• Title/Summary/Keyword: 열분해유

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Lipolytic Effect of Sparassis crispa Extracts in Differentiated 3T3-L1 Cells and High Fat Diet-induced Obese Mice (분화된 3T3-L1 세포와 비만유도 쥐에 꽃송이버섯 추출물의 지질분해 효과)

  • Lee, Mi-Ae;Park, Jin-Kyung;Um, Mi-Hyang;Jeon, Jung-Woo;Lee, Jung-Min;Park, Yoo-Kyoung
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.41 no.12
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    • pp.1708-1715
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    • 2012
  • The purpose of this study was to investigate whether water extracts of Sparassis crispa (SC) have anti-obesity effects. Treatment of mature adipocytes with SC caused a decrease in lipid accumulation (assessed by Oil Red O staining) and an increase in glycerol release. Mice were induced to obesity by a high fat diet (45% fat in total kcal) and experimental groups were treated with two different dosages of SC extracts, a low SC (LSC, 100 mg/kg/day) or high SC (HSC, 300 mg/kg/day). SC extracts were administered by gavages for 10 weeks in the experimental groups, while the control group was fed with distilled water. The body weight gain of mice fed SC was significantly reduced (11.88% lower in LSC, 14.54% lower in HSC) compared to the control group. Additionally, there were significantly reduced serum levels of triglycerides (13.57% lower in LSC, 19.46% lower in HSC), total cholesterol (32.22% lower in LSC, 24.67% lower in HSC) and glucose (28.85% lower in LSC, 25.82% lower in HSC) in mice fed SC compared to the control group. Hepatic triglycerides in mice fed SC were lower (9.68% lower in LSC, 14.24% lower in HSC) than the control group and total cholesterol levels were also lower in mice fed SC (38.72% lower in LSC, 35.20% in HSC). These results demonstrate that the water extract of SC may enhance lipolysis and up-regulate the expression of lipolytic enzymes in vitro and reduce body weight in vivo. These significant effects were found for both low and high doses of SC treatment, and suggest SC can be used as potential therapeutic substances for the prevention and treatment of obesity.

A Study on the Carbothermic Reduction and Refining of V, Ta and B Oxides by Ar/Ar-H2 Plasma (Ar/Ar-H2 플라즈마에 의한 V, Ta, B 산화물의 탄소용융환원 및 정련)

  • Chung, Yong-Sug;Park, Byung-Sam;Hong, Jin-Seok;Bae, Jung-Chan;Kim, Moon-Chul;Baik, Hong-Koo
    • Journal of Hydrogen and New Energy
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    • v.7 no.1
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    • pp.81-92
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    • 1996
  • The Ar/Ar-$H_2$ plasma method was applied to reduce oxides and refine metals of V, Ta and B. In addition, the high temperature chemical reaction in Ar plasma and of the refining reaction in the Ar-(20%)$H_2$ plasma were analyzed. The crude V of 96wt% purity was obtained at the ratio of $C/V_{2}O_{5}=4.50$ by the Ar plasma reduction grade and the maximum reduction was obtained at $C/V_{2}O_{5}=4.50$ due to the $O_{2}$ loss from the thermal decomposition of vanadium oxide. In the Ar-(20%)$H_2$ plasma refining, the metallic V of 99.2wt% was produced at the ratio of $C/V_{2}O_{5}=4.40$. It was considered that a main refining reaction resulted from the chemical reaction between the residual carbon and residual oxygen. The metallic Ta of 99.8wt% was obtained at the ratio of $C/Ta_{2}O_{5}=5.10$ in a Ar plasma reduction and the Oz loss from the thermal decomposition of tantalum pentoxide did not take place. The deoxidation reaction was more significant than the decarburization reaction in the Ar-(20%)$H_2$ plasma refining and the metallic Ta of 99.9wt% was produced within the range of $C/Ta_{2}O_{5}$ ratio of 4.50 to 5.10. The Vickers hardness of Ta in the above mentioned range was about 220Hv due to the decrease in a residual oxygen by the deoxidation reaction. On the other hand, C is no suitable agent for the reduction of $B_{2}O_{3}$ by the Ar and Ar-$H_2$ plasma. But Fe-B-Si alloy was produced with the reduction of $B_{2}O_{3}$ in the melt when Fe, C, $B_{2}O_{3}$, and ferroboron mixtures were melted by the high frequency induction melting.

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A Study on the analysis method and composition characteristics of organic materials in the pottery excavated at the palace site in Yongjangseong Fortress, Jindo (진도 용장성 왕궁지 출토 도기호 내부 유기물의 분석법과 성분 특성 연구)

  • YUN Eunyoung;YU Jia;KIM Kyuho
    • Korean Journal of Heritage: History & Science
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    • v.56 no.3
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    • pp.158-171
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    • 2023
  • Pottery filled with organic materials was excavated from the G-2 building site of Yongjangseong Fortress, Jingo, a relic of the Goryeo Dynasty. In this study, the characteristics of organic material were confirmed by a scientific analysis of organic material in pottery found at the palace in Yongjangseong, Jindo. In addition, it was intended to review the analysis method to identify the natural resin and to secure characteristic components(biomarkers) for each natural resin and use them as basic data in the future. The organic materials in the pottery were analyzed using attenuated total reflectance Fourier-transformed infrared spectroscopy(ATR-FTIR) and gas chromatography mass spectrometry(GC-MS). The infrared spectral characteristics were estimated to be natural resin, and biomarkers of organic materials were identified as sesquiterpene-based compounds(C15H24, MW 204) and derivatives. The lacquer(T.vemicifluum) is composed mainly of alkenes, alkanes, and catechol. Pine resin(P.densiflora), on the other hand, is primarily composed of diterpenoid(abietic acid, pimaric acid) and Whangchil(yellow lacquer) is identified to have sesquiterpenes(such as selinene, muurolene, calamenene) as its main components. So, the organic material in the pottery can be identified as Whangchil by comparing their compounds with modern resin materials from Dendropanax. morbifera that correspond with the results. Whangchil, which is exuded from the Dendropanax. morbifera, has been used as a natural coating materials since ancient times, and it has been confirmed that the characteristic components are well preserved even 700 years later. It can be assumed that the interior Whangchil was stored not for use as a coating, but rather for ritual purposes when the building was constructed, because the pottery was found near the cornerstone. Furthermore, based on simplified sample preparation using pyrolysis-gas chromatography mass spectrometry(Py-GC-MS), the thermal decomposition products were found to be similar to the characteristic components, suggesting that this method can be applied to the identification of natural resins used in historic artifacts.

Characteristics of Membrane Permeability on the Separation of Solid in a Liquid Livestock Manure (축분액비의 고액분리에 있어서 분리막의 투과특성)

  • 황명구;차기철;이명규
    • Journal of Animal Environmental Science
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    • v.6 no.3
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    • pp.175-184
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    • 2000
  • A lab-scale MF membrane reactor was installed to investigate the membrane permeability, characteristics of membrane fouling at each conditions, and quality of permeate (liquid livestock manure) in the separation of solid-matters using membrane. Experiment was divided three filtration type such as follows; continuous filtration, gravity filtration, and intermittent filtration. As a result of experiment, flux 1 LMH was maintained for 7days, and trans-membrane pressure(TMP) was increased gradually under 10cmHg, but it was increased immediately after 10cmHg, respectively. However, the flux was increased, the Tmax was decreased exponential more and more. During the pure-flux test, most of the fouling of membrane was reversible. At the gravity filtration, permeate could be obtained as 1.75 LMH for 3.5days without any other electronic pressure. As an investigation of membrane surface, this study could be decided that the reason of fouling at the lower flux (Run 1 and 2) was attached matters in membrane surface, but at the higher flux (Run 4-6) was concentration polarization.

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Analysis of Waterborne Automotive Refinish Paint for Investigating Insurance Fraud (차량 보수도장 보험사기 규명을 위한 수용성 페인트 성분분석)

  • Lee, Joon-Bae;Lee, Cheon-Ho;Ryu, Seung-Jin;Gong, Bokyoung;Kwon, O-Seong;Kim, Myung-Duck;Kim, Nam Yee;Paeng, Ki Jung
    • Applied Chemistry for Engineering
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    • v.28 no.4
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    • pp.490-494
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    • 2017
  • With increasing the number of vehicles, the accident rate also goes up and the damaged vehicles should be painted as a final repair process. At the painting stage the solvent-based paint causes environmental problems. To overcome these problems waterborne refinish paint is frequently used recently. However, for waterborne refinish, the costs of insurance coverage are too expensive, and insurance reimbursement costs could be burdensome. Because of the high price of aquatic paint treatment, the service shop might charge the malicious service price. In this study, the surfactant of Surfynol 104, which is the component in the paint, was used as an indicator whether the vehicle was painted with waterborne paint. The specimen was quantitatively analyzed to contain 0.38% of the surfactant through the standard addition method with isotope substituted internal standard (IS) of fluranthene-d10 by curie point pyrolysis-gas chromatography/mass spectrometry (Py-GC/MS).

Preparation of Hard Coating Films with High Refractive Index from TiO2-SnO2 Nanoparticles (TiO2-SnO2 나노입자로 부터 고굴절 하드코팅 도막의 제조)

  • Ahn, Chi Yong;Kim, Nam Woo;Song, Ki Chang
    • Korean Chemical Engineering Research
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    • v.53 no.6
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    • pp.776-782
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    • 2015
  • $TiO_2-SnO_2$ nanoparticles with an average diameter of 3~5 nm were synthesized by hydrolysis of titanium tetraisopropoxide (TTIP) and tin chloride to depress the photocatalytic activity of $TiO_2$ nanoparticles. Organic-inorganic hybrid coating solutions were prepared by reacting the $TiO_2-SnO_2$ nanoparticles with 3-glycidoxypropyl trimethoxysilane (GPTMS) by the sol-gel method. The hard coating films with high refractive index were obtained by curing thermally at $120^{\circ}C$ after spin-coating the coating solutions on the polycarbonate (PC) sheets. The coating films from $TiO_2-SnO_2$ nanoparticles showed an improved pencil hardness of 3H compared to 2H of the coating films from $TiO_2$ nanoparticles. Besides, the refractive index of the coating films from $TiO_2-SnO_2$ nanoparticles enhanced from 1.543 to 1.623 at 633 nm as the Sn/Ti molar ratio increased from 0 to 0.5.

The Comparison of Sintering Characteristics between the PVA-Al(III) Complex added $UO_2$Pellet and AlOOH added $UO_2$pellet (PVA-Al(III) 착물 첨가 $UO_2$소결체와 AlOOH 첨가 $UO_2$소결체의 소결 특성 비교)

  • Lee, Sin-Yeong;Yu, Ho-Sik;Lee, Seung-Jae;Kim, Hyeong-Su;Bae, Gi-Gwang
    • Korean Journal of Materials Research
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    • v.10 no.1
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    • pp.55-61
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    • 2000
  • The sintering characteristics of PVA-Al(III) complex added $UO_2$ pellet and AlOOH added $UO_2$pellet were compared. The major phase of PVA-Al(III) complex and AlOOH decomposed at $1000^{\circ}C$ in $H_2$atmosphere was $\theta-Al_2O_3$. Compared with the apparent density of pure $UO_2$, that of AlOOH added $UO_2$ powder was higher but that of PVA-Al(III) complex was lower. the densification of AlOOH added $UO_2$ pellet was initiated at about $800^{\circ}C$, the densification of PVA-Al(III) complex added $UO_2$ pellet was initiated at about $900^{\circ}C$ respectively. In a view of pore size distribution, the PVA-Al(III) complex added $UO_2$ pellet appeared as monomodal type, whereas the AlOOH added $UO_2$ pellet appeared as bimodal type. The grain size of AlOOH added $UO_2$ pellet was about $13\mu\textrm{m}$ but the grain size of PVA-Al(III) complex added $UO_2$ pellet was increased up to about $36\mu\textrm{m}$.

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Synthesis of Tungsten Doped Vanadium Dioxide and Its Thermochromic Property Studies (텅스텐이 도핑된 바나듐 산화물의 합성 및 열전이 특성 연구)

  • Hwang, Kyung-Jun;Jo, Cho Won;Yoo, Jung Whan
    • Applied Chemistry for Engineering
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    • v.24 no.1
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    • pp.44-48
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    • 2013
  • In this work, we have prepared tungsten doped vanadium oxide ($W-VO_2$) particles with a low phase transition temperature. $W-VO_2$ particles were synthesized via thermolysis method using vanadyl (IV) sulfate and ammonium bicarbonate as precursors. The structure and thermochromic property of synthesized $W-VO_2$ particles were investigated by FE-SEM, EDS, XRD, XPS, and DSC analysis. The prepared $W-VO_2$ showed a nearly platy morphology, which indicates that the tungsten was successfully doped in the crystal lattices of $VO_2$. $W-VO_2$ nanoparticles with the size of 60 nm exhibited a monoclinic crystal structure and its chemical composition and surface state were also likely to be close to that of $VO_2$. In addition, the phase transition temperature of $W-VO_2$ was $38.5^{\circ}C$, which was approximately $29.2^{\circ}C$ lower than that of pure $VO_2$ ($67.7^{\circ}C$), indicating that the prepared sample had a good reversible thermochromic stability.

In vitro Studies on the Superoxide Scavenging Activities, the Cytotoxic and the Immunomodulating Effects of Thirteen Kinds of Herbal Extracts (13종 허브추출물의 수퍼옥사이드 소거능과 세포독성 및 면역증강 효과의 in vitro계 검색)

  • Chung, Ha-Yull;Kim, Hyun-Bae
    • Korean Journal of Food Science and Technology
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    • v.32 no.3
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    • pp.699-705
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    • 2000
  • The superoxide scavenging activities of thirteen kinds of herbal extracts were examined together with their cytotoxic and immunomodulating effects. The extracts of 6 kinds of herbs such as eucalyptus, mate, peppermint, sage, thyme and yarrow, so called medicinal herbs, showed above 70% of the superoxide scavenging activities. They also showed cytotoxicities against the cancer cell lines of Hepa-1c1c7 and KB-3-1 as well as the normal fibroblast cell line of mouse. The $IC_{50}$ values of above 6 herb extracts on the cancer cell lines were above or similar to the $IC_{50}$ values on the normal cell line, so it was unable to observe the herb extract which showed cytotoxicity only to the cancer cell lines. Considering the results of nitric oxide test that the sage extract was the only one having the immunomodulating effect(37% of positive control), there was no significant relationship between the superoxide scavenging activities of herbs and their immunomodulating effects.

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Nondestructive Examination of PHWR Pressure Tube Using Eddy Current Technique (와전류검사 기술을 적용한 가압중수로 원전 압력관 비파괴검사)

  • Lee, Hee-Jong;Choi, Sung-Nam;Cho, Chan-Hee;Yoo, Hyun-Joo;Moon, Gyoon-Young
    • Journal of the Korean Society for Nondestructive Testing
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    • v.34 no.3
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    • pp.254-259
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    • 2014
  • A pressurized heavy water reactor (PHWR) core has 380 fuel channels contained and supported by a horizontal cylindrical vessel known as the calandria, whereas a pressurized water reactor (PWR) has only a single reactor vessel. The pressure tube, which is a pressure-retaining component, has a 103.4 mm inside diameter ${\times}$ 4.19 mm wall thickness, and is 6.36 m long, made of a zirconium alloy (Zr-2.5 wt% Nb). This provides support for the fuel while transporting the $D_2O$ heat-transfer fluid. The simple tubular geometry invites highly automated inspection, and good approach for all inspection. Similar to all nuclear heat-transfer pressure boundaries, the PHWR pressure tube requires a rigorous, periodic inspection to assess the reactor integrity in accordance with the Korea Nuclear Safety Committee law. Volumetric-based nondestructive evaluation (NDE) techniques utilizing ultrasonic and eddy current testing have been adopted for use in the periodic inspection of the fuel channel. The eddy current testing, as a supplemental NDE method to ultrasonic testing, is used to confirm the flaws primarily detected through ultrasonic testing, however, eddy current testing offers a significant advantage in that its ability to detect surface flaws is superior to that of ultrasonic testing. In this paper, effectiveness of flaw detection and the depth sizing capability by eddy current testing for the inside surface of a pressure tube, will be introduced. As a result of this examination, the ET technique is found to be useful only as a detection technique for defects because it can detect fine defects on the surface with high resolution. However, the ET technique is not recommended for use as a depth sizing method because it has a large degree of error for depth sizing.