• Title/Summary/Keyword: 열화학적 방법

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Variation in Physicochemical Properties and Anaerobic Digestion Efficiency by Thermal-alkali Pre-treatment (THAP) Factors (열화학적 가수분해 영향인자에 따른 물리화학적 특성 변화 및 혐기성소화 효율 평가)

  • Park, Seyong;Han, Sungkuk;Song, Eunhey;Kim, Choonggon;Lee, Wonbae
    • Journal of the Korea Organic Resources Recycling Association
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    • v.27 no.3
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    • pp.27-39
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    • 2019
  • In this study, thermal-alkali pre-treatment (THAP) optimal condition and co-digestion efficiency with THAP of the mixture food waste and sewage sludge were evaluated for improving the performances of co-digestion for mixed food waste and sewage sludge. The optimal condition of THAP was evaluated for solubilization COD, CST(Capillary Suction Time), TTF(Time to Filter), and volatile fatty acids (VFAs) with THAP temperature and NaOH concentration. In addition, the co-digestion of mixed food waste and sewage sludge were evaluated using biochemical methane potential (BMP) test. The optimal THAP reaction temperature and NaOH concentration of food waste and sewage sludge were $140^{\circ}C$ and 60 meq/L to solubilization COD over 20%, CST and TTF under 60sec and VFAs concentration over 12,000 mg-COD/L, respectively. The optimal condition of co-digestion of mixed food waste and sewage sludge equal to THAP condition. Therefore, it was determined that the optimal condition of THAP reaction temperature and NaOH concentration for co-digestion of mixed food waste and sewage sludge were $140^{\circ}C$ and 60 meq/L, respectively.

Reviews on the Phosphorus Recovery from Incinerated Sewage Sludge Ash (하수슬러지 소각재 중의 인 회수방법의 사례 연구)

  • Yoon, Seok-Pyo
    • Journal of the Korea Organic Resources Recycling Association
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    • v.29 no.1
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    • pp.5-17
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    • 2021
  • This study is a literature review on the recovering phosphorus from Incinerated Sewage Sludge Ash(ISSA), which has relatively high content of phosphorus. Experimental conditions and influencing factors related to the recovery of P and removal of heavy metals by wet and thermochemical methods were discussed. For the practical application of the recovery of P from ISSA, an integrated process linked to incineration facilities is required in terms of economy from the perspective of the entire system including disposal of wastewater and residues generated during the recovery process, and minimizing added chemicals and energy consumption.

Domestic Trends in Thermochemical Recycling Technology of Waste Plastics (폐플라스틱의 열화학적 재활용 기술 국내 동향)

  • Seon Ah Roh;Tai jin Min;Jin-Tae Kim;Bangwoo Han
    • Resources Recycling
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    • v.32 no.6
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    • pp.79-89
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    • 2023
  • One of the foremost environmental challenges, alongside the contemporary focus on achieving carbon neutrality, pertains to the pervasive issue of plastic waste. Thermochemical recycling technology, operating under high-temperature conditions to covert organic matter and recycle it into raw materials and energy, represents a transformative approach surpassing the conventional bounds of material recycling predominantly applied in plastic waste management. The thermochemical recycling paradigm is emerging as a pivotal technology within the circular economy, capable of transforming waste plastics into raw materials for producing original plastics. Its significance extends beyond national borders, garnering global attention due to its versatility as a chemical or energy recycling method, contingent upon the subsequent processes and final products. This study aims to scrutinize three quintessential thermochemical recycling technologies: combustion, gasification, and pyrolysis. Furthermore, the study discusses the recent major technology trends of these technologies.

Trends of Thermochemical Technology for the Recovery of Phosphorus from Sewage Sludge Ash (열화학적 방법에 의한 하수 슬러지 소각재에서의 인 회수 기술 동향)

  • Jeon, Seulki;Shin, Hyuna;Kim, Dong-Jin
    • Clean Technology
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    • v.24 no.2
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    • pp.87-98
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    • 2018
  • Phosphorus (P) is an essential and irreplaceable element for all living organisms, and it is widely used as a fertilizer. Unfortunately, it is estimated that phosphate reservoir is depleted within about 100 years. Sewage sludge ash (SSA) is an alternative resource for P recovery because of its high P content. However, SSA cannot be directly used as a fertilizer due to heavy metals in it and low P bioavailability. Thermochemical treatment with Cl donor is known to reduce heavy metal contents and increase P bioavailability of SSA. Literature review on thermochemical technologies of SSA for the reduction of heavy metals and bioavailability enhancement has been carried out to estimate the status of current P recovery technology and to develop strategic future research plan for P recovery. The review showed that $CaCl_2$ and $MgCl_2$ were the most effective Cl donors and reaction temperature (< $1000^{\circ}C$) was the critical operation condition for the reduction. The removal efficiency depends on the species of heavy metals. Thermochemical technology of SSA for P recovery showed the possibility of commercial application in the near future to overcome the coming crisis of human sustainability by P depletion, but it needs cost effectiveness and more ecofriendly process to reduce energy consumption.

Estimation of Anaerobic Co-digestion Efficiency of Dewatered Sludge and Food waste using Thermo-Chemical Pre-Treatment (열화학적 전처리에 따른 탈수슬러지 및 음식물류폐기물의 병합혐기소화 효율 평가)

  • Lee, Wonbae;Park, Seyong
    • Journal of the Korea Organic Resources Recycling Association
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    • v.30 no.4
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    • pp.27-40
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    • 2022
  • In this study, the anaerobic digestion potential and thermo-chemical pre-treatment were evaluated for efficient anaerobic co-digestion of dewatered sludge(DS) and food waste(FW). As a result, the degradable organic matter concentration and methane yield of FW were evaluated to 2.2 and 1.3 times higher than that of DS, respectively. In order to increase the amount of biogas production, it was determined that it is desirable to increase the mixing ratio of FW. The efficiency of thermo-chemical pre-treatment was evaluated for the reaction temperature, NaOH concentration, reaction time and mixture ratio. As a result of evaluation through pre-treatment efficiency and dehydration capacity, the optimum pre-treatment conditions were evaluated as follows: reaction temperature 140℃, NaOH concentration 60 meq/L, reaction time 60 min, mixture ratio 1:5(DS:FW). The gas production rate and methane yield increased 1.6 and 1.5 times, respectively, compared to before and after applying the optimum pre-treatment. Therefore, it is necessary to increase the mixing ratio of food waste for efficient anaerobic co-digestion of DS and FW. and it is necessary to increase the solubilization efficiency of waste by application of pre-treatment.

The Effect of Oxygen Absorbent on Aged Characteristics of Hanji during Biological Artificial Aging by Aspergillus versicolor and Penicillium polonicum (산소흡수제 처리가 Aspergillus versicolor와 Penicillium polonicum에 의한 한지의 생물열화 특성에 미치는 효과)

  • Jeong, Hye Young;Choi, Kyoung-Hwa;Park, Ji Hee;Seo, Jin Ho
    • 보존과학연구
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    • s.32
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    • pp.137-153
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    • 2011
  • Paper cultural heritages in museums and libraries are deteriorated by many biological factors like as fungi, insects, bacteria and rodents and get irreversibly damaged. Especially, paper components like as cellulose, hemicellulose, lignin, pectins, tannins, proteins and mineral additives are good nourishment for microorganism. Through some studies on fungi causing the aging of paper materials, Aspergilli (about 30%) and Penicilli (more than 30%) are the most common among 300 different kinds of microorganism that caused the biological aging of paper cultural heritages in museums and libraries. At present, various treatments are attempted to control the biodeterioration by these fungi. Especially, it is focused on the control of environmental factors such as humidity, temperature and oxygen. In this study, the oxygen absorbent was used to control oxygen, one of the these favorable conditions during the biological aging of Hanji by Aspergillus versicolor and Penicillium polonicum and then the effect on prevention in aging by this treatment was investigated. In result, the oxygen absorbent treatment had the good effect on prevention in aging during the biological aging by two species of fungi.

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Degradation Quantification Method and Degradation and Creep Life Prediction Method for Nickel-Based Superalloys Based on Bayesian Inference (베이지안 추론 기반 니켈기 초합금의 열화도 정량화 방법과 열화도 및 크리프 수명 예측의 방법)

  • Junsang, Yu;Hayoung, Oh
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.27 no.1
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    • pp.15-26
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    • 2023
  • The purpose of this study is to determine the artificial intelligence-based degradation index from the image of the cross-section of the microstructure taken with a scanning electron microscope of the specimen obtained by the creep test of DA-5161 SX, a nickel-based superalloy used as a material for high-temperature parts. It proposes a new method of quantification and proposes a model that predicts degradation based on Bayesian inference without destroying components of high-temperature parts of operating equipment and a creep life prediction model that predicts Larson-Miller Parameter (LMP). It is proposed that the new degradation indexing method that infers a consistent representative value from a small amount of images based on the geometrical characteristics of the gamma prime phase, a nickel-base superalloy microstructure, and the prediction method of degradation index and LMP with information on the environmental conditions of the material without destroying high-temperature parts.

Nuclear Hydrogen Production Technology Development Using Very High Temperature Reactor (초고온가스로를 이용한 원자력수소생산 기술개발)

  • Kim, Yong-Wan;Kim, Eung-Seon;Lee, Ki-yooung;Kim, Min-hwan
    • Transactions of the KSME C: Technology and Education
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    • v.3 no.4
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    • pp.299-305
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    • 2015
  • Nuclear hydrogen production technology is being developed for the future energy supply system. The sulfur-iodine thermo-chemical hydrogen production process directly splits water by using of the heat generated from very high temperature gas-cooled reactor, a typical Generation IV nuclear system. Nuclear hydrogen key technologies are composed of VHTR simulation technology at elevated temperature, computational tools, TRISO fuel, and sulfur iodine hydrogen production technology. Key technology for nuclear hydrogen production system were developed and demonstrated in a laboratory scale test facility. Technical challenges for the commercial hydrogen production system were discussed.

Degradation Estimation of 2.25Cr-1Mo Steel by Ultrasonic Guided Wave (유도초음파를 이용한 2.25Cr-1Mo재의 열화도 평가)

  • Park, Ik-Keun;Park, Un-Su;Lee, Sang-Young;Kwun, Sook-In;Cho, Youn-Ho;Yoon, Seung-Hyun
    • Journal of the Korean Society for Nondestructive Testing
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    • v.21 no.4
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    • pp.415-424
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    • 2001
  • The destructive method is reliable and widely used for the estimation of material degradation but, it have time-consuming and a great difficulty in preparing specimens from in-service industrial facilities. Therefore, the estimation of degraded structural materials by nondestructive evaluation is strongly desired. In this paper, the use of guided wave was suggested for the evaluation on thermally damaged 2.25Cr-1Mo steel as an alternative way to compensate for limitations of fracture tests. The observation of microstructure variations of the material including carbide precipitation increase and spheroidization near grain boundary was conducted and the correlation with the guided wave features such as energy loss ration and group velocity changes was investigated. Through this study, the feasibility of ultrasonic guided wave evaluation for thermally damaged materials was explored.

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