• Title/Summary/Keyword: 열팽창

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Study on the Coefficient of Thermal Expansion for Composites Containing 3-Dimensional Ellipsoidal Inclusions (3차원적 타원 형태의 충전제를 함유하는 복합체의 열팽창 계수 연구)

  • Lee, Kee-Yoon;Kim, Kyung-Hwan;Jeoung, Sun-Kyoung;Jeon, Hyoung-Jin;Joo, Sang-Il
    • Polymer(Korea)
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    • v.31 no.3
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    • pp.206-214
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    • 2007
  • The theoretical study is developed for predicting the thermal expansion changes of composites which include complex inclusion, which is used three-dimensional ellipsoid model ($a_1>a_2>a_3$), which has two aspect ratios (the primary aspect ratio, $\rho_{\alpha}=a_1/a_3$ and the secondary aspect ratio, $\rho_{\beta}=a_1/a_2$). We can predict the feature of general thermal expansion factors by theoretical approach of matrix with aligned ellipsoidal inclusion using the Eshelby's equivalent tensor. The coefficients of longitudinal linear thermal expansion ${\alpha}_{11}$ decrease to those of inclusions, ${\alpha}_f$, as both aspect ratios increase. The coefficients of transverse linear thermal expansion of composites ${\alpha}_{33}$ initially increase and show the parabolic corves with maximum values, as the concentrations of filler increase. The coefficient of thermal expansion, ${\alpha}_{22}$ in the transverse direction decreases, as $\rho_{\alpha}$ increases, however, ${\alpha}_{22}$ increases as $\rho_{\beta}$ increases. The coefficient of linear thermal expansion of composites, ${\alpha}_{33}$ in the normal direction increases, as $\rho_{\alpha}$ increases, while ${\alpha}_{33}$ decreases as $\rho_{\beta}$ increases.

Study on the prediction about thermal deformation of thin film solar cell according to metal substrates (금속기판재에 따른 박막형 태양전지의 열변형량 예측에 관한 연구)

  • Koo, Seung-Hyun;Lee, Heun-Yeol;Yim, Tai-Hong
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.11a
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    • pp.285-288
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    • 2007
  • 박막형 태양전지 및 플렉서블 태양전지 기판으로 사용되는 금속기판의 우수성은 잘 알려져 있다. 그러나 상용 금속기판이 직면하고 있는 문제점을 보완하기 위해서 전주법으로 제조된 2원합금 금속포일을 개발하였으며, 박막형 및 플렉서블 태양전지의 기판재로 적용가능성을 확인하였다. 일반적으로 태양전지를 제조할 때 열 공정이 수행되며, 이때 기판재와 cell을 구성하는 반도체의 열팽창 계수 차이에 의한 열변형으로 결함이 발생될 수 있고, 태양전지 효율 및 수명을 저하시키는 원인이 될 수 있다. 이러한 원인이 될 수 있는 구성 재료간의 열팽창계수 차이에 의한 cell 의 변형량을 추정하기 위해 유한요소해석 방법을 사용하였다. 유한요소해석을 수행하기 위해 ALGOR 라는 해석 tool 을 사용하였다. 유한요소해석 수행에 사용된 상용 금속인 Mo, Ti, Al, SUS 포일과 전주법으로 제조된 2원합금 금속포일의 열팽창 계수는 실험을 통한 측정치이며, cell을 구성하는 반도체의 열팽창 계수와 열특성은 참고 문헌에 있는 자료들이다. 이 값들을 기반으로 cell 의 구성을 단순화시킨 가상의 태양전지가 제조 공정 온도에서 상온으로 냉각될 때의 열변형량을 계산하였다.

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The prediction of thermal deformation of Ni alloy substrate for application of flexible solar cell (플렉서블 태양전지 기판재용 Ni 계 합금의 열변형 예측)

  • Koo, Seung-Hyun;Lee, Heung-Yeol;Yim, Tai-Hong
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.05a
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    • pp.382-385
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    • 2008
  • 박막형 태양전지 분야는 저가이고 가볍다는 특징을 가지고 있으며, 휘어지는 기판재를 적용하여 플렉서블 태양전지를 제조할 수도 있다는 장점을 가지고 있다. 본 연구에서 플렉서블 태양전지에 적합한 금속기판재를 제조하는 연구를 수행하였다. 일반적으로 기판재와 cell을 구성하는 반도체 층의 열팽창 거동 차이에 의한 열변형이 태양전지의 공정안정성에 영향을 주는 것으로 알려져 있었으며, cell을 구성하는 반도체 층과 열팽창 거동이 유사한 금속기판재의 적용이 필요하다. 이러한 특성을 쉽게 제어할 수 있는 금속기판재를 얇게 제조하기에 적절한 방법은 전주법이다. 전주법을 적용하여 조성 및 두께가 다른Ni 계 합금의 열팽창 거동을 TMA 장비를 사용하여 측정하였으며, 태양전지 제조에 사용되는 고온공정시 안정성 확보를 위하여 열처리후에 금속기판재의 열팽창 거동을 측정하였다. 그리고 전산해석tool 을 활용하여 가상의 CIS 플렉서블 태양전지 제조공정을 설정하고 고온공정온도에서 상온으로 냉각시 발생되는 층간 열변형 연구를 수행하였다. 그리고 플렉서블 태양전지용 기판재로 Ni 계 합금표면에 절연체인 $SiO_2$ 증착 연구를 수행하여 Fe-52Ni 합금에서 안정적인 절연층을 얻을 수 있었다.

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A Study on the Effect of Fiber Orientation on Impact Strength and Thermal Expansion Behavior of Carbon Fiber Reinforced PA6/PPO Composites (탄소섬유 강화 PA6/PPO 복합재료의 섬유 배향에 따른 충격강도 및 열팽창 거동에 관한 연구)

  • Won, Hee-Jeong;Seong, Dong-Gi;Lee, Jin-Woo;Um, Moon-Kwang
    • Composites Research
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    • v.27 no.2
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    • pp.52-58
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    • 2014
  • Short fiber reinforced composites manufactured by injection molding have diverse fiber orientations variable with measuring positions even in the same specimen, which is caused by the flow induced fiber orientation. Fiber orientations considerably affect the mechanical and thermal properties of final composite products. In this study, fiber orientation of injection molded carbon fiber reinforced PA6/PPO composite was measured at several points of the specimen by optical microscopy analysis and the corresponding izod impact strength, coefficients of thermal expansion (CTE) were also measured to investigate the influence of local fiber orientation on the mechanical and thermal properties. Izod impact strength where fiber was perpendicular to the direction of crack propagation was higher than where fiber was parallel to the direction, which could be explained be the impact resistance reinforcing mechanism by fiber orientation. CTE was also lower where fiber was parallel to the measurement direction of CTE than where fiber was perpendicular to the direction, which could be also explained by the dimensional stability mechanism by fiber orientation.

Waterproofing performance evaluation according to the number of layer for shield TBM segment hydrophilic rubber waterstop (쉴드 TBM 세그먼트 지수재의 배열수 변화에 따른 방수성능 평가)

  • Ham, Soo-Kwon;Jung, Hoon;Kim, Beom-Ju;Jeong, Kyeong-han;Lee, Seok-Won
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.22 no.1
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    • pp.47-58
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    • 2020
  • The interest in the use of shield TBM (Tunnel Boring Machine) on the tunnel excavation has been increased rapidly in Korea. The shield TBM tunnel is generally designed as non-drainage tunnel. Consequently, if water leakage through the segment joints happens, big problems on the usage and stability of tunnel can be occurred. In this study, the variation of waterproof capacity of hydrophilic rubber waterstop by the construction error and excessive displacement of segment was studied. In particular, the waterproof capacity of each of single and double layer arrangements of hydrophilic rubber waterstop was examined to verify the efficiency of the double layer arrangement. The test results show that the single layer and double layer hydrophilic rubber waterstop showed the same waterproof performance. hydrophilic rubber waterstop has favorable on the offset, however unfavorable on the gap.

Study on Sebsea Pipeline Thermal Expansion (해저송유관의 열팽창 고찰)

  • 조철희;홍성근
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.11 no.1
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    • pp.1-6
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    • 1999
  • Nearshore and offshore pipelines are often applied to carry oil, gas, water and combined products. The thermal and pressure gradients of the fluid inside pipeline cause pipeline expansion. This expansion produces stress to connecting structures with pipeline. Should this stress exceeds the yield strength of connecting components or the allowable displacement of the system, a damage can occur. As most pipelines contain hazardous and toxic fluids, the damage usually leads to fatal accidents involving great economic loss as well. Even subsea pipelines can be easily applied to transport liquid type fluid without time and space constraint, they should be designed and maintained carefully to be functional safely during design lifetime. In this paper, various theories estimating pipeline thermal expansion are investigated and the effects of pipe components to expansion are studied.

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Measurements of Thermal Expansion Coefficients in GRP Pipe (GRP 복합관의 열팽창계수 측정)

  • Oh, Jin-Oh;Yoon, Sung-Ho
    • Composites Research
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    • v.25 no.1
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    • pp.26-30
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    • 2012
  • This study was focused on the measurement of thermal expansion coefficients for GRP pipe through strain gage circuits. First of all, thermal expansion coefficients of aluminum beam were measured to examine the validity of the suggested method by using various types of strain gage circuits. Thermal expansion coefficients of GRP pipes along axial and hoop directions were measured to investigate the effect of the location of strain gages, number of repeated measurements, and strain gage types with different thermal expansion coefficients on the thermal strains and the repeatability of measured results. According to the results, thermal expansion coefficients of GRP pipes along hoop direction were lower than those along axial direction due to the constraint effect of reinforced glass fibers on thermal strains along hoop direction. As measurements were repeated, thermal expansion coefficients of GRP pipes were slightly increased, but the degree of increase became smaller. Finally, the same thermal expansion coefficients were obtained irrespective of different types of strain gages with different thermal expansion coefficients if thermal strains of strain gages were compensated by using reference compensation specimen.

Physical Properties of Polypropylene Foam Blended with Thermally Expandable Microcapsules (열팽창캡슐 적용 발포폴리프로필렌의 물리적 특성 비교)

  • Ha, Jin Uk;Jeoung, Sun Kyung;Lee, Pyoung-Chan;Hwang, Ye Jin;Nam, Byung Kook;Han, In-Soo;Kwak, Sung Bok;Lee, Jae Yong
    • Polymer(Korea)
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    • v.39 no.1
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    • pp.64-70
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    • 2015
  • Thermally expandable microcapsules (TEMs) can be expanded upon heating since the activation energy of liquid hydrocarbon at the core of the TEMs increased at high temperature. Due to this property, TEMs are widely used in the industry as blowing agents or light-weight fillers. In this article, chemical blowing agent and TEM were used for making polypropylene (PP) foams, and their mechanical properties were compared. Physical properties (tensile strength, impact strength etc.) of PP foams decreased with increasing the amount of blowing agents while weight of specimen decreased. However, PP foam produced with TEMs showed higher impact strength than the one with a chemical blowing agent. In order to figure out the difference of impact strength, the morphology of PP foamed was investigated. Expanding properties of TEM can be controlled by changing core back distance.

Effect of Cristobalite and Quartz on the Compression Strength and Thermal Expansion Coefficients of Gold Alloy Investment Materials (금합금계 매몰재의 Cristobalite와 Quartz 첨가량에 따른 열팽창과 압축강도 변화)

  • Man-So Han
    • The Journal of Engineering Research
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    • v.6 no.2
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    • pp.141-151
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    • 2004
  • The physical properties of gold investment materials are depending on it's thermal expansion coefficients, compressive strength, and particles size distributions. Normally the gold investment materials are consisted of cristobalite, quartz and plaster. Since the thermal expansion coefficient of cristobalite and quartz are $2.6\times10^{-6}/^\circC$, $2.32\times10^{-6}/^\circC$, respectively, the composition ratio of each components influence the thermal and clinical properties of gold investment materials. Recently are imported from overseas and the commercial market is expected to expand. Thus it is necessary to develop the optimum strength and compressive strength of gold investment materials which the an homogeneous size distribution and thermal expansion coefficients. Therefore two different experiments has been done. Firstly the homogeneous cristobalite and quartz are made by pulverizing milling. Secondly the compressive strength and thermal expansion coefficients are analysed by the composition ratio of cristobalite and quartz. As a results of experiments, homogeneous distribution of cristobalite and quartz are observed by pulverizing and milling. The optimum compressive strength was obtained at the ratio of 45:25 cristobalite, quartz respectively.

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