• Clean Technology
• /
• v.14 no.3
• /
• pp.184-192
• /
• 2008

Fluoride-type cleaning agents such as 2,2,2-trifluoroethanol (TFEA) and hydrofluoroethers (HFEs) do not destroy ozone in the stratosphere and have low global warming potential compared to hydrofluorocarbons(HFCs) and hydrochlorofluorocarbons (HCFCs). Especially, HFEs which have no flash point are paid attention as next generation type of cleaning agents for chlorofluorocarbons (CFCs) since they are safe in handling and have excellent penetration ability compared to hydrocarbon cleaning agents with low flash point. Here, the physical properties and cleaning abilities of fluoride-type cleaning agents such as TFEA, HFE-7100, HFE-7200, HFE-476mec, HFE-449mec-f, AE-3000 and AE-3100E and silicide-type cleaning agents such as trifluoroetoxytrimethylsilane (TFES) and hexamethyldisilazane (HMDS) were measured and compared with those of ozone destruction substances such as CFC-113 and 1,1,1-trichloroethane. They were also compared with toxic methylene chloride (MC) and isopropyl alcohol (IPA) which are now being used as an alternative cleaning agents. As a result, TFEA and HFEs had lower cleaning ability for removal of various soils compared to chloride-type cleaning agents, but they showed excellent cleaning ability fur fluoride-type soils. TFES and HMDS also showed excellent cleaning ability for silicide-type soils.

• Proceedings of the KSME Conference
• /
• 2004.11a
• /
• pp.1276-1281
• /
• 2004

Nowadays CFCs and HCFCs refrigerants are restricted because it cause depletion of ozone layer. Accordingly, this experiment apply the ammonia gas and not CFCs and HCFCs for refrigerant to study the performance characteristic from the superheat control and improve the energy efficiency from the high performance. The condensing pressure of refrigeration system is increased from 15.0bar to 16bar by 0.5bar and superheat temperature is increased from $0^{\circ}C$ to $10^{\circ}C$ by $1^{\circ}C$ at each condensing pressure. As the result of experiment, when the superheat temperature is $0^{\circ}C$ at each condensing pressure, the refrigeration system has the high performance.

• Proceedings of the KSME Conference
• /
• 2004.04a
• /
• pp.1334-1339
• /
• 2004

Nowadays CFCs and HCFCs refrigerants are restricted because it cause depletion of ozone layer. Accordingly, this experiment apply the $NH_3$ gas and not CFCs and HCFCs for refrigerant to study the performance characteristic from the superheat control and improve the energy efficiency from the high performance. The condensing pressure of refrigeration system is increased from 14.5bar to 16bar by 0.5bar and superheat temperature is increased from $0^{\circ}C$ to $10^{\circ}C$ by $1^{\circ}C$ at each condensing pressure. As the result of experiment, when the superheat temperature is $1^{\circ}C$ at each condensing pressure, the refrigeration system has the high performance.

• Proceedings of the Korea Air Pollution Research Association Conference
• /
• 2002.04a
• /
• pp.327-328
• /
• 2002

대기권 오존의 90%정도가 성층권의 15-30km 부근에 존재한다. 성층권에 존재하는 오존은 대류권에서 생성된 오존과 화학식은 동일하지만 대기 중의 생성과정과 유발시킬 수 있는 피해 정도가 다르다. 성층권 오존은 직접적으로 생체 DNA 변성, 피부암 등을 야기 시키는 자외선을 흡수ㆍ차단시켜 주므로 인간 및 동ㆍ식물에게는 중요한 기체이다. 이러한 성층권 오존이 인간에 의해 배출되는 오염물질 염화불화탄소(CFCs), 할로겐 가스등에 의해 파괴되고 있다. (중략)

• Korean Journal of Air-Conditioning and Refrigeration Engineering
• /
• v.16 no.8
• /
• pp.756-761
• /
• 2004

Since the use of CFC and HCFC refrigerants are to be restricted due to the depletion of ozone layer, this experiment applies the NH$_3$ gas to study the performance characteristics from the superheat control for improving the energy efficiency. The experiments are carried out for the condensing pressure of refrigeration system from 14.5 bar to 16.0 bar by 0.5 bar and for superheat temperature from $0^{\circ}C$ to 1$0^{\circ}C$ by 1$^{\circ}C$ at each condensing pressure. As a result of experiment, when the superheat temperature is 1$^{\circ}C$ at each condensing pressure, the refrigeration system has the highest performance.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
• /
• v.17 no.12
• /
• pp.1132-1138
• /
• 2005

Recently, production and use of freon substances are restrained due to depletion of ozone layer and global warming. In this aspect of environmental problems, the best solution is to use the natural refrigerant such as ammonia. Thus, this study is to find the optimal operating conditions by comparing the performance between the shell and tube type and shell and disk type heat exchangers using the ammonia refrigerant, and to verify the superiority of the shell and disk type heat exchanger that is not used in field of refrigeration and air conditioning. Finally, this study shows that the shell and disk type heat exchanger is applicable to the ammonia refrigeration system, and this system minimizes the refrigerant charge and installation space.

• Proceedings of the Korea Air Pollution Research Association Conference
• /
• 2003.11a
• /
• pp.374-375
• /
• 2003

산업화에 따른 화석 연료의 연소, 기타 오염원에 의하여 생성되는 대류권의 에어로졸은 전 지구적인 평균값으로 볼 때, 약 -0.5 W/$m^2$의 복사강제력(radiative forcing)을 갖는 것으로 보고되고 있다. 이러한 음의 복사강제력은 일산화탄소, 염화불화탄소, 메탄 등과 같은 온실기체에 의한 양의 복사강제력을 상쇄시키는 정도보다 더 클 수 있다고 추측되고 있어 지속적으로 관리가 필요한 것으로 보인다. 본 연구는 국내에서 청정지역으로 꼽히고 있는 제주도 고산 측정소와 한라산 1100 고지 지역에서 에어로졸 시료를 채취하고, 고도에 따라 에어로졸 조성이 어느 정도 차이를 보이는지, 그리고 고도에 따라 에어로졸 성분의 특성이 어떻게 다른지를 비교하기 위한 목적으로 수행되었다. (중략)

• Korean Chemical Engineering Research
• /
• v.55 no.5
• /
• pp.704-710
• /
• 2017

Although the desalination technique using gas hydrate formation is at a development stage compared to the commercially well-established reverse osmosis (RO), it still draws attention because of its simplicity and moderate operational conditions especially when using refrigerants for guest gases. In this study, DFT (density functional theory)-based molecular modeling was employed to explain the energetics of the gas hydrate formation using HFC (hydrofluorocarbon) and HCFC (hydrochlorofluorocarbon) refrigerants. For guest gases, R-134a, R-227ea, R-236fa, and R-141b were selected and three cavity structures ($5^{12}$, $5^{12}6^2$, and $5^{12}6^4$) composed of water molecules were constructed. The geometries of guest gas, cavity, and cavity encapsulating guest gas were optimized by molecular modeling respectively and their located energies were then used for the calculation of binding energy between the guest gas and cavity. Finally, the comparison of binding energies was used to propose which refrigerant is more favorable for the gas hydrate formation energetically. In conclusion, R-236fa was the best choice in terms of thermodynamic spontaneity, less toxicity, and low solubility in water.

• Journal of the Korean Data and Information Science Society
• /
• v.26 no.6
• /
• pp.1409-1416
• /
• 2015

The change of temperature influences on the various aspect, especially human health, plant and animal's growth, economics, industry, and culture of the country. In this article, the autoregressive error (ARE) model has been considered for analyzing the monthly temperature data at the Suwon monitoring site in Korea. In the ARE model, five meteorological variables, four greenhouse gas variables and five pollution variables are used as the explanatory variables for the temperature data set. The five meteorological variables are wind speed, rainfall, radiation, amount of cloud, and relative humidity. The four greenhouse gas variables are carbon dioxide ($CO_2$), methane ($CH_4$), nitrous oxide ($N_2O$), and chlorofluorocarbon ($CFC_{11}$). And the five air pollution explanatory variables are particulate matter ($PM_{10}$), sulfur dioxide ($SO_2$), nitrogen dioxide ($NO_2$), ozone ($O_3$), and carbon monoxide (CO). Among five meteorological variables, radiation, amount of cloud, and wind speed are more influence on the temperature. The radiation influences during spring, summer and fall, whereas wind speed influences for the winter time. Also, among four greenhouse gas variables and five pollution variables, chlorofluorocarbon, methane, and ozone are more influence on the temperature. The monthly ARE model explained about 43-69% for describing the temperature.

• Journal of Korean Society for Atmospheric Environment
• /
• v.19 no.3
• /
• pp.307-314
• /
• 2003

The sonolytic decomposition of chlorofluorocarbon (CFC 113) and several alternative compounds, such as HCFC 225ca, HCFC 225cb, and HFC 134a, in.aqueous solutions was investigated. The CFC 113 with a high volatility and a low solubility in water was rapidly decomposed with increasing sonication time. The decomposition rates were influenced by the initial concentration of CFC 113, the reaction temperature, and the gas/liquid phase volume ratio but were independant of the pH of solution. The predominant pathway of the decomposition of CFC 113 by sonication was not the oxidation by OH radicals but the pyrolysis with high temperature and pressure inside of the cavitation bubble. The pyrolysis in the cavitation bubble resulted in an almost complete mineralization of CFC 113 with the high efficient formation of inorganic products (Cl$^{[-10]}$ , F$^{[-10]}$ , CO, $CO_2$). The addition of zinc powder on the decomposition of CFC 113 by sonication caused an acceleration of the decomposition. Also, HCFCs and HFC 134a were found to be readily decomposed by the pyrolysis induced from the sonication.