• Title/Summary/Keyword: 열분석적 특성

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Adsorption Characteristics of Biochar from Wood Waste by KOH, NaOH, ZnCl2 Chemical Activation (폐목재를 이용한 KOH, NaOH, ZnCl2 화학적 활성화로 생성된 바이오차의 흡착특성에 관한 연구)

  • MinHee Won;WooRi Cho;Jin Man Chang;Jai-young Lee
    • Clean Technology
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    • v.29 no.4
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    • pp.272-278
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    • 2023
  • There is a lot of interest in methods for pollutants using adsorption, and recent research is being conducted to show that biochar can be used to remove organic and inorganic pollutants. In particular, wood waste as waste biomass requires a biomass recycling method, and a method to increase the adsorption capacity of biochar produced using wood waste is needed. Biochar is created by Hydrothermal carbonization (HTC) using, which uses low temperature and high pressure, has low energy consumption and does not require moisture removal pretreatment, and biochar is created through chemical activation using KOH, NaOH, and ZnCl2 chemicals. The adsorption characteristics of biochar were determined by analyzing iodine adsorptivity, specific surface area, pore diameter, pore volume, pore distribution, and SEM according to the activation. The results of analyzing the selecting biochar by activating the biochar produced at HTC 300℃, 4 hr by KOH, NaOH, and ZnCl2 chemicals, the specific surface area was 774~1.387 m2/g, showing a high specific surface area similar to activated carbon, and it was confirmed that micropores with an average pore diameter in the range of 21~24 Å were formed. As a result of SEM observation, the surface was uniform with a certain shape depending on activation. It was confirmed that one pore was developed and the number of pores increased.

A Study on Surface Properties of Ablative Materials from 0.4MW Arc-Heated Wind Tunnel Test (0.4MW 아크 가열 풍동 시험을 통한 삭마 재료의 표면 특성 연구)

  • Kim, Nam Jo;Oh, Philyong;Shin, Eui Sup
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.43 no.12
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    • pp.1048-1053
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    • 2015
  • Ablative materials in a thermal protection system for atmospheric re-entry suffers from the most severe heat fluxes and temperatures, which induces surface recession in the thickness direction. In this paper, a 0.4MW arc-heated wind tunnel is operated to test for ablative materials, and a non-contact three-dimensional surface measuring system is used to evaluate the different surface characteristics of them. In particular, by postprocessing the three-dimensional image data, the surface roughness and recession of ablative materials can be calculated before and after the wind tunnel test. Moreover, the surface properties are analyzed quantitatively by comparing volume and mass losses of the test specimens.

Hydrothermal Behaviors and Long-term Stability of Bentonitic Buffer Material (벤토나이트 완충재의 열수거동 및 장기건전성 연구)

  • Lee, Jae-Owan;Cho, Won-Jin
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.5 no.2
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    • pp.145-154
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    • 2007
  • In hydrothermal reaction tests, smectite-to-illite conversion was identified using a domestic bentonite which is favorably considered as a buffer material, and its dependency on various hydrothermal conditions was investigated. The analysis results of the XRD and Si concentration indicated that the smectite-to-illite conversion was a major process of bentonite alteration under the hydrothermal conditions. The temperature, potassium concentration in solution, and pH were observed to significantly affect the smectite-to illite conversion. A model of conversion reaction rate was suggested to evaluate the long-term stability of smectite composing a major constituent of bentonitic buffer. It was expected from the evaluation results that the smectite would keep its integrity for very long disposal time under a normal condition, whitens it might be converted to illite by 50 percent after over $5{\times}10^4$ year of disposal time under a conservative condition and consequently lose its swelling capacity as a buffer material of a repository.

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Design and Fabrication of a Si pin Photodetector with Peak Spectral Response in the Red Light for Optical Link (적색 중심 Optical Link용 Si pin Photodetector의 설계 및 제작)

  • 장지근;김윤희;이지현;강현구;이상열
    • Journal of the Microelectronics and Packaging Society
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    • v.8 no.1
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    • pp.1-4
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    • 2001
  • We have fabricated and evaluated a new Si pin photodetector for APF optical link. The fabricated device has the $p^{+}$-guard ring around the metal-semiconductor contact and the web patterned $p^{+}$-shallow diffused region in the light absorbing area. From the measurements of electo-optical characteristics under the bias of -5 V, the junction capacitance of 4 pF and the dark current of 180 pA were obtained. The optical signal current of 1.22 $\mu$A and the responsivity of 0.55 A/W were obtained when the 2.2 $\mu$W optical power with peak wavelength of 670 nm was incident on the device. The fabricated device showed the maximum spectral response in a spectrum of 650-700 nm. It is expected that the fabricated device can be very useful for detecting the optical signal in the application of red light optics.

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Thermal properties of the surface-modified Inconel 617 (표면 처리에 따른 Inconel 617 합금의 고온 특성)

  • Cho, Hyun;Bang, Kwang-Hyun;Lee, Byeong-Woo
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.19 no.6
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    • pp.298-304
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    • 2009
  • The effect of the surface treatments on the high temperature properties of the Inconel 617, one of the promising candidate alloys for high temperature heat-transport system, has been studied. Various surface modification methods including a rapid thermal process(RTP), a hydrothermal treatment, and a physical vapor deposition($2{\mu}m$ thick TiAlN film by an arc discharge) were applied to the Inconel 617. The morphological and the structural properties of the surface-modified Inconel 617 samples after heat treatment at $1000^{\circ}C$ in the air were compared to find out whether inhomogeneous formation of $Cr_2O_3$ crust at the surface region was suppressed or not. TiAlN-coated Inconel 617 showed homogeneous microstructure and the lowest wear loss compared to bare, RTP- and hydrothermally-treated Inconel 617 by suppressing the $Cr_2O_3$ crust formation.

Boiling heat transfer characteristics of FC-72 in parallel micro-channels (병렬 마이크로 채널에서 FC-72의 비등 열전달 특성)

  • Choi, Yong-Seok;Lim, Tae-Woo;You, Sam-Sang;Kim, Hwan-Seong;Choi, Hyeung-Sik
    • Journal of Advanced Marine Engineering and Technology
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    • v.38 no.9
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    • pp.1032-1038
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    • 2014
  • In this study, an experimental study was performed to understand the boiling heat transfer characteristics of FC-72 in parallel micro-channels. The parallel micro-channels contained channels having a $0.2mm{\times}0.45mm$ [$H{\times}W$] cross section and length of 60 mm. And heat flux was varied from 16.4 to $25.6kW/m^2$ and mass fluxes from 300 to $500kg/m^2s$. The measured heat transfer coefficient was sharply decreased at lower vapor quality and then it was kept approximately constant as the vapor quality is increased. From the experimental results, the boiling heat transfer mechanism of FC-72 was confirmed and the measured heat transfer coefficient was compared and analyzed with the existing correlations to predict the heat transfer coefficient.

Characterization of Anti-Listerial Substance Produced by Lactobacillus salivarius LCH1227 (Lactobacillus salivarius LCH1230으로부터 생산된 Listeria 균 억제물질의 특성)

  • Shin, Yu-Ri;Lim, Kong-Boon;Chae, Jong-Pyo;Kang, Dae-Kyung
    • Food Science of Animal Resources
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    • v.31 no.4
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    • pp.609-616
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    • 2011
  • In this study, a LCH1227 bacterial strain that possesses anti-listerial activity was isolated from fermented food and identified as Lactobacillus salivarius LCH1227 based on its morphological and biochemical properties, as well as its 16S rRNA gene sequences. Anti-listerial substance also inhibited the growth of various Gram-positive bacteria, such as vancomycinresistant Enterococcus faecalis, Streptococcus agalactiae, Bacillus cereus, Lactobacillus fermentum. The highest level of production of antimicrobial substances from L. salivarius LCH1227 occurred during the early stationary phase. The antilisterial activity was found to be stable over a broad range of pH values (2.0-12.0) and after heat treatment. However, it was inactivated by proteolytic enzymes, indicating its proteinaceous nature. The apparent molecular mass of the partially purified anti-listerial substance, as measured by Tricine-SDS-PAGE, was approximately 5 kDa.

Experimental Study on the Flame Spread Characteristics under Reduced Atmospheric Pressures and Elevated Oxygen Concentrations (저기압 고산소 환경에서 화염 전파특성에 관한 실험적 연구)

  • Yang, Ho-Dong;Kwon, Hang-June;Park, Seul-Hyun
    • Fire Science and Engineering
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    • v.30 no.6
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    • pp.78-83
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    • 2016
  • The characteristics of flame spread under similar atmospheric conditions to those inside the first stage of launch vehicles were investigated to provide fundamental knowledge to prevent fires and explosions of vehicles during launching operations. To this end, the rate of flame spread on the solid fuel was measured at elevated oxygen concentrations and reduced atmospheric pressures. A 0.18 mm diameter optical fiber was used as a solid fuel. The experimental results indicated that elevated oxygen concentrations can increase the rate of flame spread while increasing the atmospheric pressures to 1 atm can lead to decreases in the rate of flame spread. The increases in the rate of flame spread with pressure is due mainly to reductions in the convective heat loss that are clarified through an analysis of the pressure dependence on the convective heat transfer coefficient.

A Study on Strengthening of Steel Girder Bridge using Multi-Stepwise Thermal Prestressing Method (다단계 온도프리스트레싱을 이용한 강거더교의 보강에 관한 연구)

  • Kim, Sang Hyo;Kim, Jun Hwan;Ahn, Jin Hee
    • Journal of Korean Society of Steel Construction
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    • v.18 no.6
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    • pp.717-726
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    • 2006
  • Traditional external post-tensioning method using either steel bars or tendons is commonly used as a retrofitting method for steel composite bridges. However, the method has some disadvantages such as stress concentration at anchorages and inefficient load-carrying capability of live loads. Multi-stepwise prestressing method using thermal expanded coverplate is a newly proposed prestressing method, which was originally developed for prestressing steel structures. A new retrofitting method for steel girder bridges founded on a simple concept of thermal expansion and contraction of cover plate, the method is a hybrid of and combines the advantages of external post-tensioning and thermal prestressing. In this paper, basic concepts of the method are presented and an illustrative experiment is introduced. From actual experimental data, the thermal prestressing effect was substantiated and the FEM approach for its analysis was verified. The retrofitting effects ofa single-span bridge were analyzed and the feasibility of the developed method was examined.

Improving the PTS Method for the PAPR Reduction in the OFDM System (OFDM 시스템에서 PAPR 감소를 위한 PTS 기법의 성능개선)

  • Kim, Dong-Seek;Kwak, Min-Gil;Cho, Hyung-Rae
    • Journal of Advanced Marine Engineering and Technology
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    • v.34 no.8
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    • pp.1165-1171
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    • 2010
  • The OFDM system has better characteristics in transmission rate, power efficiency, bandwidth efficiency, impulse-noise immunity, and narrow band interference immunity etc. in comparison with other conventional systems. However, high PAPR of an OFDM signals causes some serious non-linear processing of RF amplifier. And performance of the communication system gets worse. Therefore, various methods reducing PAPR of an OFDM skills such as the clipping method, block coding method, and phase rotation method etc. have been researched. In this paper, we propose a high-speed adaptive PTS method which eliminates high PAPR. And we compare the proposed method with other conventional methods. The proposed method has decreased quantity of calculation compare with an adaptive PTS method. Of course, The more its calculation amount is decreased, the more its BER characteristic is not better than an adaptive PTS method. However, keeping up satisfactory BER performance, we highly improved calculation amount of a PTS method.