• Clean Technology
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• v.18 no.1
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• pp.57-62
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• 2012

Aqueous poly (vinyl alcohol) (PVA) solution was modified by using hydrophobic vinyltriethoxysilane (VTEOS) and then adding different amounts of poly (acrylic acid) (PAA) to the resulting solution. Thermal and mechanical properties, contact angle, water vapor transmission rate (MVTR) and oxygen gas transmission rate ($O_2TR$) of the film samples fabricated by these solutions were investigated. The glass transition temperature (Tg) of the VTEOS-modified films was sightly increased and the value remained unchanged according to the amount of PAA. The tensile strength of the VTEOS-modified films was found to be 9.48~10.72 $kg/mm^2$ which showed no significant difference compared with that of PVA. The film prepared with VTEOS-modified PVA/PAA (= 90/10), of which the swelling and solubility were measured to be 198% and 0%, respectively, showed improved water-resistance. The MVTR and $O_2TR$ for the PET film (thickness 50 ${\mu}m$) coated with VTEOS-modified PVA/PAA (= 90/10) film (thickness 2.5 ${\mu}m$) were measured to be 11.04 $g/m^2/day$ and 3.1 $cc/m^2/day$, respectively.

• Clean Technology
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• v.20 no.4
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• pp.415-424
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• 2014

In this study, two kinds of polymer (PPQX-2hdPTZ (P1), POPQX-2hdPTZ (P2)) were synthesised by Suzuki coupling reaction based on phenothiazine derivative as electron-donor and quinoxaline derivative as electron-acceptor. Microwave synthesis workstation was used to shorten the polymerization time and increase the degree of polymerization. The physical, thermal stability, optical and electrochemical properties of the synthesized polymer were confirmed. The thermal stability of two polymers was outstanding as the initial decomposition temperature was $323-328^{\circ}C$. And additional substituted alkoxy chain on P2 showed higher degree of polymerization. An analysis of electrochemical properties, all polymer had similar HOMO energy level values. Device was fabricated by ITO/PEDOT:PSS/active layer/$BaF_2$/Al structure and photovoltaic properties were confirmed. Each device has a different film thickness and the resulting change in PCE was confirmed. As a result the thinner thickness of the film showed a high efficiency ($PCE_{max}:P1=1.0%$, P2 = 1.1%).

• Management & Information Systems Review
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• v.35 no.2
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• pp.273-284
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• 2016

The objective of this study is to analyze the market efficiency in the futures markets. Although many previous studies have investigated market efficiency between spot and futures prices, that with different maturities has not been studied in the futures markets extensively. For our objective, this paper examines KOSPI200 stock index future market with different maturities. We analyze the dynamic serial relationship of the difference of basis between nearest-month contract and next nearest-month contract using dynamic regression analysis suggested by Kawamoto and Hamori(2011) Using the data from 2000. 1 to 2013. 12, the major empirical findings are as follows: First. the mean and standard deviation of basis of next nearest-month contract is bigger than those of nearest-month contract. Second, the t-period basis of nearest-month contract can be explained by (t-1)period basis of that. Third, the basis spread of t-period and (t-1)period have negative affect on the return of underlying assets. This result is very reasonable because two basis spreads are derived from same underlying assets. Finally, basis information of next nearest-month contract can be used for the prediction of nearest-month contract and spot market return.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.32 no.3C
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• pp.95-104
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• 2012

Due to current interest in creation of urban space and urban landscape, more emphasis has been placed on underground space development. With increasing number of underground power cables and its importance, a study of backfill materials for pipe is now imperative. Backfill materials require outstanding thermal characteristics since breakdown of cable insulation can be caused if heat generated from transmission of underground power cables had not been effectively discharged through backfill materials. Also, coal ash, which are industrial by-products, is being produced in high volume every year. Among them, ponded ash (PA) is not recycled and instead, mostly buried. Therefore in this study, thermal conductivity test based on mixture ratio (PA, ponded ash : FA, fly ash) was performed to evaluate the thermal conductivity characteristics of CLSM (controlled low strength materials) with coal ash. The results indicate that the mixture ratio (PA, ponded ash : FA, fly ash) of 80:20, water contents of 28~30%, and cement contents of 7-11% showed the highest conductivity at 0.796~0.884W/mK and thus, considered optimal in terms of recycling ponded ash (PA) as well as for maximizing utilization as backfill materials for pipe in underground.

• Journal of Advanced Marine Engineering and Technology
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• v.38 no.4
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• pp.367-375
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• 2014

In numbers of kinds of heat exchanger, the shell-tube heat exchanger is the most commonly used type of heat exchanger in the industry field. In order to improve the thermal performance of the heat exchanger, this study was analyzed heat transfer characteristics according to arrangement of baffle and direction of baffle and bump phase of baffle about shell-tube heat exchanger using appropriate SST (Shear Stress Transport) turbulence model for flow separation and boundary layer analysis. As the boundary condition for CFD (Computational Fluid Dynamics) analysis, the inlet temperature of shell side was constantly 344 K and the variation of the water flow rate was 6, 12, 18 and 24 l/min. As the result of analysis, zigzag baffle arrangement enhances heat transfer rate and pressure drop. Furthermore, in the direction of the baffle, heat transfer rate is more improved with vertical type and angle $45^{\circ}$ type than existing type, and pressure drop was little difference. Also, the bump shape of baffle surface contributes to heat transfer rate and pressure drop improvement due to the increased heat transfer area. Through analysis results, we knew that the increase of the heat transfer was influenced by flow separation, fluid residual time, contact area with the tube, flow rate, swirl and so on.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.34 no.3
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• pp.307-313
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• 2010

In this study, alternative designs for the bends used in district heating pipes are investigated. The district heating pipes, which are subjected to temperatures of 10 to $120^{\circ}C$ and a water pressure of $16\;kgf/cm^2$, have to withstand thermomechanical cyclic loads when in use. These pipes comprise three concentric tubes: a steel pipe (internal), polyurethane (PUR) insulator (middle), and a high-density polyethylene (HDPE) case (external). In addition, the bends in the district heating pipe system are covered with foam pads that cause aging. In this study, an alternative bend design that does not involve the use of a foam pad is proposed to overcome the aging problem in the bends. In the proposed design, "shear rings" are added to the surface of a bend, and its dimensions are determined by a combination of the statistical (Taguchi) method and FEM. The geometrical parameters such as thickness, height, and number of the rings significantly affect the design optimization, and hence, they affect the results of the FEM.

• Elastomers and Composites
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• v.34 no.2
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• pp.135-146
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• 1999

The thermal degradation kinetics of SBR and tire were studied using a conventional thermogravimetric analysis in the stream nitrogen at a heating rate of 5, 10, 15, $20^{\circ}C/min$, respectively. Thermogravimetric curves and their derivatives were analyzed using various analytical methods to determine the kinetic parameters. The degradation of the SBR and tire was found to be a complex process which has multi-stages. The Friedman method gave average activation energies for the SBR and tire of 247.53kJ/mol and 230.00kJ/mol, respectively. Mean-while, the Ozawa method Eave 254.80kJ/mol and 215.76kJ/mol. It would appear that either. Friedman's differential method or Ozawa's integral method provided satisfactory mathematical approaches to determine the kinetic parameters for the degradation of the SBR and tire. Approximately 86% and 55% of oil products were obtained at a final temperature of $700^{\circ}C$ and a heating rate of $20^{\circ}C/min$ for the SBR and tire respectively.

• Elastomers and Composites
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• v.34 no.1
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• pp.20-30
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• 1999

In this study, binary polyamide 6,6(PA 6,6)/ethylene-propylene rubber(EPM) or EPM-g-maleic anhydride(EPM-g-MA) blends and ternary PA 6,6/EPM/EPM-g-MA blends with various elastomer content were prepared in order to investigate the degree of influence of elastomer content and average particle size, morphology, and distribution of dispersed elastomer on mechanical and thermal properties of blends. According to the results, notched Izod impact strength and relative crystallinity of binary blends modified with EPM-g-MA as well as average particle size and distribution of dispersed elastomer in such blends were more improved than those of binary blends modified with EPM. Notched Izod impact strength of blend whose composition ratio(wt % ) was 70:30(PA 6,6 : EPM-g-MA) was the highest among the binary PA 6,6/EPM-g-MA blends. The impact strength was increased by 25 times and its relative crystallinity was increased by 7 times when compared with those of polyamide 6,6. In the case of ternary PA 6,6/EPM/EPM-g-MA blend of which composition ratio was 70:15:15(PA 6,6:EPM:EPM-g-MA), the elastomer was finely distributed with the average particle size of $0.56{\mu}m$. The Izod impact strength of this blend was the highest of all blends prepared with different elastomer content.

• The Journal of the Petrological Society of Korea
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• v.17 no.1
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• pp.1-15
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• 2008

The metasedimentary rocks of the Nampo Croup consisting of metaconglomerates, metasandstones, phyllites are exposed in the area of the Daechcon beach and Maryangri, Seocheon-gun. Their typical metamorphic assemblages of Bt-Mus-Grt-Qtz (${\pm}Pl{\pm}Chl$) and Bt-Mus-Qtz (${\pm}Pl{\pm}Chl$) indicate that they have been under intermediate P/T type metamorphism and were metamorphosed to garnet zone grade of amphibolite-facies during the Daebo Orogeny. Pressure-temperature conditions of peak metamorphism estimated from geothermobarometries are $560{\sim}595^{\circ}C$, $6.9{\sim}8.2\;kb$ respectively. The results of K-Ar biotite age determination are $143.2{\pm}3.6\;Ma$, $122.6{\pm}2.4\;Ma$ and $124.8{\pm}2.4\;Ma$ and the last two ages are considered as the results of later-stage thermal perturbation. On the bases of the formation age of Daedong Supergroup of $187{\sim}172\;Ma$ (Han et al., 2006; Jeon et al., 2007) combined with the results of this study, the hypothetical model of tectonometamorphic evolution of the study area during Daebo Orogeny is proposed. Crustal thickening resulted from folding and duplexing of thrusts in the area initiated at around 175 Ma just after sedimentation of Nampo Croup. And then rapid cooling by normal faulting due to crustal extention followed immediately after the peak metamorphism to the closure temperature of biotite.

• Journal of Digital Convergence
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• v.15 no.2
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• pp.67-80
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• 2017

Today, Emotional Intelligence of the leader has become important in order to achieve the achievement of the organization. Especially, the automobile industry is somewhat conservative and the organizational culture of the subcontractor is still much more important than the service industry which has a flexible. In this context, I examine the Emotional Intelligence on Organizational Citizenship Behavior and Innovative Behavior in manufacture of automobile industry focusing on moderating effect of Authentic Leadership. This Study enhances the understanding of Emotional Intelligence and extends the research. Future research will needed to pioneer research methods such as various aspects of measurement and time series of various variables.