• 한국신재생에너지학회:학술대회논문집
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• 2007.11a
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• pp.623-626
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• 2007

킬른형 열분해 반응기를 이용하여 혼합폐플라스틱의 열분해로부터 얻어진 고분자성분의 열적분해 특성에 관한 연구를 TGA와 GC-MS를 이용하여 수행하였다. 열적분해의 속도론적 연구는 $10{\sim}50^{\circ}C/min$ 사이의 여러 가열속도에서 비등온 질량감소 기술을 이용하여 수행하였으며 활성화 에너지 및 반응 차수와 같은 속도 상수들에 대한 정보를 얻기 위하여 문헌에 제시된 여러 가지의 속도론 해석방법을 이용하여 질량감소곡선 및 그 미분 값을 해석하였다. 또한 회분식 열분해 반응기를 이용하여 반응온도에 따른 액상 생성물의 수율변화를 고찰하였으며 GC-MS를 이용하여 액상 생성물의 반응온도 증가에 따른 특성연구를 수행하였다.

• Proceedings of the KWS Conference
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• 1997.10a
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• pp.68-73
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• 1997

• Proceedings of the Korean Society for Emotion and Sensibility Conference
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• 1999.11a
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• pp.7-12
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• 1999

본 연구에서는 14명의 남녀 대학생을 대상으로 열환경 챔버 내에서 여름철 열적 반응을 조사하였다. 여름철 온습도 범위에 해당하는 4가지 온도와 3가지 상대습도의 조합에 의한 8가지 조건에서 실험을 수행하였고, 주위 열환경에 대한 피험자의 심리적 반응을 살펴보기 위하여 전신온냉감과 쾌적감을 조사하였다. 조사결과를 국내 환경 실험실 연구 및 현장조사 결과와 비교하였고, 환경 실험실 연구 수행시의 문제점을 검토하였다.

• Korean Journal of Materials Research
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• v.5 no.5
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• pp.606-610
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• 1995

Diglycidyll ether of bisphenol A(DGEBA)/4, 4'-methylene dianiline(MDA)계에 반응성 첨가제 malononitrile(MN)을 첨가하면 내충격성은 크게 향상되나 반응속도는 감소하게 된다. 에폭시 수지의 경화반응은 에폭시기가 개환되어 생성되는 히드록시기가 촉매로 작용하는 자촉매 반응이며, 외부에서도입된 히드록시기도 같은 효과를 나타낸다. 따라서 본 연구에서는 DGEBA/MDA/MN 계의경화 반응속도를 증가시키기 위해 히드록시기를 가진 촉매로서 hydroquinone(HQ)을 도입하였고 이들 계의경화특성 및 열적성질을 고찰하였다. HQ가 첨가됨으로 인해 활성화 에너지는 감속하고 속도상수는 증가하였으며, 발열곡선에서 반응 시작온도가 낮아졌다. 이 결과로부터 HQ가 반응 가속제로 작용하고 있음을 알 수 있다.

• Proceedings of the KSME Conference
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• 2004.11a
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• pp.1063-1068
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• 2004

A numerical study is performed to predict the effect of operating conditions on the thermal response of electronic assemblies during infrared reflow soldering. The multimode heat transfer within the reflow oven as well as within the electronic assembly is simulated, and the predictions illustrate the detailed thermal responses. Parametric study is performed to determine the thermal response of electronic assemblies to various conditions such as conveyor speed, exhaust velocity, and component emissivity. The predictions of the detailed electronic assembly thermal response can be used in selecting the oven operating conditions to ensure proper soldering and minimization of thermally-induced electronic assembly stresses.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.14 no.1
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• pp.1-9
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• 2002

The thermal response of electronic components during infrared reflow soldering is studied by a two-dimensional numerical model. The convective, radiative and conduction heat transfer within the reflow oven as well as within the card assembly are simulated. Parametric study is also performed to determine the thermal response of electronic components to various conditions such as conveyor velocities, exhaust velocities and emissivities. The results of this study can be used in selecting the oven operating conditions to ensure proper solder melting and minimization of thermally induced card assembly stresses.

• Journal of the Korean Institute of Gas
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• v.17 no.4
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• pp.1-8
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• 2013

The aim of this study is to assess thermal hazards of polystyrene polymerization process by bulk polymerization with accelerating rate calorimeter(ARC) and Multimax reactor system(MM). From this study, we found out that the polymerization process should be operated at reaction temperature of $120^{\circ}C{\sim}130^{\circ}C$. At reaction temperature over $130^{\circ}C$, there was a runaway reaction hazard due to the temperature control failure following a viscosity increase of reaction products. With a cooling failure of a reactor in the early stage of process operation at the reaction temperature ($120^{\circ}C{\sim}130^{\circ}C$), there was a high thermal hazard of burst of a reactor's rupture disk or explosion of a reactor caused by the rapid rise of temperature and pressure to $340^{\circ}C$, 5.3 bar respectively within 30 - 50 minutes.

• Journal of Environmental Science International
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• v.5 no.5
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• pp.569-577
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• 1996

pure compound chloromethanes; methyl chloride, methylene chloride, chloroform and The carbon tetrachloride were used as a model of chlorocarbon system with Cl/H ratio to investigate thermal stability and hydrodechlorination process of carbon tetrachloride under excess hydrogen atmosphere. The parent thermal stability on basis of temperature required for 99% destruction at 1 second no was evaluated as $875^{\circ}C$ for $CH_3Cl$, $780^{\circ}C$ for $CH_2Cl_2$, $675^{\circ}C$ for $CHCl_3$ and $635^{\circ}C$ for $CCl_4$. Chloroform was thermally less stable than $CCl_4$ at fairly low temperatures $(<570^{\circ}C).$ The lion of $CCl_4$ became more sensitive to increasing temperature, and $CCl_4$ was degraded CHCl3 at above $570^{\circ}C.$ The number and quantity of chlorinated products decreases with increasing temperature for the Product distribution of $CCl_4$ decomposition reaction system. Formation of non-chlorinated hydrocarbons such as $CH_4$, $C_2H_4$ and C_2H_6$ increased as the temperature rise and particularly small amount of methyl chloride was observed above $850^{\circ}C$ in $CC1_4$/$H_2$ reaction system. The less chlorinated products are more stable, with methyl chloride the most stable chlorocarbon in this reaction system.

• Proceedings of the KIEE Conference
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• 2007.10c
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• pp.39-40
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• 2007

본 논문은 Slotless BLDCM의 발열특성에 고려하여 열 발생을 최소화 하고자 다중 반응표면법을 적용하여 모터의 형상 및 권선 사양의 최적 선정에 관한 연구이다. 본 연구에서는 전류밀도의 최소화를 목적함수로 하여 형상 및 권선 사양의 최적화를 실시하였다. 변수에 대한 영향도의 분석은 전자계 해석을 통한 결과값을 통하여 실시하였으며, 열적 특성을 파악하기 위해서 전자계-열계의 해석을 통해서 최적값의 열적 안정성을 파악하였다.

• Applied Chemistry for Engineering
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• v.17 no.3
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• pp.296-302
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• 2006

The kinetics of the thermal-oxidative decomposition of waste polyurethane (PU) according to oxygen concentration has been studied using a non-isothermal thermogravimetric technique at several heating rates from 10 to $50^{\circ}C/min$. A kinetic model accounting for the effects of the oxygen concentration by the differential and integral method based on Arrhenius equation was proposed to describe the thermal-oxidative decomposition of waste PU. To obtain the information on the kinetic parameters such as activation energy, reaction order, and pre-exponential factor, the thermogravimetric analysis curves and its derivatives have been analyzed using the kinetic analysis method proposed in this work. From this work, it was found that reaction orders for oxygen concentration had a negative sign, and activation energy decreased as the oxygen concentration increased. It was also found that the kinetic parameters obtained from the integral method using the single heating rate experiments varied with heating rates. Therefore, it is thought that the differential method using the multiple heating rate experiments more effectively represents the thermal-oxidative decomposition of waste polyurethane.