• Title/Summary/Keyword: 염료폐수

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파일럿 규모 초임계 염색에 관한 연구

  • 김병희;최준혁;안재명;이건호;손보국;심재진;이광수
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2003.04a
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    • pp.83-86
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    • 2003
  • 기존의 습식염색법이 에너지 다소비형일 뿐만 아니라 분산염료를 이용해 PET, Nylon과 같은 합성섬유를 염색할 때 첨가되는 조제(계면활성제, 균염제, 유연제 등)가 난분해성 폐수를 유발시킨다. 이를 방지하기 위한 새로운 초임계염색법이 1991년 독일의 Schollmeyer 교수에 의해 보고된 이후, 한국, 미국, 이태리, 프랑스 등에서도 이에 관한 연구가 활발히 진행되어 현재 많은 연구 성과를 거두고 있다. (중략)

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알칼리성 염색폐수의 색도제거를 위한 호알칼리성 균주의 분리와 성장 특성

  • Kim, Jeong-Mok
    • 한국생물공학회:학술대회논문집
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    • 2000.11a
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    • pp.544-548
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    • 2000
  • Strains degrading and decolorizing anthraquinone dyes, Remazol brilliant blue R were isolated from natural system, was named as RBB. The optimal culture conditions of temperature and pH were $35^{\circ}C$, 9.0, respectively. Growth rate of cells in conditions of aerobic shaking more than standing culture conspicuously increased.

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Study on the Carbon Membrane System for the Wastewater Treatment Via the Electric Adsorption and Desorption Process (전기적 흡.탈착법을 이용한 폐수처리용 탄소막 시스템 연구)

  • JeGal, Jong-Geon;Lee, Yong-Hwan;Jaung, Jae-Yun
    • Membrane Journal
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    • v.18 no.2
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    • pp.109-115
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    • 2008
  • To remove total dissolved solid (TDS) from wastewater, a carbon membrane system was prepared, using carbon membranes made from conductive activated carbon and poly(vinylidene fluoride) (PVDF). Using 100 ppm aqueous solutions of NaCl, $Na_2SO_4,\;MgCl_2,\;MgSO_4$, the basic properties of the carbon membranes used were studied. For the treatment of the real dye wastewater supplied from Kyungin Corp., a pilot scale carbon membrane system was also prepared, which was consisted of 240 plies of carbon membranes of $20cm{\times}20cm$ (length${\times}$width). Using the real wastewater with different TDS such as 941, 2050, 2810, 3830, 4960, 6030 ppm, prepared by the dilution of the original wastewater with pure water, the performance of the pilot scale carbon membrane system was studied. The effect of the operational conditions was studied.

Bacterial Cellulose Membrane for Wastewater Treatment: A Review (폐수 처리를 위한 박테리아 셀룰로오스 막: 리뷰)

  • Jang, Eun Jo;Patel, Rajkumar
    • Membrane Journal
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    • v.31 no.6
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    • pp.384-392
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    • 2021
  • Growing pollution due to industrialization leads to difficulties in survival of mankind. Generation of clean water from wastewater by membrane separation process is emerging cost efficient technology. Membrane prepared from renewable resources are in lots of demand to reduce burden on synthetic polymers which is one of the source of environmental pollution. Bacterial cellulose (BC) is very pure and distinct form of cellulose nanofibrils (CNF). Nanopapers prepared from CNF are used ad ultrafiltration (UF) and nanofiltration (NF) membrane for different applications. High crystallinity of BC gives rise to excellent mechanical property, an essential criterion for wastewater treatment membrane. In this review, BC based membrane for application in dye, oil, heavy metal and chemical removal from wastewater is discussed.

Preparation and Polarization Properties of Poly(vinyl alcohol) Polarizing Film Using the Mixed System of Supercritical $CO_2$/Organic Solvents/Dichroic Dye (초임계 탄산가스/유기용매/이색성 염료의 혼합계를 이용한 폴리(비닐 알코올) 편광필름의 제조 및 편광특성)

  • Park, Ki-Sang;Choi, E-Joon;Chang, Jin-Ho;Park, Il-Hyun
    • Polymer(Korea)
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    • v.35 no.5
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    • pp.458-466
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    • 2011
  • In the mixed system of supercritical carbon dioxide/organic solvents, poly(vinyl alcohol)(PVA) film of high degree of hydrolysis could be dyed with a dichroic dye of C. I. direct black 22(DB22) and as a result, high durability was obtained. Especially, as a dye dispersant in a supercritical fluid phase, a mixed solvent system of ethylene glycol: dimethyl sulfoxide=4 : 6 weight ratio was investigated. Then the optimum pressure for dyeing could be reduced down to 200 bar. Using this supercritical fluid system, the maximum dyeing appeared as the transmittance of less than 1% and the waste amount was reduced to the level of 1/10. After 500% drawing of this PVA film, both the polarizing efficiency of 94% and the single piece transmittance of 30% were obtained. The limitation of DB22 and further improvements were also discussed.

Removal of Reactive Dyes using Chitin-based Adsorbent PEI-chitin (키틴 기반 흡착제 PEI-chitin을 이용한 반응성염료의 제거)

  • Kim, Gyeong Min;Wang, Zhuo;Won, Sung Wook
    • Korean Chemical Engineering Research
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    • v.57 no.2
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    • pp.232-238
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    • 2019
  • Polyethylenimine-crosslinked chitin (PEI-chitin) was developed as a biosorbent to effectively remove dyestuffs from dye-containing wastewater. A representative reactive dye, Reactive Orange 16 (RO16) was used as a model dye. The effect of pH, isotherm, kinetic and desorption experiments were performed to evaluate the adsorption/desorption ability of PEI-chitin for RO16. As a result, the maximum adsorption capacity calculated by the Langmuir model was 266.3 mg/g at pH 2, and the time needed for adsorption equilibrium was evaluated to be about 20, 60, and 240 min for 50, 100, and 200 mg/L, respectively. The desorption experiments were carried out using various eluents such as ammonia/ethanol mixture, NaOH, $NaHCO_3$, and $Na_2CO_3$, and the highest desorption rate was 75.24% in the ammonia/ethanol mixture.

Treatment of dyeing wastewater using Moving Bed Bioractor (부유메디아 생물막 공정을 이용한 염색폐수처리)

  • Shin, Dong-Hoon;Lee, Sang-Hun;Ryu, Seung-Han;Park, Jun-Hyung;Jo, Seog-Jin
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2011.03a
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    • pp.110-110
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    • 2011
  • 염색공업 폐수는 그 성분이 일반적으로 매우 복잡하며, 작업공정의 가동 사항에 따라 수질 변동이 큰것이 특징으로, 각 공정에서 배출되는 염료, 보조화학물질, PVA(Polyvinyl alchol), 전분, wax 등이 포함되어 있으며 pH가 높고, 색도로 인해 하천에 방류될 경우 확산성이 높아 미생물에 의한 자정작용을 방해하여 하천의 수중생태계를 파괴할 우려가 있다. 이러한 염색산업에서 발생하는 폐수는 일반적으로 응집침전, 부상분리법 등의 전처리한 후 활성오니공정으로 처리하는 방법이 널리 이용되고 있으나, 이들 처리공정으로는 폐수 속에 포함되어 있는 다양한화학적 구조의 색소성분 및 유해물질을 완벽하게 제거하는 것이 어려운 실정이다. 유기물 함량이 높은 염색폐수를 처리하기 위해 제안된 기술로는 산소활성슬러지법, 유동상 및 고정상 생물막법, 포괄고정화법 등이 있다. 이러한 기술들중 기존의 처리공정을 증축없이도 처리효율을 높일 수 있는 방법으로 담체를 이용한 부유메디아 생물막공정(Moving-Bed BioReactor, MBBR)이 있다. 이공정은 미생물이 부착, 성장할 수 있는 공극율과 비표면적이 큰 담체를 이용하므로 반응조내의 부유 미생물 뿐만 아니라 담체에 고농도로 부착된 부착 미생물에 의해서도 유기물을 제거하기 때문에 다른 공정들에 비해 처리효율이 뛰어나고 기존의 활성슬러지 공정에 비해 갑작스러운 부하변동 및 유독성 폐수유입에 대해서도 안정적으로 운전이 가능한 장점이 있다. 본연구에서는 부유메디아 생물반응기(Moving-Bed BioReactor, MBBR)을 이용하여 염색폐수내 $COD_{Mn}$, 색도 및 난분해성 물질인 PVA 저감에 대한 Lab-scale test 수행하였다. 실험에 사용된 염색폐수의 수질은 평균 pH 13, $COD_{Mn}$ 900 mg/L, SS 135 mg/L, 색도 1,134 [C.U.], PVA 593 mg/L였으며, 2L의 반응기를 사용하여 회분식 실험을 수행였다. 본 실험에서는 호기성 미생물에 의한 염색폐수의 생분해가 유지되는데 필요한 최적의 용존산소 농도와 이에 필요한 공기 폭기량을 결정하기 위하여 i) DO uptake rate측정과 ii) 담체의 충진율, iii) COD/N ratio, iv) Air 유량, v) 담체내 흡착제의 종류, vi) $Ca^{2+}$ 첨가가 염색폐수의 생분해에 미치는 영향을 살펴보았다. 운전시간을 7일로 하여 COD, 색도, PVA 등을 측정한 결과 담체를 첨가한 경우가 담체를 첨가하지 않은 경우 보다 제거효율이 뛰어났다. 특히 충진율 30%(C/N 3)의 경우에서 COD, 색도, PVA의 제거율이 각각 평균 65%, 70%, 60%로 가장 높은 제거효율을 나타내었다.

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Analysis of Degradation Products in Madder Dyed Fabrics in Selective Degradation Conditions (퇴화조건에 따른 꼭두서니 염색물의 퇴화물 연구)

  • Ahn, Cheun-Soon;Obendorf, S.-Kay
    • Journal of the Korean Society of Clothing and Textiles
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    • v.29 no.12 s.148
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    • pp.1608-1618
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    • 2005
  • The purpose of this investigation was to investigate the degradation products of the dye component extracted from madder dyed fabrics using the GC-MS analysis and to evaluate the change of color due to degradation treatment. Four different degradation protocols were used in this study,; refrigeration at $7^{\circ}C$ (LT), room temperature (RT), oven treatment at $100^{\circ}C$ (OV), and $H_2O_2/UV(PER)$ method. Degradation times for each thermal system were 6 hour, 24 hour, 48 hour, 1 week, 2 week, 4 week. Alizarin was detected from the control and degraded samples of both alizarin dyed and madder dyed fabrics. Benzoic acid, 2, 4-di-tert-butylphenol, phthalic anhydride were detected as the degradation products for both alizarin dyed and madder dyed fabrics. The result suggest that these products can be used as the fingerprints of GC-MS analysis for the identification of madder dye in archaeological textiles. Both alizarin dyed and madder dyed samples became less red and less yellow after degradation. In the PER degradation system madder dyed sample showed the greatest color difference even after 1 week of degradation treatment. Further research is necessary for investigating the color change in the exhumed textiles, which is caused by the dual action of dye fading and the staining of organic matters in the soil.

Decoloration in Dyebath by Dye Absorption of Chitin(Part I) (키틴의 염료 흡착에 의한 염액의 색소제거에 관한 연구(제1보))

  • 유혜자;이혜자;이전숙
    • Journal of the Korean Society of Clothing and Textiles
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    • v.24 no.3
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    • pp.385-392
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    • 2000
  • The adsorption ability of dyes on chitin, a natural polymer was investigated for decolorization of dye wastewater. Chitin was manufactured in lab by decalcification in dilute aqueous HCI solution and deproteination in dilute aqueous NaOH solution with shrimp shells. Absorbance of residue solution of dyebaths after dye adsorptions of chitin were measured in varieties of dye concentration and dipping periods. Four kinds of dyestuffs were used, C.I.Acid Blue 29. C.I.Direct Blue 6, C.I.Reactive Orange 12 and C.I.Basic Red 18. When chtin 1g was dipped in 0.05% of dyebath with stirring, maximum adsorption ratio of each kind of dyes was exhibited as 91.6% for C.I.Acid Blue 29, 95% for C.I.Direct Blue 6, 58.2% for C.I.Reactive Orange 13 and 75.8% for C.I.Basic Red 19. It shows that chitin has better adsorption abilities of ionic dyes of acid, direct and basic dye than non-ionic reactive dye. And chitin has better adsorption abilities of anionic acid direct dyes than cationic basic dye because of the presence of nitrogen atoms. All kinds of dyestuffs used showed speedy absorption effects by chitin, so chitin can absorb much amount of dyes in 5 mimutes reach to equilibrium of adsorption in 2 hours after dipping. Basic dye was absorbed the most speedily in 5 minutes, although maximum adsorption ratio is not high. That reason can be thought that chitin surface is essentially negatively charged due to polar funtional groups.

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Solubility Measurement and its Correlation of Disperse Dye in Supercritical HFC-134a (초임계 HFC-134a에 대한 분산염료의 용해도 측정과 모델링)

  • Park, Min-Woo;Bae, Hyo-Kwang
    • Korean Chemical Engineering Research
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    • v.40 no.6
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    • pp.715-718
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    • 2002
  • The supercritical dyeing process has been gaining the increasing importance because of environment reason. For further development of this process, it is needed to measure the solubility in supercritical fluids in the extensive ranges of temperature and pressure. In this study, using the semi-flow type apparatus consisted of supercritical fluid equilibrium cell, the solubility of disperse dye(C.I. disperse red 60) in supercritical HFC-134a has been measured at the temperatures of 383.2 K and 413.2 K, and in the pressure range of 50 bar to 160 bar. The solubility data are, with good agreement, correlated by an expanded liquid model which considers the supercritical fluid as compressed liquid.