• Title/Summary/Keyword: 열분석적 특성

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Optimum Mix Proportion and Characteristics of the Combined Self Compacting Concrete according to Cement Types (시멘트 종류에 따른 병용계 자기충전 콘크리트의 최적배합비와 특성)

  • Kwon, Yeong-Ho
    • Journal of the Korea Concrete Institute
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    • v.21 no.1
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    • pp.55-64
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    • 2009
  • This study is aimed to derive the optimum mix proportion of the combined self compacting concrete according to cement types (blast-furnace slag cement and belite cement) and to propose the basic data to field construction work after evaluating the quality properties. Specially, lime stone powder (LSP) as binder and viscosity agent are used in the combined self compacting concrete because slurry wall of an underground LNG storage tank should be kept stability of quality during concrete working. Replacement ratio of LSP is determined by confined water ratio test and main design factors including fine aggregate ratio ($S_r$), coarse aggregate ratio ($G_v$) and water-cement ratio (W/C) are selected. Also, quality properties including setting time, bleeding content, shortening depth and hydration heat on the optimum mix proportion of the combined self compacting concrete according to cement type are compared and analyzed. As test results, the optimum mix proportion of the combined self compacting concrete according to cement type is as followings. 1) Slag cement type-replacement ratio of LSP 13.5%, $S_r$ 47% and W/C 41%. 2) Belite cement type-replacement ratio of LSP 42.7%, Sr 43% and W/C 51%. But optimum coarse aggregate ratio is 53% regardless of cement types. Also, as test results regarding setting time, bleeding content, shortening depth and hydration heat of the combined self compacting concrete by cement type, belite cement type is most stable in the quality properties and is to apply the actual construction work.

The Effect of Functional Group Position of the Piperidine Derivatives on the CO2 Absorption Characteristics in the (H2O-Piperidine-CO2) System ((H2O-Piperidine-CO2) system에서 piperidine 유도체의 작용기 위치에 따른 이산화탄소 흡수특성 연구)

  • Choi, Jeong Ho;Yun, Soung Hee;Kim, Yeong Eun;Yoon, Yeo Il;Nam, Sung Chan
    • Korean Chemical Engineering Research
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    • v.53 no.1
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    • pp.57-63
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    • 2015
  • Absorption characteristics of 2-methylpiperidine (2MPD), 3-methylpiperidine (3MPD) and 4-methylpiperidine (4MPD) absorbents were studied by a vapor-liquid equilibrium (VLE) apparatus and a differential reaction calorimeter (DRC). Using a VLE apparatus, the $CO_2$ loading capacity of each absorbent was estimated. After reaching the absorption equilibrium, nuclear magnetic resonance spectroscopy (NMR) had been conducted to characterize the species distribution of the ($H_2O$-piperidine-$CO_2$) system. Using a DRC, the reaction of heat was confirmed in accordance with the absorption capacity. The unique characteristics of 2MPD, 3MPD and 4MPD absorbents appeared by the position of methyl group. The 2MPD possessing the methyl group at the ortho position showed its hindrance effect during the absorption process; however, piperidine derivatives possessing the meta position and para position did not show its characteristics in $H_2O$-piperidine-$CO_2$ system.

The Factor Analysis of Land Surface Temperature(LST) Change using MODIS Imagery and Panel Data (MODIS 영상 자료와 패널 자료를 이용한 지표면온도변화 요인분석)

  • BAE, Da-Hye;KIM, Hong-Myung;HA, Sung-Ryong
    • Journal of the Korean Association of Geographic Information Studies
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    • v.21 no.1
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    • pp.46-56
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    • 2018
  • This paper aimed to identify main factors of community characters, which have an effect on the land surface temperature(LST) change and estimate the impacting coefficient(ratio) of factors in a significant level of statistics. Chungcheongbuk-do province was selected and then partitioned into city and county areas for the sake of convenience of modeling. LST time series data and the community character data were developed based on Terra Satellite MODIS data and collected from the National Statistical Office, respectively. By the cause and effect relationship between community characters and LST, regression coefficients were estimated using a penal model. In a panel modeling, LST and community characters were used as a dependent variable and explanatory variables, respectively. Panel modeling analysis was carried out using statistical package STATA14 and one-way fixed effect model was selected as the most suitable model to evaluate the regression coefficients in the study area. The impacting ratio of LST change by any explanatory variable derived from the regression coefficients of the panel model fixed. Impacting ratios for industrial areas, elevation ${\times}$ building, energy usage, average window speed, non-urban management area, agricultural, nature and environmental conservation, average precipitation were 3.746, 2.856, 2.742, 0.553, 0.102, 0.071 and 0.003, respectively.

Synthesis and Characterization of Some Transition Metal Complexes of Unsymmetrical Tetradentate Schiff Base Ligand (비대칭 Tetradentate Schiff 염기 리간드의 전이금속 착물에 대한 합성 및 특성)

  • Munde, A. S.;Jagdale, A. N.;Jadhav, S. M.;Chondhekar, T. K.
    • Journal of the Korean Chemical Society
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    • v.53 no.4
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    • pp.407-414
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    • 2009
  • The solid complexes of Cu(II), Ni(II), Co(II), Mn(II) and Fe(III) with 4-hydroxy-3-(1-{2-(2-hydroxybenzylidene)- amino phenylimino}-ethyl)-6-methy-pyran-2-one (H2L) derived from o-phenylenediamine, 3-acetyl- 6-methyl-(2H) pyran, 2,4 (3H)-dione (dehydroacetic acid or DHA) and salicylic aldehyde have been synthesized and characterized by elemental analysis, conductometry, magnetic susceptibility, UV-visible, IR, $^1H$-NMR spectra, X-ray diffraction, thermal analysis, and screened for antimicrobial activity. The IR spectral data suggest that the ligand behaves as a dibasic tetradentate ligand with ONNO donor atoms sequence towards central metal ion. From the microanalytical data, the stoichiometry of the complexes has been found to be 1:1 (metal: ligand). The physico-chemical data suggests square planar geometry for Cu(II) and Ni(II) complexes and octahedral geometry for Co(II), Mn(II) and Fe(III) complexes. The x-ray differaction data suggests orthorhombic crystal system for Cu(II) complex, monoclinic crystal system for Ni(II), Co(II) and Fe(III) and tetragonal crystal system for Mn(II) complex. Thermal behaviour (TG/DTA) of the complexes was studied and kinetic parameters were determined by Coats-Redfern method. The ligand and their metal complexes were screened for antibacterial activity against Staphylococcus aureus and Escherichia coli and fungicidal activity against Aspergillus Niger and Trichoderma.

Flow Characteristics of R600a in an Adiabatic Capillary Tube (단열 모세관내 R600a의 유동 특성)

  • Ku, Hak-Geun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.11 no.2
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    • pp.449-454
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    • 2010
  • In this paper, flow characteristics of R600a in an adiabatic capillary tube were investigated employing the homogeneous flow model. The model is based on fundamental equations of mass, energy and momentum which are solved simultaneously. Two friction factors(Churchill) and viscosity(McAdams) are comparatively used to investigate the flow characteristics. Thermodynamic and transport properties of R600a are calculated employing EES property code. Flow characteristics analysis of R600a in an adiabatic capillary tube is presented to offer the basic design data for the operating parameters. The operating parameters considered in this study include condensation temperature, evaporation temperature, subcooling degree and inner diameter tube of the adiabatic capillary tube. The main results were summarized as follows: condensation and evaporation temperature, inlet subcooling degree and inner diameter tube of an adiabatic capillary tube using R600a have an effect on length of an adiabatic capillary tube. The length of an adiabatic capillary tube using R600a is expressed to the correlation shown in Eq. (15).

The study of aerodynamic characteristics to design of optimum jetvane (제트베인 최적 설계를 위한 공기역학 특성 연구)

  • 신완순;길경섭;이택상;박종호;김윤곤
    • Journal of the Korean Society of Propulsion Engineers
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    • v.5 no.1
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    • pp.26-33
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    • 2001
  • Thrust vector control system is control device which is mounted exit of the nozzle to generate pitch, yaw and roll directional force by deflecting flow direction of the supersonic jet from the nozzle. By obtaining control force, jetvane which is exposed in jet flow is working thermal and aerodynamic load. Axial thrust loss and side thrust is affected by shock patterns and interactions between jetvanes according to jetvane geometry and turning angle. In this study, we designed 6 types of jetvane to evaluate pitch, yaw and roll characteristics of ietvane in supersonic flow, and perform the cold flow test in range of turning angles of jetvanes between $0^{\cire}$ and $25^{\cire}$ by $5^{\cire}$ respectively. Also, calculation is going side by side to analyse flow interaction. Results show that there is no interactions between jetvanes upto turning angle 20$^{\circ}$, chord and lead length ratio is very important parameter to aerodynamic performance and maximum thrust loss is appeard to 17% of axial thrust in roll directional control.

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Numerical Study of Aerodynamics of Turbine Rotor with Leading Edge Modification Near Hub (허브 측 선단 수정에 따른 터빈 로터의 공력 특성에 대한 수치적 연구)

  • Kim, Dae Hyun;Lee, Won Suk;Chung, Jin Taek
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.37 no.8
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    • pp.1007-1013
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    • 2013
  • This study aims to analyze the aerodynamics when the geometry of the turbine rotor is modified. The turbine used in this study is a small engine used in the APU of a helicopter. It is difficult to improve the performance of small engines owing to the structural weakness of the blade tip. Therefore, the improvement of the hub geometry is investigated in many ways. The working fluid of a turbine is a high-temperature and high-pressure gas. The heat transfer rate of the turbine surface should be considered to avoid the destruction of blade owing to the heat load. The SST turbulence model gives an excellent prediction of the aerodynamic behavior and heat transfer characteristics when the numerical simulations are compared with the experimental results. In conclusion, the aerodynamic efficiency is improved when a bulbous design is applied to the leading edge near the hub. The endwall loss is reduced by 15%.

The analysis of surface degradation on polymer material by contact angle properties (접촉각 특성을 이용한 고분자복합재료의 표면열화 해석)

  • Park, Jong-Kwan
    • Journal of the Institute of Electronics Engineers of Korea TE
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    • v.39 no.3
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    • pp.8-14
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    • 2002
  • UV, heat, and discharge treatments are arbitrary simulated for finding out the initiations and processes of surface degradation on the polymer surface. Especially, this study is focused on the inter-relation between chemical changes and electrical properties. In contact angle to measure the change of activated degree, that of polymers surface shows a slight hydrophobicity of 73$^{\circ}$~91$^{\circ}$. But, discharge treatment and UV treatment of 300 nm wavelength changed it to the hydrophilic one with the decrease of contact angle, 13.8$^{\circ}$ and 20$^{\circ}$ respectively. Thermal-treatment and UV treatment of 430~500 nm wavelength changed the surface to the hydrophobic one with the increase of contact angle, 90$^{\circ}$ and 80.1$^{\circ}$ respectively.  

Effects of Cement Fineness Modulus (CFM) on the Fundamental Properties of Concrete (시멘트 입도계수(CFM)가 콘크리트의 기초적 특성에 미치는 영향)

  • Noh, Sang-Kyun;Han, Cheon-Goo
    • Journal of the Korea Institute of Building Construction
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    • v.12 no.3
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    • pp.284-290
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    • 2012
  • Cement Fineness Modulus (CFM) is a method of expressing the distribution of particle sizes of cement in numeric form. If CFM is controlled through crush process of cement without modifying the chemical components or mineral composition of cement, it is judged to be able to produce a cement satisfying various requirements because it is estimated to enable various approaches to cement such as high early strength, moderate heat, low heat cement and so on. Therefore, in this study, as basic research for manufacturing special cement utilizing the controls of CFM, the intention was to review the impacts of CFM on the fundamental properties of concrete. To summarize the result, as mixture characteristics of fresh concrete, ratio of small aggregate and unit quantity were gradually increased, securing greater fluidity, with an increase in CFM, while the amount of AE and SP were reduced gradually. In addition, setting time was delayed as CFM increased. Furthermore, compression strength was relatively high during initial aging as CFM became smaller, but as time passed, compression strength became smaller, and it showed the same level of strength as aging time passed about three years.

Study of Focusing Characteristics of Ultrasound for Designing Acoustic Lens in Ultrasonic Moxibustion Device (뜸 자극용 초음파 치료기기의 음향렌즈 설계를 위한 초음파 집속 특성 연구)

  • Bae, Jae-Hyun;Song, Sung-Jin;Kim, Hak-Joon;Kim, Ki-Bok
    • Journal of the Korean Society for Nondestructive Testing
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    • v.35 no.2
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    • pp.134-140
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    • 2015
  • Traditional moxibustion therapy can cause severe pain and leave scarring burns at the moxibustion site as it relies on the practitioner's subjective and qualitative treatment. Recently, ultrasound therapy has received attention as an alternative to moxibustion therapy owing to its objectiveness and quantitative nature. However, in order to convert ultrasound energy into heat energy, there is a need to precisely understand the ultrasound-focusing characteristics of the acoustic lens. Therefore, in this study, an FEM simulation was performed for acoustic lenses with different geometries a concave lens and zone lens as the geometry critically influences ultrasound focusing. The acoustic pressure field, amplitude, and focal point were also calculated. Furthermore, the performance of the fabricated acoustic lens was verified by a sound pressure measurement experiment.