• Title/Summary/Keyword: 열분석적 특성

Search Result 2,493, Processing Time 0.031 seconds

Anti-corrosion properties for cross section of Mg films on galvalume steel coated by PVD process (PVD법에 의해 Mg 코팅된 갈바륨 도금강판의 단면부 내식특성)

  • Park, Jae-Hyeok;Kim, Sun-Ho;Park, Gi-Dong;Jeong, Jae-In;Yang, Ji-Hun;Lee, Gyeong-Hwang;Lee, Myeong-Hun
    • Proceedings of the Korean Institute of Surface Engineering Conference
    • /
    • 2018.06a
    • /
    • pp.65-65
    • /
    • 2018
  • 갈바륨 도금강판은 알루미늄의 우수한 차폐 특성과 내열성, 열 반사성을 가지며 아연의 희생방식 특성을 겸비하여 동일 부착량의 용융 아연도금 및 알루미늄 도금강판에 비해 우수한 내식성을 나타낸다고 알려져 있다. 또한 이것은 표면이 미려하고 경제성이 높아 건자재 용도로 현재까지도 세계적으로 널리 이용되고 있다. 여기서 지칭하는 바륨 도금강판(galvalume steel)은 아연과 알루미늄 도금강판의 장점을 접목하기 위해 55 Al-43.4 Zn-1.6 Si (wt.%)로 구성되어 개발된 3원계 성분의 합금도금강판이다. 한편, 최근에는 강재의 내식성을 향상시키기 위한 다양한 연구 결과에 의해 Zn-Al-Mg의 3원계 합금도금강판도 개발되어 사용되고 있다. 이것은 기존의 아연도금 강판 보다 10배 정도의 우수한 내식성을 나타내는 것으로 보고되고 있다. 특히, 이것은 도금된 평판부의 내식성은 물론 절단된 도금 단면부의 내식성도 매우 우수하다고 알려져 있다. 그러나 상기한 갈바륨 도금강판의 경우에는 도금된 표면부에 비해 단면부의 내식성이 상대적으로 취약한 것으로 알려져 있다. 따라서 본 연구에서는 갈바륨 도금강판의 내식성을 종합적으로 향상시키기 위하여 이 갈바륨 도금강판 상에 PVD 스퍼터링법에 의해 Mg 코팅막의 제작을 시도하였다. 여기서 Mg 코팅막은 후처리 된 갈바륨 도금강판 상에 Ar 공정압력 2 및 20 mTorr 조건 중 1.5 및 $3{\mu}m$ 두께로 제작하였다. 또한 제작한 코팅막에 대해서는 모폴로지 관찰(SEM) 및 결정구조 분석(XRD)을 하였고, 분극측정, 염수분무 시험(SST) 및 복합부식 시험(CCT)에 의해 표면 및 단면부의 내식성평가를 수행하였다. 또한 여기서는 염수분무 및 복합부식 시험 후의 시험편도 채취 하여 표면 및 단면부위에 대한 원소조성 분석(EPMA)과 결정구조 분석(XRD)을 실시하였다. 이상의 실험 결과에 의하면, 본 실험에서 제작한 Mg 코팅막은 그 두께가 두꺼울수록 표면 Mg 결정립의 크기가 증가하였고, 그 부식속도가 증가하는 경향을 나타내었다. 또한 여기서는 공정압력이 높은 조건에서 제작한 막일수록 Mg(002)면 피크 강도가 감소하고 Mg(101)면 피크의 배향성이 증가하였다. 그때 그 막의 내식성은 향상되는 경향을 나타내었다. 그리고 종합적으로 염수분무 및 복합부식 시험 결과에 의하면 Mg이 코팅된 갈바륨 도금강판은 기존 갈바륨 도금강판 보다 내식성이 현저히 향상되었다. 특히, 단면부 내식성의 경우에는 기존 대비 5배 이상 향상되는 경향을 나타내었다. 여기서 단면부 내식특성 분석을 위한 EPMA 원소조성 분석 결과에 의거하면, 부식 초기에는 마그네슘의 부식생성물에 의해 단면부가 치밀하게 보호되고 있음을 확인할 수 있었다. 그 이후에는 부식이 지속적으로 진행됨에 따라 갈바륨 도금층에서 용출된 알루미늄 및 아연 성분이 마그네슘과 함께 치밀한 부식생성물을 형성하여 단면부를 차폐함에 따라 단면부의 내식성이 크게 향상된 것으로 생각된다. 이러한 부식생성물의 결정구조 분석 결과에 따르면, 염수분무와 복합부식 시험에서는 공통적으로 MgO, $Mg(OH)_2$ 이외에도 Simonkolleite상 등이 형성되었다. 또한 건-습 반복 부식시험인 복합부식시험 후에는 $Mg_5(CO_3)_4(OH)_24H_2O$(Hydromagnesite)상 등이 형성됨을 확인할 수 있었다. 즉, 본 실험에서 후처리된 갈바륨 도금강판 상에 제작한 마그네슘 코팅막의 경우에는 상기와 같은 다양한 부식반응에 의해 표면 및 단면부에 형성된 Mg계 부식생성물과 $Zn_5(OH)_8Cl_2H_2O$(Simonkolleite)상에 의해서 표면은 물론 단면부 내식성이 크게 향상된 것으로 사료된다.

  • PDF

Comparison of Spatio-temporal Fusion Models of Multiple Satellite Images for Vegetation Monitoring (식생 모니터링을 위한 다중 위성영상의 시공간 융합 모델 비교)

  • Kim, Yeseul;Park, No-Wook
    • Korean Journal of Remote Sensing
    • /
    • v.35 no.6_3
    • /
    • pp.1209-1219
    • /
    • 2019
  • For consistent vegetation monitoring, it is necessary to generate time-series vegetation index datasets at fine temporal and spatial scales by fusing the complementary characteristics between temporal and spatial scales of multiple satellite data. In this study, we quantitatively and qualitatively analyzed the prediction accuracy of time-series change information extracted from spatio-temporal fusion models of multiple satellite data for vegetation monitoring. As for the spatio-temporal fusion models, we applied two models that have been widely employed to vegetation monitoring, including a Spatial and Temporal Adaptive Reflectance Fusion Model (STARFM) and an Enhanced Spatial and Temporal Adaptive Reflectance Fusion Model (ESTARFM). To quantitatively evaluate the prediction accuracy, we first generated simulated data sets from MODIS data with fine temporal scales and then used them as inputs for the spatio-temporal fusion models. We observed from the comparative experiment that ESTARFM showed better prediction performance than STARFM, but the prediction performance for the two models became degraded as the difference between the prediction date and the simultaneous acquisition date of the input data increased. This result indicates that multiple data acquired close to the prediction date should be used to improve the prediction accuracy. When considering the limited availability of optical images, it is necessary to develop an advanced spatio-temporal model that can reflect the suggestions of this study for vegetation monitoring.

Monitoring Vegetation Phenology Using MODIS in Northern Plateau Region, North Korea (MODIS자료를 이용한 북한 개마고원 및 백무고원 식생의 생물계절 모니터링)

  • Cha, Su-Young;Seo, Dong-Jo;Park, Chong-Hwa
    • Korean Journal of Remote Sensing
    • /
    • v.25 no.5
    • /
    • pp.399-409
    • /
    • 2009
  • Many researches have shown that NDVI provides a potential methods to derive meaningful metrics that describe ecosystem functions. In this paper we investigated the use of the MODIS NDVI (Normalized Difference Vegetation Index) to monitor vegetation phenology dynamics of Northern plateau region, North Korea, during last 9-years (2000~2008). The findings of this paper can be summarized as follows. First, the length of growing season ranged from a low of 128 days in 2003 to a high of 176 days in 2000 and 2005. On the average of the last 9 years, the highest NDVI of 0.86 was marked on 28 July. Greenup onset occurs at the start of May, while the senescence begins between late September and October. Second, these annual vegetation cycles were compared with Seorak and Jiri Mountain regions of South Korea which have similar vegetation condition. Greenup onsets in South Korea were observed earlier than those of North Korea and the average time lag between the South and North Korea in Greenup was about 16 days which is a time-resolution of remotely sensed data. Sub-alpine conifers of such areas may be severely affected by the large of phenological characteristics due to the global warming trend.

Distribution Characteristics Analysis of Pine Wilt Disease Using Time Series Hyperspectral Aerial Imagery (소나무재선충병 발생시기별 피해목 탐지를 위한 시계열 초분광 항공영상의 활용)

  • Kim, So-Ra;Kim, Eun-Sook;Nam, Youngwoo;Choi, Won Il;Kim, Cheol-Min
    • Korean Journal of Remote Sensing
    • /
    • v.31 no.5
    • /
    • pp.385-394
    • /
    • 2015
  • Pine wilt disease has greatly damaged pine forests not only in East Asia including South Korea and China, but also in European region. The damage caused by pine wood nematode (Bursaphelenchus xylophilus) is expressed in bundles within stands and rapidly spreading, however, present field survey methods have limitations to detecting damaged trees at regional level. This study extracted the damaged trees by pine wilt disease using time series hyperspectral aerial photographs, and analyzed their distribution characteristics. Hyperspectral aerial photographs of 1 meter spatial resolution were obtained in June, September, and October. Damaged trees by pine wilt disease were extracted using Normalized Difference Vegetation Index (NDVI) and Vegetation Index green (VIgreen) of the September photograph. Among extracted damaged trees, dead trees with leaves and without leaves were classified, and the spectral reflectance values from the photographs obtained in June, September, and October were compared to extract new outbreaks in September and October. Based on the time series dispersion of extracted damaged trees, nearest neighbor analysis was conducted to analyze distribution characteristics of the damaged trees within the region where hyperspectral aerial photographs were acquired. As a result, 2,262 damaged trees were extracted in the study area, and 604 dead trees (dead trees in last year) with leaves in relation to the damaged time and 300 and 101 newly damaged trees in September and October were classified. The result of nearest neighbor analysis using the data shows that aggregated distribution was the dominant pattern both previous and current year in the study area. Also, 80% of the damaged trees in current year were found within 60 m of dead trees in previous year.

Purification and Biochemical Characterization of Lectin from Viscum album (겨우살이 Lectin의 정제 및 생화학적 특성)

  • Jang, Cheol-Su;O, Mi-Jeong;No, Gwang-Su
    • KSBB Journal
    • /
    • v.14 no.5
    • /
    • pp.578-584
    • /
    • 1999
  • The lectin was purified through 0.15 M NaCl extraction, ammonium sulfate precipitation, sepharose 4B affinity chromatography and gel filtration using sephadex G-150 from the leaves of Visum album collected in Mt. Duk Yu. The final gel filtration step resulted in 11.64 folds purification with 0.14% of recovery yield. We also performed biochemical characterization of the purified Visum album lectin. HPLC analysis of lectin purified by gel filtration revealed a singel peak. The analysis of the purified lectin by SDS-PAGE showed a tetramer composed of two identical subunits with molecular weights of 32 and 30 kDa. The lectin was a glycoprotein containing 14.4% carbohydrate, which consist of glucose, fructose, arabinose and xylose, and the amino acids such as phenylalanine, lysine and tyrosine. The purified lectin agglutinated human red blood cell types with similar potency, but when tested against red blood cells from mouse, bovine, rabbit, chicken and porcine, significant difference in potency were observed. Hemaggluting activity was inhibited by D-galactose, D-mannose, D-lactose and D-raffinose, but not by D-glucose, D-glucosamine, D-mannosamine, L-fructose, D-xylose, D-arabinose, D-galacturonic acid, D-fructose, L-rhamnose and N-acetyl-D-galactosamine. The optimal pH and thermal stability of the purified lectin were pH 4.0-7.0 and 20-5$0^{\circ}C$, respectively.

  • PDF

Analysis of Secular Changes in the Hydrological Characteristics of a Small Forested Watershed using a Baseflow Recession Curve (감수곡선을 이용한 산림소유역 유출특성의 시계열 변화 평가)

  • Lee, Ik-Soo;Lee, Heon-Ho
    • Journal of Korean Society of Forest Science
    • /
    • v.103 no.3
    • /
    • pp.383-391
    • /
    • 2014
  • Long-term changes in the hydrological characteristics of a small forest watershed were examined using a master baseflow recession curve and the measured rainfall-runoff data from the experimental forest watershed in the measured years 2003-2011. The results of the study showed that the recession coefficient of direct runoff was lower than that of baseflow. In small forested watershed, the direct flow was lower than that of large scale watershed, flow due to its shorter period of occurrence. And baseflow was similar to large scale watershed's. A regression equation $y=0.7528e^{-0.022x}$($R^2=0.8938$, range 0.3~0.8 mm) was obtained using the master baseflow recession curve for the study period and the recession coefficient was calculated as K = 0.978. Changes between master baseflow recession curve and runoff showed great association and relevance such as increasing runoff was associated with the gentle slope of master baseflow recession curve and decreasing runoff was associated with the slope of master baseflow recession curve contrary. In the later years of the study period, the slope of the master baseflow recession curve appreciably became more gentle due to increases in baseflow. This suggests that the forested experimental watershed exhibit improved structural functioning of normal flood control and reduced occurrence of water shortage problems.

Analysis of the Detection Characteristics of Irradiated Dried Spices and Herbs by Photostimulated Luminescence (PSL) (광자극발광법(PSL)에 의한 방사선 조사 건조향신료의 검지 특성)

  • Park, Eun-Ryong;Kang, Hye-Soon;Ahn, Hyun-Joo;An, Kyung-A;Cho, Soo-Yeul;Kim, Hee-Yun;Kim, Dong-Sul;Kim, Do-Hoon;Kang, Chan-Soon
    • Korean Journal of Food Science and Technology
    • /
    • v.42 no.2
    • /
    • pp.136-141
    • /
    • 2010
  • This study attempted to determine whether Photostimulated Luminescence (PSL) is applicable for the detection of post-irradiated foods by measuring the PSL photon counts of unirradiated and irradiated dried spices and herbs. A total of 19 dried spices and herbs was irradiated with a $^{60}Co$ $\gamma$-ray source at 1, 5 and 10 kGy followed by measurement of PSL photon. The photon counts of unirradiated samples below 700 correspond to negative. Fifteen samples irradiated over 1 kGy showed photon counts of more than 5,000, indicating irradiation treatment. Intermediate counts (photon count 700-5,000) were observed in irradiated white/black pepper, nutmeg and cinnamon bark at 10 kGy. These results suggest that it is possible to detect whether dried spices and herbs were irradiated by analyzing PSL, with the exception of white/black pepper, nutmeg and cinnamon bark. Irradiated white/black pepper, nutmeg and cinnamon bark containing low levels of minerals were not sensitive to PSL. Therefore, further investigation is sugguested to be performed by Thermoluminescence (TL) analysis or another validated or standardized method.

Design Strategies of Large Park in the International Design Competition for Central Open Space in Multi-Functional Administrative City, Korea (행정중심복합도시 중앙녹지공간 국제설계공모에 나타난 대형 공원의 설계 전략)

  • Park, Keun-Hyun;Pae, Jeong-Hann
    • Journal of the Korean Institute of Landscape Architecture
    • /
    • v.36 no.5
    • /
    • pp.13-25
    • /
    • 2008
  • Although competitions for large parks are increasing rapidly across the world, theoretical research and critiques of these competitions are as yet insufficient. The 'International Design Competition for Central Open Space in Multi-functional Administrative City, Korea', a representative competition for large park design, can be a significant resource for examining the contemporary design strategies that go into the design of a large park. In this study, the authors make a framework for analysis by looking at the competition's design guidelines and literatures on 'large parks', and by then analyzing the ten finalists. Four questions that were derived from the framework were: 'what are the approaches to large parks?', 'what is the process of design?', 'what is the sustainability of the park?', and 'what are the relations between city and park?' The results of the study are as follows. First, the design concepts for large parks are primarily site-specific. It is particularly important in ensuring the identity of the large park. Second, it is difficult to find design proposals which satisfy the four main questions sufficiently, and works submitted tend to be visual-oriented, form-oriented, and results-centered. Third, the notion of 'sustainability' in large parks is a comprehensive one which includes various aspects such as ecology, finance, programming, and community. However, the notion remains ambiguous, and plans for operation and management are not concretely proposed. Finally, design proposals for large parks accompany positive relations with the city. Especially, 'productive parks' and 'city self-sufficiency' are very important demands in regards to large parks.

Using Syntactic Unit of Morpheme for Reducing Morphological and Syntactic Ambiguity (형태소 및 구문 모호성 축소를 위한 구문단위 형태소의 이용)

  • Hwang, Yi-Gyu;Lee, Hyun-Young;Lee, Yong-Seok
    • Journal of KIISE:Software and Applications
    • /
    • v.27 no.7
    • /
    • pp.784-793
    • /
    • 2000
  • The conventional morphological analysis of Korean language presents various morphological ambiguities because of its agglutinative nature. These ambiguities cause syntactic ambiguities and they make it difficult to select the correct parse tree. This problem is mainly related to the auxiliary predicate or bound noun in Korean. They have a strong relationship with the surrounding morphemes which are mostly functional morphemes that cannot stand alone. The combined morphemes have a syntactic or semantic role in the sentence. We extracted these morphemes from 0.2 million tagged words and classified these morphemes into three types. We call these morphemes a syntactic morpheme and regard them as an input unit of the syntactic analysis. This paper presents the syntactic morpheme is an efficient method for solving the following problems: 1) reduction of morphological ambiguities, 2) elimination of unnecessary partial parse trees during the parsing, and 3) reduction of syntactic ambiguity. Finally, the experimental results show that the syntactic morpheme is an essential unit for reducing morphological and syntactic ambiguity.

  • PDF

Development of optimization algorithm to set transition point for multi-segmented rating curve (구간 분할된 레이팅 커브의 천이점 선정을 위한 최적화 알고리즘 개발)

  • Kim, Yeonsu;Noh, Joonwoo;Kim, Sunghoon;Yu, Wansik
    • Proceedings of the Korea Water Resources Association Conference
    • /
    • 2018.05a
    • /
    • pp.421-421
    • /
    • 2018
  • 효율적인 수자원 관리를 위하여 전국유역조사, 수자원 장기종합계획 등 다양한 사업이 수행되고 있으며, 이를 위하여 유출해석은 필수적인 항목이라 할 수 있다. 유출해석을 위하여 수문모형 또는 관측소의 유량자료가 활용되고 있으나, 이는 기존에 관측된 유량자료를 바탕으로 구축된 수위-유량관계 곡선식(Rating-curve)을 활용하여 재생산된 자료라 할 수 있다. 즉, 수위자료는 매시간 관측소에서 측정이 되지만, 유량자료의 경우 측정이 어려울 뿐만 아니라 변동성 및 불확실성이 크기 때문에 시계열 수위를 곡신식을 통해 유량으로 변환하여 활용하고 있다. 이와 같이 수위-유량관계 곡선식의 정확성이 수문자료 생산에 핵심 요소임에도 불구하고 이에 대한 연구는 제한적이며, 특히 홍수터 등의 영향을 고려하여 분할된 곡선의 천이점 접합시 곡선식의 정확도 향상을 위한 연구도 드문 편이다. 따라서 본 연구에서는 구간 분할된 곡선의 최적 천이점 선정을 위하여 Particle Swarm Optimization(PSO)기법을 활용하였으며, 총 5개 구간까지 구간별 목적함수로 RMSE, RSR, 결정계수 적용시 특성변화에 대한 연구를 수행하였다. 구간에 대하여 절대적인 오차를 산정하는 RMSE를 활용하는 경우 저수위 부분에 대한 오차가 증가하는 것을 확인할 수 있었으며, 상대적인 오차인 RSR, 결정계수를 활용하는 경우 전체 구간에 대한 오차를 보완할 수 있는 것으로 나타났다. PSO기법을 활용하여 도출된 곡선식에 대해서는 구간 및 전체구간에 대한 오차(RMSE, 결정계수, RSR, MAPE)를 활용하여 불확실성을 검토할 수 있도록 하였고, 잔차분석을 통한 이상치 및 회귀곡선에 대한 정규성 검토를 수행할 수 있는 툴을 개발하였다. 레이팅 커브를 작성하는데 있어 최적화 알고리즘을 활용하여 구간분할시 천이점 선정의 자동화로 천이점 선정에 소요되는 시간을 대폭 감축할 수 있을 뿐만 아니라, 구간별 오차를 종합적으로 고려하여 우수한 품질의 레이팅 커브를 도출할 수 있는 기반을 구축하였다.

  • PDF