlled by $P_{CO2}/P_{CO}$ ratio. The value of $(%PbO)_{slag}/[%Pb]_{metal}$ increased with increasing $SiO_2$ content of slag, and the value of $(%Bi_2O_3)_{slag}/[%Bi]_{metal}$ decreased with increasing $SiO_2$ content of slag. The concentration of Pb in metal increased with increasing temperature. These experimental results agreed well with the thermodynamic prediction.

• Applied Chemistry for Engineering
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• v.20 no.6
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• pp.638-645
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• 2009

High alumina refractory used in a coal gasifier was analyzed and the degradation mechanism by molten slag was investigated. The depth of refractory severely damaged by slag varied between 12~40 mm, including the adhered slag layer. The sample also showed the cracks formed in parallel to the slag/refractory interface. The degree of degradation varied with the micro-structures in the refractory. Fused alumina grains showed the uneven boundary and pore formation just along the edges, while the tablet alumina showed the slag penetrated between sintered alumina around which the formation of Al-Fe phase was observed. Calcium aluminate cements were not observed at the high temperature zone near the slag/refractory interface, probably due to dissolution into molten slag. Around large grains of alumina, rod shape alumina, which appeared to be recrystallized during cooling, were observed, and large pores were also formed around those grains. Therefore, in high alumina refractories, hot molten slag dissolves the bonding phase and rod-shape alumina phase is recrystallized upon cooling. During this process, cracks are developed due to structural change, and the degradation occurs by physical causes such as structural spalling.

• Proceedings of the Korean Radioactive Waste Society Conference
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• 2009.06a
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• pp.120-121
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• 2009

• Proceedings of the KWS Conference
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• 2009.11a
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• pp.15-15
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• 2009

최근 컨테이너선은 점차 대형화되고 있으며, 이에 따라 선체의 외판 상부의 철판 두께도 최대 80mm 까지 설계되고 있다. 블록 외판의 수직 맞대기 용접의 경우 고능률 용접기법인 Electro Gas Weldig(이하 EGW)이 적용되고 있으나, 극 후판의 경우, 기존의 한 개의 전극만으로는 적용 가능한 두께 범위의 한계가 있어 수직 맞대기 용접의 용접생산을 향상시키기 위해 2개의 전극을 사용하는 탄뎀 EGW 기법에 의한 시공법이 고려되었다. 탄뎀 EGW 기법의 시공법에 관한 보고서는 국내외에서 많이 발표되어져 왔다. 하지만 실선 적용에 있어 두께 80mm, 길이 2M 이상의 철판을 안정적으로 용접하기 위한 장애요소는 용접 중 적절한 슬래그의 배출 조절이다. 두개의 용접 와이어를 동시에 공급할 때 발생하는 슬래그를 균형있게 배출하지 못하는 경우 용융, 금속 상부에 적층되는 슬래그의 양이 증가하게 되고, 아크는 불안해져서 전극팁에의 슬래그 부착, 전극 팁의 발열 등에 의한 요인들이 송급을 불안하게 하여 연속 용접이 어려워진다. 본 연구에서는 탄뎀 EGW 기법을 실제로 현업에 적용하기 위해서는 안정적인 슬래그 배출에 착안하여 동당금의 형상에 따라 슬래그의 배출 성능을 확인하고 형상별 전류, 전압 파형을 측정하고, 파형 결과에 따라 아크 안정성을 평가함으로서 탄뎀 EGW 용접기법에 적정한 동당금을 설계한 결과를 소개하고자 하였다.

• Journal of the Korean Recycled Construction Resources Institute
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• v.7 no.2
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• pp.101-108
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• 2019

This study is analysis of the utilization as a concrete fine aggregate on CGS, a by-product of Integrated coal gasification combined cycle(IGCC). That is, in KS F 2527 "Concrete aggregate," properties of 1~12times to CGS were evaluated, focusing on quality items corresponding to natural aggregate sand(NS) and melted slag aggregate sand(MS). As a result, the distribution of grain shape, safety and expansion were all satisfied with KS standards by physical properties, but the quality was unstable at 7~12times of water absorption ratio and absolute dry density. The particle size distribution was unstable due to asymmetry distribution of coarse particles, and particles were too thick for 7~12times. The passing ratio of 0.08mm sieve was also out of the KS standard at part factor of 7~12times, but chloride content, clay contents, coal and lignite were all satisfactory. Meanwhile, chemical composition was satisfactory except for $SO_3$ in 1~6times, and content and amount of harmful substances were all within the specified value except for F in 7~12times. As a result of SEM analysis, the surface quality and porosity were 7~12times more than 1~6times, and it was the quality was degraded. Therefore, it is necessary to reduce the quality deviation by using separate measures in order to utilize it as concrete aggregate in the future, and if it is premixed with fine quality aggregate, it will contribute positively to solve aggregate supply shortage and utilize circulation resources.