DOI QR코드

DOI QR Code

Fiber Orientation and Warpage of Film Insert Molded Parts with Glass Fiber Reinforced Substrate

유리섬유가 강화된 필름 삽입 사출품의 섬유배향 및 휨

  • Received : 2012.05.30
  • Accepted : 2012.07.27
  • Published : 2012.08.31

Abstract

Warpage of the film insert molded (FIM) part is caused by an asymmetric residual stress distribution. Asymmetric residual stress and temperature distribution is generated by the retarded heat transfer in the perpendicular direction to the attached film surface. Since warpage was not prevented by controlling injection molding conditions, glass fiber (GF) filled composites were employed as substrates for film insert molding to minimize the warpage. Distribution of short GFs was evaluated by using micro-CT equipment. Proper models for micro mechanics, anisotropic thermal expansion coefficients, and closure approximation should be selected in order to calculate fiber orientation tensor and warpage of the FIM part with the composite substrate. After six kinds of micro mechanics models, three models of the thermal expansion coefficient and five models of the closure approximation had been considered, the Mori-Tanaka model, the Rosen and Hashin model, and the third orthotropic closure approximation were selected in this study. The numerically predicted results on fiber orientation tensor and warpage were in good agreement with experimental results and effects of GF reinforcement on warpage of the FIM composite specimen were identified by the numerical results.

필름 삽입 사출 시편의 휨은 비대칭적인 잔류응력 분포에 기인한다. 비대칭적 잔류응력과 온도 분포는 삽입된 필름 표면의 수직방향으로 지연되는 열 전달에 의해 발생한다. 사출 공정조건 최적화를 통해 필름 삽입 사출 시편의 휨을 억제할 수 없었기 때문에, 필름 삽입 사출 시편의 휨을 최소화하기 위해서 유리 섬유가 강화된 복합재료를 기판으로 사용하였다. 유리 단섬유의 분포를 마이크로 CT 장비를 이용하여 평가하였다. 복합재료로 구성된 기판을 이용한 필름 삽입 사출 시편의 배향 텐서와 휨을 계산하기 위해서는 적절한 마이크로 역학, 이방적 열팽창계수 및 닫힌 어림법 모델이 선택되어야만 한다. 여섯 종류의 마이크로 역학모델, 세 종류의 열 팽창 계수 모델 및 다섯 종류의 닫힌 어림법 모델을 고려한 후, Mori-Tanaka 모델, Rosen and Hashin 모델 및 third orthotropic 닫힌 어림법 모델을 선택하였다. 수치적으로 계산된 섬유 배향 텐서와 휨에 관한 결과들은 실험결과와 잘 일치하였고, 유리 섬유의 보강효과가 필름 삽입 사출 복합 재료 시편의 휨에 미치는 영향을 파악하였다.

Keywords

References

  1. Leong, Y.W., Kotaki, M., and Hamada, H., "Effects of the Molecular Orientation and Crystallization on Film-Substrate Interfacial Adhesion in Poly(ethylene terephthalate) Film-Insert Moldings," Journal of Applied Polymer Science, Vol. 104, 2007, pp. 2100-2107. https://doi.org/10.1002/app.25620
  2. Kim, S.Y., Lee, J.T., Kim, J.Y., and Youn, J.R., "Effects of Film and Substrate Dimensions on Warpage of Film Insert Molded Parts," Polymer Engineering and Science, Vol. 50, 2010, pp. 1205-1213. https://doi.org/10.1002/pen.21649
  3. Kim, S.Y., Kim, S.H., Oh, H.J., Lee, S.H., and Youn, J.R., "Residual Stress and Viscoelastic Deformation of Film Insert Molded Automotive Parts," Journal of Applied Polymer Science, Vol. 118, 2010, pp. 2530-2540. https://doi.org/10.1002/app.32371
  4. Kim, S.Y., Oh, H.J., Kim, S.H., Kim, C.H., Lee, S.H., and Youn, J.R., "Prediction of Residual Stress and Viscoelastic Deformation of Film Insert Molded Parts," Polymer Engineering and Science, Vol. 48, 2008, pp. 1840-1847. https://doi.org/10.1002/pen.21152
  5. Kim, S.Y., Kim, S.H., Oh, H.J., Lee, S.H., Baek, S.J., Youn, J.R., Lee, S.H., and Kim, S.-W., "Molded Geometry and Viscoelastic Behavior of Film Insert Molded Parts," Journal of Applied Polymer Science, Vol. 111, 2009, pp. 642-650.
  6. Kim, S.Y., Lee, S.H., Baek, S.J., and Youn, J.R., "Thermoviscoelastic Behavior of Film-insert-Molded Parts Prepared under Various Processing Conditions," Macromolecular Materials and Engineering, Vol. 293, 2008, pp. 969-978. https://doi.org/10.1002/mame.200800193
  7. Baek, S.J., Kim, S.Y., Lee, S.H., Youn, J.R., and Lee, S.H., "Effect of Processing Conditions on Warpage of Film Insert Molded Parts," Fibers and Polymers, Vol. 9, No. 6, 2008, pp. 747-754. https://doi.org/10.1007/s12221-008-0117-y
  8. Kim, S.Y., Lee, S.H., and Youn, J.R., "Warpage of Film Insert Molded Parts and Optimum Processing Conditions," International Polymer Processing, Vol. XXV, No. 2, 2010, pp. 109-117. https://doi.org/10.3139/217.2269
  9. Kennedy, P., Flow Analysis Reference Manual, Moldflow Pty. Ltd., Kilsyth, Australia, 1993.
  10. Macosko, C.W., Rheology, Principles, Measurements, and Applications, Wiley-VCH, New York, 1994.
  11. Advani, S.G., and Tucker III, C.L., "The use of Tensors to Describe and Predict Fiber Orientation in Short Fiber Composites," Journal of Rheology, Vol. 31, No. 8, 1987, pp. 751-784. https://doi.org/10.1122/1.549945
  12. Folgar, F., and Tucker III, C.L., "Orientation Behavior of Fibers in Concentrated Suspensions," Journal of Reinforced Plastics and Composites, Vol. 3, 1984, pp. 98-119. https://doi.org/10.1177/073168448400300201
  13. Zheng, R., Kennedy, P., Phan-Thien, N., and Fan, X-J., "Thermoviscoelastic simulation of thermally and pressureinduced stresses in injection moulding for the prediction of shrinkage and warpage for fibre-reinforced thermoplastics," Journal of Non-Newtonian Fluid Mechanics, Vol. 84, 1999, pp. 159-190. https://doi.org/10.1016/S0377-0257(98)00148-7
  14. Doi, M., "Molecular Dynamics and Rheological Properties of Concentrated Solutions of Rodlike Polymers in Isotropic and Liquid Crystalline phases," Journal of Polymer Science: Polymer Physics Edition, Vol. 19, 1981, pp. 229-243. https://doi.org/10.1002/pol.1981.180190205
  15. Hinch, E.J., and Leal, L.G.., "Constitutive equations in suspension mechanics. Part 2. Approximate forms for a suspension of rigid particles affected by Brownian rotations," Journal of Fluid Mechanics, Vol. 76, 1976, pp. 187-208. https://doi.org/10.1017/S0022112076003200
  16. Cintra Jr. J.S., and Tucker III, C.L., "Orthotropic closure approximations for flow-induced fiber orientation," Journal of Rheology, Vol. 39, No. 6, 1995, pp. 1095-1122. https://doi.org/10.1122/1.550630
  17. Kinloch, A.J., and Taylor, A.C., "The mechanical properties and fracture behavior of epoxy-inorganic micro- and nano-composites," Journal of Materials Science, Vol. 41, 2006, pp. 3271-3297. https://doi.org/10.1007/s10853-005-5472-0
  18. Ahmed, S., and Jones, F.R., "A review of particulate reinforcement theories for polymer composites," Journal of Materials Science, Vol. 25, 1990, pp. 4933-4942. https://doi.org/10.1007/BF00580110
  19. Cox, H.L., "The elasticity and strength of paper and other fibrous materials," British Journal of Applied Physics, Vol. 3, 1951, pp. 72-79.
  20. Krenchel, H., Fibre reinforcement - Theoretical and practical investigations of the elasticity and strength of fibre-reinforced materials, Akademisk Forlag, Copenhagen, 1964.
  21. Van Den Oever, M.J.A., Bos, H.L., and Van Kemenade, M.J.J.M., "Influence of the physical Structure of Flax Fibres on the Mechanical Properties of Flax Fibre Reinforced Polypropylene Composites," Applied Composite Materials, Vol. 7, 2000, pp. 387-402. https://doi.org/10.1023/A:1026594324947
  22. Tekkanat, B., and Gibala, R., "Short Fiber Reinforced Thermoplastics: Prediction of Stiffness in Injection Molded PS-PPO Blends," Journal of Thermoplastic Composite Materials, Vol. 4, 1991, pp. 190-204. https://doi.org/10.1177/089270579100400205
  23. Halpin, J.C., and Kardos, J.L., "The Halpin-Tsai Equations: A Review," Polymer Engineering and Science, Vol. 16, No. 5, 1976, pp. 344-352. https://doi.org/10.1002/pen.760160512
  24. Tandon, G.P., and Weng, G.J., "The Effect of Aspect Ratio of Inclusions on the Elastic Properties of Unidirectionally Aligned Composites," Polymer Composites, Vol. 5, No. 4, 1984, pp. 327-333. https://doi.org/10.1002/pc.750050413
  25. Tucker III, C.L., and Liang E., "Stiffness predictions for unidirectional short-fiber composites: Review and evaluation," Composites Science and Technology, Vol. 59, 1999, pp. 655-671. https://doi.org/10.1016/S0266-3538(98)00120-1
  26. Shapery, R.A., "Thermal Expansion Coefficients of Composite Materials Based on Energy Principles," Journal of Composite Materials, Vol. 2, No. 3, 1968, pp. 380-404. https://doi.org/10.1177/002199836800200308
  27. Bowles, D.E., and Tompkins, S.S., "Prediction of Coefficients of Thermal Expansion for Unidirectional Composites," Journal of Composites Materials, Vol. 23, 1989, pp. 370-388. https://doi.org/10.1177/002199838902300405
  28. Sideridis, E., "THERMAL EXPANSION COEFFICIENTS OF FIBER COMPOSITES DEFINED BY THE CONCEPT OF THE INTERPHASE," Composites Science and Technology, Vol. 51, 1994, pp. 301-317. https://doi.org/10.1016/0266-3538(94)90100-7
  29. Rogers, K.F., Phillips, L.N., Kingston-Lee, D.M., Yates, B., Overy, M.J., Sargent, J.P., and Mccalla, B.A., "The thermal expansion of carbon fibre-reinforced plastics Part 1 The influence of fibre type and orientation," Journal of Materials Science, Vol. 12, 1977, pp. 718-734. https://doi.org/10.1007/BF00548162
  30. Adams, D.F., and Crane, D.A., "Combined loading micromechanical analysis of a unidirectional composite,: Composites," Vol. 15, No. 3, 1984, pp. 181-192. https://doi.org/10.1016/0010-4361(84)90273-8
  31. Rosen, B.W., and Hashin, Z., "EFFECTIVE THERMAL EXPANSION COEFFICIENTS AND SPECIFIC HEATS OF COMPOSITE MATERIALS," International Journal of Engineering Science, Vol. 8, 1970, pp. 157-173. https://doi.org/10.1016/0020-7225(70)90066-2
  32. Hashin, Z., "Analysis of properties of fiber composites with anisotropic constituents," Journal of Applied Mechanics, Vol. 46, 1979, pp. 543-550. https://doi.org/10.1115/1.3424603
  33. Karadeniz, Z.H., and Kumlutas, D., "A numerical study on the coefficients of thermal expansion of bier reinforced composite materials," Composite Structures, Vol. 78, 2007, pp 1-10. https://doi.org/10.1016/j.compstruct.2005.11.034
  34. Santhanam, N., Chiang, H.H., Himasekhar, K., Tuschak, K.P., and Wang, K.K., "Postmolding and Load-Induced Deformation Analysis of Plastic Parts in the Injection Molding Process," Advanced Polymer Technology, Vol. 11, 1991, pp. 77-89. https://doi.org/10.1002/adv.1991.060110201
  35. Kim, S.Y., Residual stress and deformation analysis of film insert injection molding, Seoul National University, Seoul, 2010.
  36. Youn, J.Y., Kim, S.W., Park, B.H., Lee, S.H., Kwon, T.H., and Kim, K.T., "A Study on the Structure Analysis System for Short Fiber Reinforced Plastics," Journal of the Korean Society for Composite Materials, Vol. 24, No. 4, 2011, pp. 41-47. https://doi.org/10.7234/kscm.2011.24.4.041
  37. Leong, Y.W., Umemura, T., and Hamada, H., "Film Insert Molding as a Novel Weld-Line Inhibition and Strenghening Technique," Polymer Engineering and Science, Vol. 48, 2008, pp. 2147-2158. https://doi.org/10.1002/pen.21157

Cited by

  1. Development of a Prediction Model for the Mechanical Properties of Polypropylene Composites Reinforced by Talc and Short Glass Fibers vol.26, pp.4, 2013, https://doi.org/10.7234/composres.2013.26.4.245