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http://dx.doi.org/10.9713/kcer.2019.57.2.232

Removal of Reactive Dyes using Chitin-based Adsorbent PEI-chitin  

Kim, Gyeong Min (Department of Marine Environmental Engineering and Institute of Marine Industry, Gyeongsang National University)
Wang, Zhuo (Department of Ocean System Engineering, Gyeongsang National University)
Won, Sung Wook (Department of Marine Environmental Engineering and Institute of Marine Industry, Gyeongsang National University)
Publication Information
Korean Chemical Engineering Research / v.57, no.2, 2019 , pp. 232-238 More about this Journal
Abstract
Polyethylenimine-crosslinked chitin (PEI-chitin) was developed as a biosorbent to effectively remove dyestuffs from dye-containing wastewater. A representative reactive dye, Reactive Orange 16 (RO16) was used as a model dye. The effect of pH, isotherm, kinetic and desorption experiments were performed to evaluate the adsorption/desorption ability of PEI-chitin for RO16. As a result, the maximum adsorption capacity calculated by the Langmuir model was 266.3 mg/g at pH 2, and the time needed for adsorption equilibrium was evaluated to be about 20, 60, and 240 min for 50, 100, and 200 mg/L, respectively. The desorption experiments were carried out using various eluents such as ammonia/ethanol mixture, NaOH, $NaHCO_3$, and $Na_2CO_3$, and the highest desorption rate was 75.24% in the ammonia/ethanol mixture.
Keywords
Chitin; Biosorbent; Reactive dye; Surface modification; Polyethylenimine;
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