• Title/Summary/Keyword: 염화물 이온 침투 저항성

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Durability of Ultrarapid-Hardening Polymer-Modified Mortar Using Redispersible Polymer Powder (재유화형 분말수지 혼입 초속경 폴리머 시멘트 모르타르의 내구성)

  • 이윤수;주명기;연규석;정인수
    • Journal of the Korea Concrete Institute
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    • v.14 no.5
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    • pp.660-667
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    • 2002
  • The effects of polymer-cement ratio and antifoamer content on the durability of ultrarapid-hardening polymer-modified mortars using redispersible polymer powder are examined. As a result, regardless of the antifoamer content, the setting time of the ultrarapid-hardening polymer-modified mortars using redispersible polymer powder tend to delay with increasing polymer-cement ratio. The water absorption and chloride ion penetration depth of the ultrarapid-hardening polymer-modified mortars using redispersible polymer powder decrease with increasing polymer-cement ratio and antifoamer content. The resistance of freezing and thawing and chemicals improvement is attributed to the improved bond between cement hydrates and aggregates because of the incorporation of redispersible polymer powder

A Method on the Rapid Assessment of Resistance to Chloride Ion Penetration for Mortar and Concrete with Mineral Admixtures (혼화재를 사용한 모르타르 및 콘크리트의 염소이온 침투 저항성 평가)

  • Park Jung-Jun;Kim Sung-Wook;Koh Kyung-Taek;Lee Jong-Suk;Lee Jang-Hwa
    • Journal of the Korea Concrete Institute
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    • v.16 no.4 s.82
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    • pp.485-492
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    • 2004
  • In this study, ASTM C 1202 which is most commonly used for evaluating the penetration resistance into the concrete is reviewed. The test results by ASTM C 1202 showed that the passed charge could be underestimated as the $OH^-$ ion concentration in the concrete is lowered when the concrete is mixed with the admixtures. Therefore, the modified method using the distilled water was proposed in the paper. According to the test results, the modified method is not susceptible to $OH^-$ ion and temperature rise. In addition, the long term emersion test for the concrete mixed with the admixtures in the NaCl solution showed that the chloride diffusion coefficient tested by the modified method have higher correlation compared to the conventional ASTM method.

An Experimental Study on the Engineering Characteristics of Ternary Lightweight aggregate Mortar Using Recycling Water (회수수를 사용한 3성분계 경량 골재 모르타르의 공학적 특성에 관한 실험적 연구)

  • Lee, Jae-In;Bae, Sung-Ho;Kim, Ji-Hwan;Choi, Se-Jin
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.10 no.1
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    • pp.48-55
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    • 2022
  • This study uses the recovered water as mixing water and artificial lightweight aggregate pre-wetting water as part of a study to increase the recycling rate and reduce greenhouse gas of the ready-mixed concrete recovered during the concrete transport process, and cement fine powder of blast furnace slag(BFS) and fly ash(FA). The engineering characteristics of the three-component lightweight aggregate mortar used as a substitute were reviewed. For this purpose, the flow, dry unit mass, compressive strength, drying shrinkage, neutralization depth, and chloride ion penetration resistance of the three-component lightweight aggregate mortar were measured. When used together with the formulation, when 15 % of BFS and 5 % of FA were used, it was found to be positive in improving the compressive strength and durability of the mortar.

Corrosion-Inhibition and Durability of Polymer-Modified Mortars Using Bisphenol A and F Type Epoxy Resin with Calumite (비스페놀 A 및 F형 에폭시수지와 칼루마이트를 병용한 폴리머 시멘트 모르타르의 방청성 및 내구성)

  • Kim, Joo-Young;Kim, Wan-Ki
    • Journal of the Korea Concrete Institute
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    • v.26 no.4
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    • pp.517-524
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    • 2014
  • Nitrite-Type hydrocalumite (calumite) is a material that can adsorb chloride ions ($Cl^-$) that cause corrosion of reinforce bars and liberate the nitrite ions ($NO_2{^-}$) that inhibit corrosion in reinforced concrete. In this study, polymer-modified mortars using two types of epoxy resin with calumite are prepared with various polymer binder-ratios of 0, 5, 10, 15, 20% and calumite contents of 0, 5%. The specimens are tested for chloride ion penetration, carbonation, drying shrinkage and corrosion inhibition. As a result, the chloride ion penetration and carbonation depth of PMM using epoxy resin somewhat increases with increasing calumite contents, but those remarkably decreases depending on the polymer-binder ratios. The 28-d drying shrinkage shows a tendency to decrease with increasing polymer-binder ratio and calumite content. Unmodified mortars with calumite content of 5% did not satisfy quality requirement by KS. However, it was satisfied with KS requirement by the modification of epoxy resin in cement mortar. On the whole, the carbonation and chloride ion penetration depth of epoxy-modified mortars with calumite is considerably improved with an increase in the polymer-binder ratio regardless of the calumite content, and is remarkably improved over unmodified mortar. And, the replacement of the portland cement with the calumite has a marked effect in the corrosion-inhibiting property of the epoxy-modified mortars.

Experimental Study for Evaluation of Chloride Ion Diffusion Characteristics of Concrete Mix for Nuclear Power Plant Water Distribution Structures (원전 취배수 구조물 콘크리트 배합의 염소이온 확산특성 평가를 위한 실험적 연구)

  • Lee, Ho-Jae;Seo, Eun-A
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.26 no.5
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    • pp.112-118
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    • 2022
  • In this study, the diffusion characteristics were evaluated using the concrete mix design of nuclear safety-related structures. Among the concrete structures related to nuclear power safety, we selected the composition of intake and drainage structures that are immersed in seawater or located on the tidal platform and evaluated the chloride ion permeation resistance by compressive strength and electrical conductivity and the diffusion characteristics by immersion in salt water. analyzed. Compressive strength was measured on the 1st, 7th, 14th, 28th, 56th, and 91st days until the 91st day, which is the design standard strength of the nuclear power plant concrete structure, and chloride ion permeation resistance was evaluated on the 28th and 91st. After immersing the 28-day concrete specimens in salt water for 28 days, the diffusion coefficient was derived by collecting samples at different depths and analyzing the amount of chloride. As a result, it was found that after 28 days, the long-term strength enhancement effect of the nuclear power plant concrete mix with 20% fly ash replacement was higher than that of concrete using 100% ordinary Portland cement. It was also found that the nuclear power plant concrete mix has higher chloride ion permeation resistance, lower diffusion coefficient, and higher resistance to salt damage than the concrete mix using 100% ordinary Portland cement.

Effect of PVA Fiber and Silica Fume Addition on Chloride Penetration Resistance of Alkali-Activated Slag (PVA 섬유와 실리카흄 첨가가 알칼리 활성 슬래그의 염화물 침투 저항성에 미치는 영향)

  • Yoon, Hyun No
    • Journal of Urban Science
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    • v.12 no.2
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    • pp.13-18
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    • 2023
  • This study investigates the effect of polyvinyl alcohol (PVA) fiber and silica fume addition on the chloride penetration resistance of alkali-activated slag. Silica fume was added to replace slag at the dosage of 0, 5, 10, and 20% by weight of the binder, while PVA fiber was added at the dosage of 0, 1, and 2% by volume of the mixture. Samples were synthesized via alkali activator with 1.0 of silicate modulus and cured at room temperature for 28 days. Compressive strength test, permeable voids volume test, water absorprtion test, and rapid chloride penetration test were conducted for measuring the charaterisitics of alkali-activaed slag. The results showed that increasing silica fume content up to 10% in alkali-activated slag improved compressive strength and chloride penetration resistance. Addition of PVA fibers up to 1% by volume enhanced strength and chloride penetration resistance, but exceeding this led to reduced strength and durability due to increased void formation in the matrix.

Properties of Epoxy-Modified Mortars with Alkali Activators and Ground Granulated Blast Furnace Slag (알칼리자극제 및 고로슬래그미분말을 병용한 에폭시수지 혼입 폴리머 시멘트 모르타르의 성질)

  • Kim, Wan-Ki
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.25 no.1
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    • pp.85-92
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    • 2021
  • The purpose of this study is to investigate the properties of hardener-free epoxy-modified mortars(EMMs) using ground granulated blast furnace slag(GGBFS) and alkali activators. The hardener-free EMMs with a GGBFS content of 20% using 4 types of alkali activators were prepared with various polymer-binder ratios, and tested for strengths, water absorption, carbonation depth, chloride ion and H2SO4 penetration depth. The conclusions obtained from the test results are summarized as follows: The compressive strength of the EMMs with a GGBFS content of 20% attains a maximum at a polymer-binder ratio of 10%. The flexural strength of the hardener-free EMMs using Ca(OH)2 as a alkali activator is improved with increasing polymer-binder ratios. However, the flexural strength of the EMMs using NaCO3, Na2SO4 and Li2CO3 is gradually decreased with increasing polymer-binder ratios. Regardless of the type of alkali activator, the water absorption, chloride ion penetration and carbonation depth are remarkably decreased with increasing polymer-binder ratios due to the epoxy film formed in the EMMs. The H2SO4 penetration depth of the hardener-free EMMs with a GGBFS content of 20% is gradually increased with increasing polymer-binder ratio. In this study, the properties of hardener-free EMMs using Ca(OH)2 as a alkali activator are more excellent than those of other alkali activators.

Properties of Steel Corrosion as a Hydration of Mortar with Calcium Aluminate Cement (알루민산칼슘 시멘트를 사용한 모르타르의 수화도에 따른 철근 부식 특성)

  • Min-Cheol Shin;Ki-Yong Ann
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.12 no.2
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    • pp.214-221
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    • 2024
  • The present study concerns the resistance of calcium aluminate cement (CAC) to steel corrosion. The corrosion behavior of steel, chloride binding/buffering and chloride transport were evaluated in order to predict the risk of steel corrosion. The CAC mortar exhibited no corrosion on steel, irrespective of the curing temperature and CAC types, whereas ordinary Portland cement (OPC) showed a severe corrosion on the steel surface. The chloride binding capacity of CAC found to be was lower than that of OPC, yet buffering capacity against pH decrease was found to be significantly higher in the CAC paste. Furthermore, chloride ingress at all depths was found to be reduced in CAC, thereby reducing the risk of corrosion.

Resistance of Chloride Penetration into High Strength Concrete Containing Mineral Admixtures according to Curing Conditions (광물질혼화재 혼합 고강도콘크리트의 양생조건에 따른 염화물이온 침투저항성)

  • Moon, Han-Young;Kim, Byoung-Kwon
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.8 no.2
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    • pp.185-194
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    • 2004
  • In recent years, construction company makes inroads into the world construction market, and receives the order of extra-large concrete structure under marine environment in south-east asia specially. At this point of time, to enhance the quality of concrete, we research the High Strength Concrete (HSC) containing mineral admixtures. In this study, therefore, HSC with various combination of ordinary portland cement(OPC), blast-furnace slag(SG), silica fume(SF), and expansion admixture(SS) are cured 23 and $35^{\circ}C$ considering the site weather, and are cured in water for 3, 7 or 56 days respectively. Test results show that the HSC cured at $35^{\circ}C$ gains higher early-age strength but eventually gains lower later-age strength compare with the HSC cured at $23^{\circ}C$. Especially, HSC with combination of OPC+SG+SF+SS or OPC+SG+SF show very excellent resistance of chloride penetration. The permeability of HSC was therefore enhanced as because of containing the proper content of SG, SF, and SS and making dense micro-structure of HSC.

Chloride Diffusion Coefficients in Cold Joint Concrete with GGBFS (고로슬래그 미분말을 혼입한 콜드조인트 콘크리트의 염화물 확산계수)

  • Oh, Kyeong-Seok;Mun, Jin-Man;Kwon, Seung-Jun
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.20 no.5
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    • pp.44-49
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    • 2016
  • Among the deteriorating agents, chloride ion is reported to be one of the most harmful ions due to its rapid diffusion and direct effect on steel corrosion. Cold joint which occurs in mass concrete placing is vulnerable to shear resistance and more severe deterioration. The paper presents an quantitative evaluation of chloride diffusion coefficient in OPC(Ordinary Portland Cement) and GGBFS(Ground Granulated Blast Furnace Slag) concrete containing cold joint. GGBFS concrete shows $6.6{\times}10^{-12}m^2/sec$ which is almost 30% level of OPC concrete results and the trend is repeated in the case of cold joint concrete. Compared with OPC concrete, GGBFS concrete is evaluated to have better resistance to chloride penetration, showing 0.30 times of chloride diffusion coefficient in concrete without cold joint 0.39 times with cold joint, respectively.