• Title/Summary/Keyword: 염화물 확산 계수

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Time-dependent characteristics of chloride diffusion coefficient of concrete (콘크리트 염소이온 확산계수의 시간 의존적 특성)

  • Choi, Sung;Lee, Kwang-Myong;Shin, Kyung-Joon;Bae, Su-Ho
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.545-548
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    • 2008
  • As the corrosion of reinforcing bar in concrete structures exposed to chloride attack is one of main factors to determine the remaining service life, marine concrete structures have to be designed to protect the chloride penetration. Among the durability design methods such as deterministic method and probabilistic method, design method based on the probabilistic theory has been widely studied. However, the most essential material, data of the material properties related to chloride diffusion, are still insufficient. In this paper, the probabilistic distribution of chloride diffusion coefficients and aging coefficients are derived by the experiment and analysis for the chloride coefficients of concrete containing pozzolans, which are generally used in marine structures.

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Evaluation of Strength and Chloride Diffusion in Concrete with FA Considering Temperature Effect (FA를 혼입한 콘크리트의 온도 영향을 고려한 강도 및 염화물 확산성 평가)

  • Keun-Hyeok Yang;Seung-Jun Kwon
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.11 no.1
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    • pp.62-69
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    • 2023
  • For the nuclear power concrete plant structures in the UAE, it is necessary to consider the deterioration from high sulfate ions in the atmosphere and high chloride ions from the coast. In this study, two strength grade concrete mixture (40 MPa and 27 MPa) and two curing/diffusion temperatures (20 ℃ and 50 ℃) were considered for evaluating the temperature effects on diffusion and strength due to high average temperature above 38 ℃ a year in UAE. When the initial curing temperature was high, the compressive strength increased in high-temperature curing to 7 days, but the strength slightly increased in the 20 ℃ curing condition at 28 days. Regarding diffusion test, unlike the compressive test results, reduced chloride diffusion coefficients were evaluated both in 40 MPa and 27 MPa grade at 28 days. In the case of 91 days of curing, an increase in diffusivity due to high temperature and a decrease in diffusivity due to age effect occur simultaneously. Compared to the results of the curing and diffusion tests at 20 ℃ and 28 days, when the curing and diffusion tests were conducted at 50 ℃ in 91 days, the diffusion coefficients decreased to 76.2 % in 40 MPa grade and 85.4 % in 37 MPa grade with increasing curing period, respectively.

An Experimental Study on Relation between Chloride Diffusivity and Microstructural Characteristics for GGBS Concrete (슬래그 미분말 혼합 콘크리트의 공극구조와 염화물 확산계수와의 관계에 대한 실험적 연구)

  • Kim, Tae-Sang;Jung, Sang-Hwa;Choi, Young-Cheol;Song, Ha-Won
    • Journal of the Korea Concrete Institute
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    • v.21 no.5
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    • pp.639-647
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    • 2009
  • In order to evaluate the durability of reinforced concrete structures under chloride attack from sea water and frost damage, it is important to analyze both the microstructural characteristics of concrete and its diffusion resistance of concrete against chloride ingress. In this study, a relation between micro-pore structures of concrete obtained by the Mercury Intrusion Porosimetry and accelerated chloride diffusivity as well as long term chloride diffusivity were studied for ground granulated blast furnace slag(GGBS) concrete. Different water-cement ratio of 40, 45, 50% and different unit cement concrete of 300, 350, 400 or 450 kg/$m^3$ of the GGBS concrete along with OPC concrete were used and freeze and thawing, and the change in diffusivity and microstructure were observed for both GGBS concrete and damaged GGBS concrete due to rapid freezing and thawing.

Characteristics of Calcium Leaching Resistance for Concrete Mixed with Mineral Admixture (광물질 혼화재를 혼합한 콘크리트의 칼슘용출 저항 특성)

  • Choi, So-Yeong;Choi, Yoon-Suk;Yang, Eun-Ik
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.20 no.4
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    • pp.59-67
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    • 2016
  • Concrete is a very useful construction material for the sealing disposal of hazardous substances. In general, mass concrete is applied to these structures. And, the mineral admixtures are recommended for the long term performance. Calcium leaching could be happened due to the contact with pure water in underground structures. Thus, it is needed to evaluate the resistance of calcium leaching for concrete mixed with mineral admixtures. From the test results, the mineral admixtures are effective to the improvement of long term compressive strength and chloride diffusion coefficient in concrete members. When calcium leaching is happened, however, the reduction of compressive strength and chloride penetration resistance is severe than OPC case, the micro pore distribution is adversely affected. Consequently, when the mineral admixtures are applied to underground structures which is exposed to calcium leaching environment, it is desirable to reduce water-to-binder ratio, to expose after the sufficient pozolanic reaction, and to use BFS than FA.

Chloride Penetration Resistance and UV Properties in Coating Materials Containing Various Slime-Forming Bacteria (슬라임 생성 박테리아를 혼입한 코팅재의 염해 저항성 및 초음파 특성)

  • Kwon, Seung-Jun;Yoon, Hyun-Sub;Yang, Keun-Hyeok
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.5 no.4
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    • pp.395-402
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    • 2017
  • Recently, many researches on crack healing and repairing technique using bacteria which can produce vital-reacted calcite have been proposed. This study is for a basic research on repair material with slime formation through bacteria and deals with durability evaluation for coating materials containing bacteria-forming slime. For the work, 4 types of bacteria (Rhodobacter capsulatus, Rhodopseudomonas palustris, Bacillus thuringiensis, and Bacillus subtilis) and 2 types of nutrient conditions are considered, and several tests covering strength evaluation under sulfate condition, accelerated chloride diffusion, and UV (Ultrasonic Velocity) measurement are performed. Strength improvement in coating materials containing bacteria is evaluated in spite of even exposure to sulfate attack to 7 days. Chloride diffusion coefficient and UV properties are also improved except for the case of Rhodopseudomonas palustris. With resistance of slime to long term exposure and aerobic conditions for bacteria longevity, the proposed bacteria shows an engineering feasibility for repair material of RC structure exposed harsh environment.

Effect of Initial Flexural Crack on Resistance to Chloride Penetration into Reinforced Concrete Members (초기 휨균열이 철근콘크리트 부재의 염화물침투저항성에 미치는 영향)

  • Yang, Eun Ik;Jin, Sang Ho;Kim, Myung Yu;Choi, Yoon Suk;Han, Sang Hun
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.15 no.2
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    • pp.79-87
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    • 2011
  • In this study, the chloride penetration tests were performed for the initially cracked reinforced concrete members. The chloride diffusion characteristics and the critical crack width are compared, and the properties of self-healing are investigated. According to the test results, the chloride penetration resistance was greatly reduced as the surface crack width increased. When the mineral admixtures are added, the chloride penetration resistance of uncracked specimens were effectively increased, however, in case of the blast furnace slag and fly ash, the cracked specimens showed the more reduced resistance than OPC case, inversely. Also, the critical width was $29{\mu}m$, on average, for immersion test. The crack width with $4{\sim}15{\mu}m$ was restored by self-healing, The parts restored by self-healing were seemed to be visually restored, however, the chloride penetration resistance was not restored, perfectly.

Evaluation of Durability Performance of Fly Ash Blended Concrete due to Fly Ash Replacement with Tire Derived Fuel Ash (타이어 고무 애쉬 치환에 따른 플라이애쉬 혼입 콘크리트의 내구성능 성능 평가)

  • Kwon, Seung-Jun;Yoon, Yong-Sik;Park, Sang-Min;Kim, Hyeok-Jung
    • Journal of the Korea Concrete Institute
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    • v.28 no.6
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    • pp.647-653
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    • 2016
  • In the paper, durability performance in FA (Fly Ash) blended concrete is evaluated considering replacement of FA with TDFA (Tire Derived Fuel Ash) from 3.0% to 12%. TDFA is a byproduct from combustion process in thermal power plant, where chopped rubber is mixed for boiling efficiency. This is the 1st study on application of TDFA to concrete as mineral admixture. For the work, concrete samples containing 0.5 of w/b (water to binder) ratio and 20% replacement ratio of FA are prepared. With replacing FA with TDFA to 12%, durability performance is evaluated regarding compressive strength, carbonation, chloride diffusion, and porosity. The results of compressive strength, carbonation, and porosity tests show reasonable improvement in durability performance to 12% replacement of TDFA. In particular, clear decreasing diffusion coefficient is observed with increasing TDFA replacement due to its packing effect. Concrete containing TDFA can be effective for durability improvement when workability is satisfied in mixing stage.

Assessment of Recovery of Chloride Penetration Resistance of Self-healing Cement Mortars Containing Layered Double Hydroxide (이중층수산화물을 혼입한 자기치유 시멘트 모르타르의 염화물 침투 저항성 회복 평가)

  • Kyung Suk, Yoo;Seung Yup, Jang
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.10 no.4
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    • pp.600-608
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    • 2022
  • This study investigates the effect of layered double hydroxide (LDH) on the healing performance of self-healing concrete by assessing the chloride penetration resistance of self-healing cement mortars using electrical chloride ion migration-diffusion test. Test results show that both mortars containing healing materials only and mortars containing healing materials and Ca-Al LDH together mostly had higher migration-diffusion coefficients right after cracking, but the migration-diffusion coefficients decreased more than that of OPC with increasing healing ages, and thus, they yielded higher healing capacities than OPC. Also, mortars containing Ca-Al LDH together with healing materials showed higher reduction of their migration-diffusion coefficients, and thus, higher healing capacities than mortars containing healing materials only. This suggests that as the self-healing product increases on the crack surface, the binding of chloride ions by LDH inside the crack increases.

A Study on the Cover Property of Offshore Reinforced Concrete Structure (내구성 해양 RC 구조물의 철근 피복적정성에 관한 연구)

  • Im, Jung-Soon;Bahng, Yun-Suk;Jo, Jae-Byung
    • Journal of the Korean Society of Hazard Mitigation
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    • v.4 no.3 s.14
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    • pp.73-81
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    • 2004
  • On this study, durability decreasing element caused by salt damage was analyzed elementally and studied with the data of the inside and outside in the country. The design strength and water-cement ratio according to diffusion coefficients of chloride were applied to Fick's diffusion equation. The required over depended on environmental conditions is estimated with endurance period, and the influences on cover according to the transformation of the each parameter were investigated. In consequence, if water-cement ratio decreases and design strength increases, it shows that slowing infiltration velocity of chloride ion can decrease required cover. Especially, it is more effective to use Portland blast-furnace slag cement into high strength concrete in the splash zone environmental conditions in blocking the diffusion of chloride ion. As the result, in the case of the offshore concrete structure needed high durability, it is needed to increase cover($3cm{\sim}8cm$) than minimum standard cover(8cm) according to environmental conditions.