• Journal of the Korean Electrochemical Society
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• v.22 no.3
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• pp.79-86
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• 2019

Most of low-grad heat (< $200^{\circ}C$) generated from industrial process and human body, is abandoned as waste heat. To harvest the waste heat, the thermoelectrics (TE) technology has been widely investigated so far. However, TE suffers from poor performance and high material cost. As an alternative to the TE device, the thermoelectrical cell (TEC) is gaining growing attention these days. The TEC features several advantages such as high Seebeck coefficient, low cost and design flexibility compared to TE, but its commercial viability was limited by its low heat-to-electricity conversion efficiency. However, recent reports have demonstrated that the performance of TEC can be markedly improved by employing novel electrode/electrolyte materials and by optimizing cell design. This article summarizes the recent progress of TECs in terms of the redox couples, electrolyte solvents and additives, electrode materials and cell design.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.40 no.11
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• pp.1010-1015
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• 2012

In this study, a thin-film thermo-electrochemical cell that directly converts waste thermal energy into electrical energy was fabricated. Electrical conductivity of conducting carbon fiber, which was used as flexible electrode, was increased through coating of carbon nanotube, and resistance of the CNT-coated fiber electrode was not changed even after bending test with various curvatures. Maximum output power of the thermocell was increased quadratically with the temperature difference, and showed a value of about 2.5 mW/kg at temperature difference of $3.4^{\circ}C$. As a result of discharge test for 12 hours, it is confirmed that the cell can operates continuously. And thin-film thermocell wrapped around a pipe with hot liquid flowing within was demonstrated. Internal resistance of the cell was decreased with various curvature of heat pipe, and maximum output power was increased by 30 %. Therefore, the cell can be applied to various heat source.

• Journal of the Korean Society of Propulsion Engineers
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• v.23 no.1
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• pp.116-123
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• 2019

Thermal batteries are also called molten-salt batteries as the electrolyte is mainly composed of molten salt. The molten-salt electrolyte is a solid that does not conduct electricity at room temperature, but when it is melted by a pyrotechnic heat source, it becomes an excellent ionic conductor. Thermal batteries are a kind of pyrotechnic battery because they operate only when the solid electrolyte is melted by the heat energy provided by pyrotechnic materials. Pyrotechnic components used in a thermal battery include heat sources, fuse strips, and an igniter. The reliability of these pyrotechnic components critically affects the reliability and performance of the battery that must supply electricity stably to guided munitions even under extreme environmental conditions. Different igniter types offer different advantages: notch-type igniters offer improved ignition probability, whereas film-type igniters offer improved safety. The addition of metal oxides to the heat paper could improve the burn rate, and the ignition reliability could be greatly improved by using it with a flame igniter at the same time. Using a two-step reduction process, high-purity Fe particles in coral form can be safely obtained.

• Journal of the Speleological Society of Korea
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• no.79
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• pp.41-46
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• 2007

지구자기장의 성인에 대하여 고찰하고 기존 학설에 대한 신 모델을 제안하였다. 지자기 성인의 가장 유력한 이론적 모델은 열전류와 열화학적 전류에 의한 자기장 형성이다. 하지만, 이 모델은 매우 한정적 조건을 바탕으로 설명하고 있으며, 동시에 지자기의 분산과 세기의 상쇄 요인을 내포하고 있기 때문에 설득력이 저하된다. 그러나 본 제안의 가설에서 주장하는 이온층 전류에 의한 지자기의 성인은 그와 같은 분산 요인이 있을 수 없으며, 그 결과로 나타나는 지자기의 새기와 방향도 일정하게 형성됨이 해석 가능하기 때문에 타당성과 설득력이 높은 완벽한 이론이다. 따라서 이온층 전류에 의한 보다 안정적인 지자기성인의 전자기학적 신 모델을 제안한다.

• Electrical & Electronic Materials
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• v.22 no.7
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• pp.24-33
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• 2009

• Proceedings of the Korean Vacuum Society Conference
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• 2013.02a
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• pp.661-661
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• 2013

열전재료는 열-전기가 상호 가역적으로 변하는 재료로서, 에너지 변환소재 분야에서 널리 각광받고 있다. 열전재료의 성능은 무차원 열전성능지수(dimensionless figure of merit, $ZT={\alpha}^2{\sigma}T/{\kappa}$)로 평가된다. 여기서 ${\alpha}$는 제벡계수(Seebeck coefficient), ${\sigma}$는 전기전도도(electrical conductivity), ${\kappa}$는 열전도도(thermal conductivity), T는 Kelvin 온도를 나타낸다. 500 K에서 800 K까지의 중온 영역에서 우수한 열전특성을 보이는 $Mg_2X$ (X=Si, Ge, Sn)와 이들의 고용체는 성분원소가 독성이 없고, 매장량이 많아 친환경 열전재료로 각광받고 있다. $Mg_2X$ 고용체 중 $Mg_2Si-Mg_2Sn$ 고용체는 Si와 Sn의 큰 원자량 차이로 인해 낮은 열전도도와 높은 성능지수(ZT)를 얻을 것이라 예상되며 열전발전 소자로서의 응용이 기대된다. Sb가 도핑된 $Mg_{2+x}Si_{0.7}Sn_{0.3}Sb_y$ (x=0, 0.1, 0.2, y=0, 0.01) 고용체를 고상합성과 기계적 합금화로 합성한 후, 진공 열간압축 성형을 통해 성공적으로 제조하였다. X선 회절분석으로 상합성과 고용체 형성 여부를 확인하였고, Mg의 과잉첨가와 Sb 도핑에 따른 열전특성의 변화를 조사하였다.

• Applied Chemistry for Engineering
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• v.29 no.6
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• pp.696-702
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• 2018

Recently, the current thermal battery technology needs new materials for electrodes in the power and energy density to meet various space and defense requirements. In this paper, to replace the pellet type Li(Si) anode having limitations of the formability and capacity, electrochemical properties of the lithium anode with high density for thermal batteries were investigated. The lithium anode (Li 17, 15, 13 wt%) was fabricated by mixing the molten lithium and iron powder used as a binder to hold the molten lithium at $500^{\circ}C$. The single cell with 13 wt% lithium showed a stable performance. The 2.06 V (OCV) of the lithium anode was significantly improved compared to 1.93 V (OCV) of the Li(Si) anode. Specific capacities during the first phase of the lithium anode and Li(Si) were 1,632 and $1,181As{\cdot}g^{-1}$, respectively. As a result of the thermal battery performance test at both room and high temperatures, the voltage and operating time of lithium anode thermal batteries were superior to those of using Li(Si) anode thermal batteries. The power and energy densities of Li anode thermal batteries were also remarkably improved.

• Journal of the Korea Institute of Military Science and Technology
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• v.11 no.1
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• pp.102-111
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• 2008

This paper describes the basic model and simulation results of thermal battery. Voltage and thermal analysis is a critical part of thermal-battery design because of the need to maintain the inner temperature above the electrolyte melting point. Traditionally, battery design has depended on an empirical approach, in which prototype batteries are outfitted with thermocouples and the design of subsequent batteries is refined accordingly. We have developed the basic model that allows the design engineer to configure or modify a battery, quickly conduct a thermal analysis, and efficiently review the results. Based on performance tests, the thermal-battery model was established and the effect of design parameters on battery performance was analyzed.

• Fire Science and Engineering
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• v.24 no.6
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• pp.98-103
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• 2010

A series of fire experiments have been performed to examine the measurement bias of the bare bead thermocouple widely used in fire testing and analyze the measurement bias of bare bead thermocouple comparing with the measured temperature using the aspirated thermocouple. The measured temperature of the bare bead thermocouple was lower than that of the aspirated thermocouple in the hot upper layer while it showed opposite trends in the upper layer. Also, the bare bead thermocouple showed higher measurement bias in the lower layer rather than upper layer in the compartment fire. The maximum relative percentage error of the bare bead thermocouple against the aspirated thermocouple reached 250% in the present study. The present study points out the need of correction process of the measured temperature by bare bead thermocouple for improving the reliability of the fire tests.

• Journal of the Korean Institute of Telematics and Electronics
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• v.5 no.1
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• pp.6-12
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• 1968

Experiments have been made on alloys to determine the practicability of using the Peltier effect in a thermoelectric devices. The cooling and heating results of thermoelectrie material coposed of n and p type BiTe are used, whose properties are; , , , , and K: thermal conductivity. The temperature of the cold part has been measured in veccum with respect to the temperature of the hot part. The experiment result agreed fairly with expectation such as was 42 degree C.