• Title/Summary/Keyword: 오염물질

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Primary Productivity of Phytoplankton in the Shallow and Hypertrophic River (Seonakdong River) (서낙동강에서 식물플랑크톤의 1차 생산성)

  • Jeon, Seung-Il;Cho, Kyung-Je
    • Korean Journal of Ecology and Environment
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    • v.37 no.1 s.106
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    • pp.57-63
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    • 2004
  • Primary productivity of phytoplankton was measured by $^{14}C$ method from January to October of 1996 in Seonakdong River. This river was a highly productive freshwater showing the euphotic depth of 1.4 m in August and 2.1 m in the remaining season. Chlorophyll-a concentrations of phytoplankton ranged from 67 ${\mu}g\;L^{-1}$ to 894 ${\mu}g\;L^{-1}$ and showed the great increase in August. Maximum specific productivity was 2.1 ${\sim}$4.3 mg C mg $chl-a{-1}\;hr^{-1}$ and occurred above 0.4m depth. In photosynthesis-irradiance relation, photoinhibition or photosynthetic suppression of phytoplankton occurred clearly in the cold seasons, while phytoplankton (mainly Microcystis aeruginosa and its relatives) in August did not show any symptom of the photosynthetic inhibition against the high irradiance. The specific productivity of phytoplankton was eventually dependant upon incident irradiance to show the linear correlation with received irradiance infield, and the areal productivity of phytoplankton upon chlorophyll-a standing crops. In the downstream of the Nakdong River, phytoplankton productions have linearly increased since the estuarine barrage construction to reflect the gradual eutrophication in the estuarine area. Average chlorophyll-a increase of 10 ${\mu}g\;chl-a\;L{-1}$ absolutely corresponded to the primary production acceleration of 30 mg C $m^{-2}\;day^{-1}$ on the annual basis.

Runoff Analysis for Weak Rainfall Event in Urban Area Using High-ResolutionSatellite Imagery (고해상도 위성영상을 이용한 도시유역의 소강우 유출해석)

  • Kim, Jin-Young;An, Kyoung-Jin
    • Journal of Korean Society of Environmental Engineers
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    • v.33 no.6
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    • pp.439-446
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    • 2011
  • In this research, enhanced land-cover classification methods using high-resolution satellite image (HRSI) and GIS in terms of practicality and accuracy was proposed. It aims for understanding non-point pollutant origin/loading, assessment the efficiency of rainfall storage/infiltration facilities and sounds water-environment management. The result of applying enhanced land-cover classification methods to the urban region verifies that roof and road area are including various vegetations such as roof garden, flower bed in the median strip and street tree. This accounts for 3% of total study area, and more importantly it was counted as impervious area by GIS alone or conventional indoor work. The feasibility of the method was assessed by applying to rainfall-runoff analysis for three weak rainfall in the range of 7.1-10.5 mm events in 2000, Chiba, Japan. A good agreement between simulated and observed runoff hydrograph was obtained. In comparison, the hydrograph simulated with land-use parameters by the detailed land-use information of 10m grid had an error between 31%~71%, while enhanced method showed 4% to 29%, and showed the improvement particularly for reproducing observed peak and recession flow rate of hydrograph in weak rainfall condition.

Fundamental Properties of Low Strength Concrete Mixture with Blast Furnace Slag and Sewage Sludge (고로슬래그미분말 및 하수슬러지를 활용한 저강도 콘크리트의 기초적 물성)

  • Kwon, Chil Woo;Lim, Nam Gi
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.17 no.3
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    • pp.136-144
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    • 2013
  • In this study, in order to establish a plan that will enable safe use of renewable resources such as diverse industrial by-products and urban recycled materials, we conducted experiments that focused on flow, bleeding, compressive strength and environmental pollution evaluation to evaluate the material properties of low strength concrete using BFS and SS. In the case of low strength concrete using BFS and SS, blending of at least BFS 6000 within a 30% range regardless of the type of sand used was found to be the most effective approach for improving the workability by securing the minimum unit quantity of water, restraining the bleeding ratio and establishing compressive strength by taking account of the applicability at the work site. In particular, in view of the efficient use of SS, the optimal mixing condition was found to be the mixing of BFS 8000 with in the 30% range, not only for improving the workability restraining the bleeding ratio and establishing the compressive strength but also for application to the work site. Further, the results of tests on hazardous substance content and those of elution tests conducted on soil cement using SS indicated that all values satisfied the environmental standards without any harmful effects on the surrounding environment.

Control Measures for Air Pollutant Emissions from In-Use Light-Duty Diesel Vehicles Regarding their Emission Control Technologies (배출허용기준 대응기술을 고려한 국내 소형 경유 운행차의 대기오염물질 관리 방안)

  • Lee, Taewoo;Park, Hana;Park, Junhong;Jeon, Sangzin;Kim, Jeongsoo;Choi, Kwangho
    • Journal of Korean Society for Atmospheric Environment
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    • v.30 no.4
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    • pp.327-338
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    • 2014
  • The objective of this study is to enhance the effectiveness of Korean Inspection and Maintenance (I/M) program. Three main tasks are: to measure pollutant emissions of in-use light-duty diesel vehicles (LDVs); to evaluate the validity of existing smoke control scheme for low-smoke-emitting vehicles, which have diesel particulate filters, DPF, to meet stringent Euro-5 emission limits; and to assess the necessity and the benefit of $NO_x$ inspection, which is not involved in current I/M program. We measured second-by-second smoke, particulate and gaseous emissions of 27 LDVs using opacity smoke meter, photo-acoustic soot sensor, and portable emissions measurement system, respectively, under the Korean I/M test driving cycle, KD-147. We find that the DPF plays a key role in controlling soot, which can be considered as black carbon contained in particulate matter. Thus, from an I/M perspective, we believe smoke inspection strategies for Euro-5 diesel vehicles should be more focused on the capability of detecting DPF malfunctions or failures, in order to keep DPF properly functional. Fleet averaged distance-specific $NO_x$ emissions are consistently higher than corresponding emission limits, and the values are similar among pre-Euro-3, Euro-3, and Euro-4 vehicle fleets. These findings indicate that the $NO_x$ inspection should be incorporated into current I/M program in order to manage urban $NO_x$ emissions. This research allows the Korean I/M program keep pace with developments in vehicle technologies, as well as the increased emphasis on $NO_x$ with respect to air quality and human health.

Estimation of Personal Exposure to Air Pollutants for Workers Using Time Activity Pattern and Air Concentration of Microenvironments (시간활동 양상과 국소환경 농도를 이용한 근로자의 유해 공기오염물질 노출 예측)

  • Lee, Hyunsoo;Lee, Seokyong;Lee, Byoungjun;Heo, Jung;Kim, Sunshin;Yang, Wonho
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.24 no.4
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    • pp.436-445
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    • 2014
  • Objectives: Time-activity studies have become an integral part of comprehensive exposure assessment and personal exposure modeling. The aims of this study were to estimate exposure levels to nitrogen dioxide($NO_2$) and volatile organic compounds(VOCs), and to compare estimated exposures by using time-activity patterns and indoor air concentrations. Methods: The major microenvironments for office workers were selected using the Time-Use Survey conducted by the National Statistical Office in Korea in 2009. A total of 9,194 and 6,130 workers were recruited for weekdays and weekends, respectively, from the Time-Use Survey. It appears that workers were spending about 50% of their time in the house and about 30% of their time in other indoor areas during the weekdays. In addition, we analyzed the time-activity patterns of 20 office workers and indoor air concentrations in Daegu using a questionnaire and time-activity diary. Estimated exposures were compared with measured concentrations using the time-weighted average analysis of air pollutants. Conclusions: According to the time-activity pattern for the office workers, time spent in the residence indoors during the summer and winter have been shown as $11.12{\pm}2.20$ hours and $12.48{\pm}1.77$ hours, respectively, which indicates higher hours in the winter. Time spent in the office in the summer has been shown to be 1.5 hours higher than in the winter. The target pollutants demonstrate a positive correlation ($R^2=0.076{\sim}0.553$)in the personal exposure results derived from direct measurement and estimated personal exposure concentrations by applying the time activity pattern, as well as measured concentration of the partial environment to the TWA model. However, these correlations were not statistically significant. This may be explained by the difference being caused by other indoor environments, such as a bar, cafe, or diner.

A Field Survey on the Characteristics of Air Pollutants Emission from Commercial Charcoal Kiln (숯가마에서 발생하는 대기오염물질의 배출특성에 관한 현장조사 연구)

  • Park, Seong-Kyu;Choi, Sang-Jin;Kim, Jin-Yun;Park, Gun-Jin;Hwang, Ui-Hyun;Lee, Jeong-Joo;Kim, Tae-Sik
    • Journal of Korean Society for Atmospheric Environment
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    • v.29 no.5
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    • pp.601-614
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    • 2013
  • The commercial charcoal kiln was projected the largest source of biomass burning sector in Korea. Commercial charcoal kiln was operated to emit air pollutants into the air without any air pollution prevention equipment. The object of this field survey was to understand characteristics of air pollutants concentration and emission factors and to provide preliminary data for effective processor from oak charcoal manufacturing process. As result of field survey, TSP, $PM_{10}$ and $PM_{2.5}$ concentration from charcoal kiln were 400~37,000 $mg/m^3$. These values were over the 100 $mg/m^3$ in TSP, this value was effluent quality standard of Clean Air Conservation Act. The average concentration of CO, $SO_2$ and TVOC were 2~5%. 0~110 ppm and 820~10,000 ppm respectively. The emission factors were 42.4 g-PM/kg-oak in TSP, 40.3 g-PM/kg-oak in $PM_{10}$, 38.2 g-PM/kg-oak in $PM_{2.5}$, 182.5 g-CO/kg-oak, 1.0 g-NO/kg-oak, $SO_2$ 0.2 g-$SO_2/kg$-oak and 104.4 g-TVOC/kg-oak. The part of commercial charcoal kiln had air pollution prevention equipment but it was difficult to work properly. Much wood tar excreted in exhaust emissions from oak charcoal manufacturing process. This wood tar was cause of many troubles sticking in the air pollutant prevention equipment. For handling particulate matters and gaseous air pollutants from oak charcoal manufacturing process in biomass burning, air pollutant prevention equipment design and management needs preprocessor for removal wood tar.

Effect of Barley Mixtures on Forage Production and Soil Characteristics in Dry Riverbed of Ansancheon (안산천에서 청보리 혼파조합이 사초 생산성과 토양 특성에 미치는 영향)

  • Kim, Jong-Duk;Ko, Ki-Hwan;Kwon, Chan-Ho
    • Korean Journal of Organic Agriculture
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    • v.21 no.4
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    • pp.701-710
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    • 2013
  • This experiment was carried out to determine the forage production and soil characteristics in mixtures of barley and annual legumes at riverbed. The dry matter (DM) and total digestible nutrients (TDN) in barley and hairy vetch mixture were higher compared to other mixtures. Barley, single cropping was the highest in DM content. Comparing different mixtures, barley and crimson clover mixture was higher than other mixtures in DM contest. The crude protein (CP) content of barely and hairy vetch mixture was highest, but ether extract (EE) and TDN contents were lower than other mixtures. Barely and hairy vetch mixture significantly removed organic matter and phosphorus from riverbed through forage production (P<0.05). The total nitrogen (TN) of barley and hairy vetch mixture was highest because of high nitrogen fixation in riverbed soil. Single barley was highest in organic matter (OM) of soil. Comparing different mixtures, barley and crimson clover mixture was higher than other mixtures in OM contest. The available P2O5 of soil in barley and crimson clover mixture and barley and rape mixture were higher than others, and that of barley and hairy vetch was lower than other mixtures. The barely and hairy vetch mixture was highest in cation exchange capacity (CEC) content. Therefore barley and hairy vetch mixture is more suitable in forage mixtures because of high forage production and protein, and reduction of soil phosphorus in riverbed.

Analysis of Trace Copper Metal at The Electrode Consisting of Carbon Nanotube using Stripping Voltammetry (벗김전압전류법을 이용한 카본나노튜브 전극에서의 구리 분석)

  • Choi, Chang-Kun;Jung, Young-Sam;Kim, Nack-Joo;Pak, Dae-Won;Chung, Kun-Yong;Kim, Lae-Hyun;Kwon, Yong-Chai
    • Korean Chemical Engineering Research
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    • v.50 no.5
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    • pp.933-937
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    • 2012
  • In the present study, we evaluate the sensitivity and optimal stripping voltammetry (SV) conditions of copper (Cu), which is one of the main trace heavy metals inducing the environmental contamination, using carbon nanotube (CNT) electrode. In addition, the reaction mechanism of stripping reaction of Cu is investigated. The electrochemical analyses such as squarewave stripping voltammetry (SWSV) and linear scan voltammetry (LSV) are used for the evaluations. As a result of that, the best SWSV conditions like squarewave amplitude of 15 mV, frequency of 60 Hz, deposition potential of -1.0V vs. Ag/AgCl and deposition time of 200s are determined with the measured Cu sensitivity of $1.824{\mu}A/{\mu}M$. As a driving force affecting the stripping reaction of Cu, surface reaction is more dominant one than diffusion. These results are compared with other reference results and it is confirmed that our suggested CNT electrode gives rise to better Cu sensitivity result than other references.

Wear Behaviors of WC-CoCr and WC-CrC-Ni Coatings Sprayed by HVOF (고속화염 용사법으로 제조된 WC-CoCr 코팅과 WC-CrC-Ni 코팅의 내마모 거동)

  • Lee, Seoung Soo
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.21 no.6
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    • pp.204-211
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    • 2020
  • The high-velocity oxy-fuel (HVOF) thermal spraying coating technique has been considered a promising replacement for traditional electrolytic hard chrome plating (EHC), which caused environmental pollution and lung cancer due to toxic Cr6+. In this paper, two types of cermet coatings were prepared by HVOF spraying: WC-CoCr and WC-CrC-Ni coatings. The produced coatings were analyzed extensively in terms of the micro-hardness, porosity, crystalline phase and microstructure using a hardness tester, optical microscopy, X-ray diffraction, and scanning electron microscopy (including energy dispersed spectroscopy (EDS)), respectively. The wear and friction behaviors of the coatings were evaluated comparatively by reciprocating sliding wear tests at 25 ℃, 250 ℃, and 450 ℃. The results revealed correlations among the microstructures, metallic binder matrixes, porosities, and wear performance of the coatings. For example, WC-CoCr coatings showed better sliding wear resistance than WC-CrC-Ni coatings, regardless of the test temperature due to the more homogeneous microstructure, Co-rich, Cr-rich metallic binder matrix, and lower porosity.

Economic Evaluation of a Crush-screen Hybrid Pretreatment Process for Waste Vinyl (폐비닐의 파쇄/선별 융합 전처리 공정의 경제성 평가)

  • Seo, Su Been;Cho, Il Ho;Yun, Hyun Pyo;Kang, Seo Yeong;Kim, Hyung Woo;Lee, See Hoon
    • Clean Technology
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    • v.25 no.4
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    • pp.289-295
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    • 2019
  • Though the usage of vinyls and plastics produced from fossil fuels has been increasing in the world, the eco-friendly domestic disposal or recycling of waste vinyls has to be executed because the migration or importation of waste vinyls or waste plastics are globally prohibited. Even though the eco-friendly domestic disposal or recycling of waste vinyls and waste plastics should be developed, promising eco-friendly recycling methods are few because there are extraneous substances in waste vinyls and waste plastics. Also, conventional incineration and landfill methods result in secondary contamination and then increase disposal costs. Therefore, the selective elimination of extraneous substances or other materials included in waste vinyls and waste plastics could make valuable recycling or reuse possible. In particular, the novel hybrid process in which crushing and screening are simultaneously conducted in a rotary kiln type reactor can domestically maximize the material recycling or reuse. In this study, the feasibility study for a crushing/screening hybrid process developed in Korea was performed and evaluated in case of thermal recycling (TR) and material recycling (MR). The effect of various subsidies on economic efficiency was especially evaluated by means of domestic recycling plans. The incentive revenues from waste vinyl recycling and the incineration share of waste vinyls affected the net present values and internal rate of returns of the hybrid process.