• Title/Summary/Keyword: 열역학법

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열/플라즈마 산화를 이용한 그래핀 내산화 특성 연구

  • Lee, Byeong-Ju;Jeong, Gu-Hwan
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.78-78
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    • 2010
  • 그래핀(Graphene)은 탄소원자가 육각형 벌집(honeycomb)구조로 빼곡히 채워진 2차원의 단원자 층으로 역학적 강도와 우수한 화학적/열적 안정성 및 흥미로운 전기 전도 특성을 가지고 있다. 이러한 그래핀의 우수한 특성으로 인하여 현재 기초연구뿐만 아니라 응용연구 등 많은 연구들이 진행되고 있다. 일반적으로 그래핀의 우수한 물리적 특성들은 그래핀의 층수, 모서리(edge)구조, 결함(defect), 불순물 등에 의해 크게 좌우되는 것으로 알려져 있다. 따라서 그래핀의 구조 및 결함정도를 자유로이 제어하고 그에 따르는 특성 변화를 관찰하는 것은 기초연구의 측면에서 뿐만 아니라 향후 그래핀 응용에 있어서도 매우 중요하다고 할 수 있다. 본 연구에서는 그래핀의 내산화 특성을 연구하기 위하여, 그래핀을 열 및 플라즈마 산화 분위기에 노출시킨 후, Raman 분광법을 이용하여 광학적, 구조적 변화를 분석함으로써 그래핀의 내산화 특성에 대하여 조사하였다. 그래핀은 실리콘 웨이퍼에 전자빔증착법으로 니켈박막을 증착한 후 열화학증기증착법으로 합성하였으며, 메탄가스를 원료가스로 $900^{\circ}C$ 전후에서 합성하였다. 합성한 그래핀은 산화반응 시 기판의 영향을 제거하기 위하여 트렌치 구조의 기판 위에 전사(transfer)함으로써 공중에 떠있는 구조를 구현하였다. 열 산화의 경우, 합성한 그래핀을 대기분위기의 고온($500^{\circ}C$) 챔버에 넣고 처리시간에 따른 특성변화를 살펴보았다. 플라즈마 산화의 경우는 공기를 이용하여 직류플라즈마를 발생시킨 후 0.4 W의 낮은 플라즈마 파워를 이용하여 플라즈마 산화처리와 특성평가를 매회 반복하였다. 그래핀의 특성분석은 Raman분광기와 광학현미경, 원자힘현미경(AFM) 등을 이용하여 분석하였으며, 상기 결과들은 향후 산화환경에서의 그래핀 응용소자 개발에 유용할 것으로 예상된다.

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Effect of Thermal Properties of Bentonite Buffer on Temperature Variation (벤토나이트 완충재의 열물성이 온도 변화에 미치는 영향)

  • Kim, Min-Jun;Lee, Seung-Rae;Yoon, Seok;Jeon, Jun-Seo;Kim, Min-Seop
    • Journal of the Korean Geotechnical Society
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    • v.34 no.1
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    • pp.17-24
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    • 2018
  • A buffer in a geological disposal system minimizes groundwater inflow from the surrounding rock and protects the disposed high-level waste (HLW) against any mechanical impact. As decay heat of a spent fuel causes temperature variation in the buffer that affects the mechanical performance of the system, an accurate estimation of the temperature variation is substantial. The temperature variation is affected by thermal and material properties of the system such as thermal conductivity, density and specific heat capacity of the buffer, and thus these factors should be properly included in the design of the system. In particular, as the thermal properties are variable depending on the density and water content of the buffer, consideration of the effects should be included in the analysis. Hence, in this study, a numerical model based on finite element method (FEM) which is able to consider the change of density and water content of the buffer was established. In addition, using the numerical model, a parametric study was conducted to investigate the effect of each thermal property on the temperature variation of the buffer.

핵융합로용 초전도 전자석 구조재의 파괴역학적 특성에 관한 연구

  • 김지현;황일순
    • Proceedings of the Korean Nuclear Society Conference
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    • 1997.05b
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    • pp.52-57
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    • 1997
  • 국제 열 핵융합로 (International Thermonuclear Experimental Reactor) 의 중앙 솔레노이드(solenoid) 초전도 전자석의 피복관 (conduit) 으로서 가장 유력한 후보 재료인 니켈-철 기저 초합금에 대한 개선된 파괴역학적 거동 예측 모형을 개발하기 위하여 피로균열 성장과 파괴 인성 치의 측정이 사용되었다. 유한 요소법을 사용하는 상용 구조해석 코드인 ANSYS 제 5.2판에 의해 초전도 전자석 피복관 재료에 대한 탄소성 파괴역학적 거동을 살펴보았다. 정확한 파괴 기준을 개발하기 위하여 삼차원 J 적분 인자에 의한 결과를 사용하였다. 얇은 피복관재의 경우에 절대온도 4도에서의 적합한 파괴 인성치는 실제 단면효과를 고려한 표면균열 인장시험 결과를 토대로 J 적분으로 도출한 150 MPaㆍm$^{1}$2/ 로 제시되었다.

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Numerical Study on the Characteristics of Thermal Plasmas Disturbed by Inserting a Langmuir Probe (랑뮤어 탐침에 의해 변형된 열플라즈마 특성에 관한 해석적 연구)

  • Lee, J.C.;Kim, Y.J.
    • Journal of the Korean Vacuum Society
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    • v.17 no.3
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    • pp.189-194
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    • 2008
  • Measurements with a Langmuir probe, which are the most often used procedures of plasma diagnostics, can disturb plasma flows and change its characteristics quite a little because the probe should be inserted into thermal flowing plasmas. In this study, we calculated the characteristics of thermal plasmas with and without the probe into an atmospheric argon free-burning arc numerically, and investigated aerodynamic and thermal disturbances with temperature and axial velocity distributions. For the modelling of thermal plasmas, we have made two governing equations, which are on the thermal-flow and electromagnetic fields, coupled together with a commercial CFD package and user-coded subroutines. It was found that thermal disturbances happened to both sides of the probe, before and behind, seriously. Due to the aerodynamic disturbance, we could find that there were the stagnation point in front of the probe and the wake behind it. Therefore, aerodynamic and thermal disturbances caused by the probe insertion should be considered to increase the reliability of the probe diagnostics.

Variations of Turbulent Fluxes in the Atmospheric Surface Layer According to the Presence of Cloud (구름 유무에 따른 대기표층 난류속의 변화)

  • de Oliveira Junior, Jose Francisco;Kwon, Byung-Hyuk
    • Journal of the Korean earth science society
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    • v.25 no.2
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    • pp.87-93
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    • 2004
  • To study the effect of cloud on the variabilities of turbulent fluxes over the flat terrain, we used the gradient method to analyze the dynamic and thermodynamic data from the meteorological 9-m mast (0.75, 3 and 9 m) in Villafria airport in Spain. The decrease of the surface wind speed is governed by cooling at the surface following the evening transition. The sensible heat flux and the momentum flux are increased with the dynamic factor rather than the thermodynamic factor, and the sensible heat flux was not affected by the thermal condition. The global radiation did not play an important role in the variation of the sensible heat flux in the cloudy day, but the atmospheric surface layer was characterized rather by the wind intensity.

Analysis on Thermal Structural Characteristics of Thermal Protection System Panel for a High-speed Vehicle (초고속 비행체 열방어 시스템 패널의 열구조 특성 분석)

  • Lee, Heesoo;Kim, Yongha;Park, Jungsun;Goo, Namseo;Kim, Jaeyoung
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2017.05a
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    • pp.942-944
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    • 2017
  • High-speed vehicles are subjected to complex loads, such as acoustic pressure from the engine at launch and aerodynamic heating and aerodynamic pressure during flight. A thermal protection system panel is required to protect internal systems such as the fuel tank of the vehicle from the external environment. This study defines analytical models for heat transfer and thermal structure characteristics of the thermal protection system panel. Furthermore, the study performed parameters analysis to achieve the thermal structural integrity and to make it lighter.

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A Finite Element Analysis of Deformation-Induced Heating in Tensile Testing of Sheet Metals (박판 인장 시험에서 가공열의 영향에 관한 유한요소 해석)

  • ;Wagoner, R.H.
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.13 no.4
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    • pp.680-688
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    • 1989
  • A numerical method for analyzing non-isothermal plastic deformation of sheet metals has been developed and sheet tensile tests have been analyzed using a two-dimensional finite element formulation. A modified Bishop`s method is used to solve the thermoplasticity problem in decoupled form at each time step. The accuracy of the analysis is confirmed by comparison with experimental data. The uniform elongation is found is drop by 0.1 to 2.7% at moderate strain rates, while total elongation decreases upto 6.0% during tensile testing in air compared to the isothermal case. The effect of deformation heating, becomes more pronounced as necking develops and at higher testing speed.

A Novel Method for In Situ Stress Measurement by Cryogenic Thermal Cracking - Concept Theory and Numerical Simulation (저온 열균열 현상을 이용한 초기 응력 측정법 - 개념, 이론 및 수치해석)

  • Ryu, Chang-Ha;Ryu, Dong-Woo;Choi, Byung-Hee;Synn, Dong-Ho;Loui, John P.
    • Tunnel and Underground Space
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    • v.18 no.5
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    • pp.343-354
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    • 2008
  • A new method is suggested herein to measure the virgin earth stresses by means of a borehole. This novel concept is basically a combination of borehole stress relieving and borehole fracturing techniques. The destressing of the borehole is achieved by means of inducing thermal tensile stresses at the borehole periphery by using a cryogenic fluid such as Liquid Nitrogen($LN_2$). The borehole wall eventually develops fractures when the induced thermal stresses exceed the existing compressive stresses at the borehole periphery in addition to the tensile strength of the rock. The above concept is theoretically analyzed for its potential applicability to interpret in situ stress levels from the tensile fracture stresses and the corresponding borehole wall temperatures. Coupled thermo-mechanical numerical simulations are also conducted using FLAC3D, with thermal option, to check the validity of the proposed techniques. From the preliminary theoretical and numerical analysis, the method suggested for the measurement of in situ stresses appears to be capable of accurate estimation of the virgin stresses by monitoring tensile crack formation at a borehole wall and recording the wall temperatures at the time of crack initiation.

Formulation of Fully Coupled THM Behavior in Unsaturated Soil (불포화지반에 대한 열-수리-역학 거동의 수식화)

  • Shin, Ho-Sung
    • Journal of the Korean Geotechnical Society
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    • v.27 no.3
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    • pp.75-83
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    • 2011
  • Emerging issues related with fully coupled Thermo-Hydro-Mechanical (THM) behavior of unsaturated soil demand the development of a numerical tool in diverse geo-mechanical and geo-environmental areas. This paper presents general governing equations for coupled THM processes in unsaturated porous media. Coupled partial differential equations are derived from three mass balances equations (solid, water, and air), energy balance equation, and force equilibrium equation. With Galerkin formulation and time integration of these governing equations, finite element code is developed to find nonlinear solution of four main variables (displacement-u, gas pressure-$P_g$), liquid pressure-$P_1$), and temperature-T) using Newton's iterative scheme. Three cases of numerical simulations are conducted and discussed: one-dimensional drainage experiments (u-$P_g-P_1$), thermal consolidation (u-$P_1$-T), and effect of pile on surrounding soil due to surface temperature variation (u-$P_1$-T).

Fiber Orientation and Warpage of Film Insert Molded Parts with Glass Fiber Reinforced Substrate (유리섬유가 강화된 필름 삽입 사출품의 섬유배향 및 휨)

  • Kim, Seong-Yun;Kim, Hyung-Min;Lee, Doo-Jin;Youn, Jae-Ryoun;Lee, Sung-Hee
    • Composites Research
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    • v.25 no.4
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    • pp.117-125
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    • 2012
  • Warpage of the film insert molded (FIM) part is caused by an asymmetric residual stress distribution. Asymmetric residual stress and temperature distribution is generated by the retarded heat transfer in the perpendicular direction to the attached film surface. Since warpage was not prevented by controlling injection molding conditions, glass fiber (GF) filled composites were employed as substrates for film insert molding to minimize the warpage. Distribution of short GFs was evaluated by using micro-CT equipment. Proper models for micro mechanics, anisotropic thermal expansion coefficients, and closure approximation should be selected in order to calculate fiber orientation tensor and warpage of the FIM part with the composite substrate. After six kinds of micro mechanics models, three models of the thermal expansion coefficient and five models of the closure approximation had been considered, the Mori-Tanaka model, the Rosen and Hashin model, and the third orthotropic closure approximation were selected in this study. The numerically predicted results on fiber orientation tensor and warpage were in good agreement with experimental results and effects of GF reinforcement on warpage of the FIM composite specimen were identified by the numerical results.