• Analytical Science and Technology
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• v.24 no.6
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• pp.451-459
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• 2011

Eight coordinated terbium(III) complexes, tris (2-pyrazinecarboxylato)(phenanthroline) terbium(III) [$Tb(pzc)_3$(phen)], tris (5-methyl-2-pyrazinecarboxylato) (phenanthroline) terbium(III) [$Tb(mpzc)_3$(phen)] and tris(2-picolinato) (phenanthroline) terbium(III) [$Tb(pic)_3$(phen)], have been synthesized and characterized by Fourier transform infrared (FT-IR), UV-Visible and X-ray photoelectron spectroscopy. Photoluminescence (PL) spectroscopy shows that these complexes emitted strong green luminescence. When powder samples of the $Tb^{3+}$ complexes are examined using time-resolved spectroscopic analysis, the luminescence lifetimes are found to be 0.87 ms and 1.0 ms, respectively. Thermogravimetric analysis reveals the terbium complexes to have good thermal stability up to $333-379^{\circ}C$. Cyclic voltammetry shows that HOMO-LUMO energy gap of the $Tb^{3+}$ complexes ranges from 4.26~4.41 eV. These values are similar to those obtained from the UV-visible spectra. Overall, the synthesized $Tb^{3+}$ complexes may be useful advanced materials for green light emitting devices.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.42 no.2
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• pp.150-157
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• 2014

Li-Ion battery is used in the most satellites now due to advantages such as weight, thermal dissipation and self discharge compared to the previous generations of electrochemical batteries. The performance analysis model of the Li-Ion battery is needed to aid the design of new satellite electrical power subsystem. This paper develops the performance analysis model of the Li-Ion battery to apply to the electrical power subsystem design and energy balance analysis on geostationary orbit. The analysis model receives the satellite bus power, solar array power and battery temperature and gives the battery voltage, charge and discharge currents, taper index, state of charge and power dissipation. The results from the performance analysis are compared and analyzed with the flight data to verify the model. The compared results show satisfactory without significant difference with the flight data.

• Journal of Bio-Environment Control
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• v.7 no.3
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• pp.214-218
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• 1998

This study was performed to stabilize the physical properties of Sodium Carbonate Decahydrate that was selected as a highly concentrative thermal energy storage medium. The addition of ARS(additives to prevent supercooling) showed to prevent the supercooling of Na$_{2}$CO$_{3}$.10H$_{2}$O, and the supercooling was decreased below $1.5^{\circ}C$ with ARS of 3 wt% and the addition of PSC(phase separation controller) of 1.5 wt% controlled the phase separation of Na$_{2}$CO$_{3}$ .10H$_{2}$O with the phase change cycles increased from 0 to 1,500, the phase change temperature and the latent heat has changed in the range of 30$\pm$1.$0^{\circ}C$ and 54$\pm$2.0Kcal.kg$^{-1}$ respectively.

• Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
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• v.27 no.1
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• pp.683-692
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• 2009

On-site remote sensing technique by using single lens reflex(SLR) digital camera will be expected as the useful tool for the vegetation measurement field such as a crop growth management, the monitoring of revegetation slope and the evaluation of environment. We reviewed the availability of the vegetation measurement using a digital camera which is sailed for general-purpose. As a result, we could analysis relationship with the illuminance of image plane and incidence energy of multitemporal observation images by doing gamma correction and exposure compensation. And also, we proposed the model formulas for the correction of influences of capturing angle and illuminance. In addition, we obtained high correlation of normalized difference vegetation index(NDVI) between digital camera and spectral photometer.

• Journal of the Korean Society for Nondestructive Testing
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• v.31 no.2
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• pp.139-143
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• 2011

The problem of delamination of composite tubes by impact has been acknowledged in aerospace and automobile industry. Non-destructive testing(NDT) methods in composite material structure are important to evaluate reliability of composite structure. There are many kinds of NDT methods which can detect the inside defect of the composite material such as Infrared Thermography(IRT). Infrared thermal imaging of object is different from that of a defect, in heated composite tubes with an internal defect, and then location and size of a defect can be measured by the analysis of thermal imaging pattern. In this study, Lock-in Infrared thermography detect internal defects of Impacted composite tubes by the inspection of infrared lay radiated from the surface of composite tubes.

• Journal of the Korean Society for Nondestructive Testing
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• v.31 no.2
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• pp.127-133
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• 2011

A LabVIEW program has been developed together with simple infrared thermography(IRT) system to control the lock-in conditions of the system efficiently. The IR imaging software was designed to operate both of infrared camera and halogen lamp by synchronizing them with periodic sine signal based on thyristor(SCR) circuits. LabVIEW software was programmed to provide users with screen-menu functions by which it can change the period and energy of heat source, operate the camera to acquire image, and monitor the state of the system on the computer screen. In experiment, lock-in IR image for a specimen with artificial hole defects was obtained by the developed IRT system and compared with optical image.

• Polymer(Korea)
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• v.29 no.2
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• pp.122-126
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• 2005

The effect of Al-MCM-41 preparation methods on the catalytic degradation of linear low density polyethylene (LLDPE) was investigated. Al-MCM-41 catalysts were synthesized by direct method (Al-MCM-41-D) and post treatment method (Al-MCM-41-P) and their characteristics were elucidated by XRD, BET, $NH_3\;TPD,\;^{27}Al$ MAS NMR. TGA kinetic analysis showed that the catalytic activation energies of Al-MCM-41-D and Al-MCM-41-P were 191.54 and 114.26 kJ/mol, respectively. The higher catalytic activity of Al-MCM-41-P would be attributed to its smaller pore size as well as higher number of acid sites that are accessible.

• Microbiology and Biotechnology Letters
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• v.7 no.3
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• pp.141-147
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• 1979

Naringinase from Atpergillus nidulans was immobillized on DEAE-Sephadex A-25 and its characteristics were studied. The optimal conditions for the preparation of the immobilized enzyme were as follow; optimal pH, incubation time and the suitable amount of enzyme were 6.0, 30 min. and 110 units per gram of the dried ion exchage resin, respectively. The optimal pH of the immobilized enzyme was higher than that of the native enzyme. The optimal temperature increased from 4$0^{\circ}C$ to 5$0^{\circ}C$. The heat and pH stability of the immobillized enzyme were better than those of the native enzyme. No significant difference in the Michaelis constant was detected. Activation energy of the immobilized enzyme was 7.96 Kcal/mole, and the apparent Michaelis rate equation was used to describe the action of this material. The degree of hydrolysis was dependant on the flow rate at low rate of perfusion through the column. As the flow rate increased, the value of the apparent Km decreased.

• Journal of Biosystems Engineering
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• v.35 no.1
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• pp.46-52
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• 2010

The temperature of root zone was known as an important factor for the growth of crops and reduction of energy in greenhouse. The purpose of this study was to design the apposite inflow of calories per the unit area by comparison of temperature in the warmed and non-warmed soil. The energy needed for soil warming about pipe length showed the change of temperature on inflow and outflow as $2^{\circ}C{\sim}3^{\circ}C$(average $2.5^{\circ}C$). Therefore, the inflow per the unit hour was 3,450, 57,5 kcal/$h{\cdot}m^2$ on soil heating respectively. The non-warmed soil temperature in greenhouse made a difference by depth and it was partially affected inner temperature under 15 cm, but it was not above 15 cm. The soil temperature would be raised over $5^{\circ}C$ than non-warmed soil to increase effect of soil warming. Therefore, the inflow per the unit area that should be provided was about 100 kcal/$h{\cdot}m^2$.

• The Journal of the Acoustical Society of Korea
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• v.14 no.3
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• pp.61-70
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• 1995

In this paper, the PLP cepstrum which is close to human perceptual characteristics was extracted through the spread time area to get the temperal feature. Phonemes were recognized by artificial neural network similar to the learning method of human. The phoneme strings were matched by Markov models which well suited for sequence. Phoneme recognition for the continuous Korean speech had been done using speech blocks in which speech frames were gathered with unequal numbers. We parameterized the blocks using 7th order PLPs, PTP, zero crossing rate and energy, which neural network used as inputs. The 100 data composed of 10 Korean sentences which were taken from the speech two men pronounced five times for each sentence were used for the the recognition. As a result, maximum recognition rate of 94.4% was obtained. The sentence was recognized using Markov models generated by the phoneme strings recognized from earlier results the recognition for the 200 data which two men sounded 10 times for each sentence had been carried out. The sentence recognition rate of 92.5% was obtained.