• Title/Summary/Keyword: 연화제

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Pollution of Pb in paddy field soil and rice plants at roadside areas;I. Pollution of Pb in paddy field soil and its chemical forms (도로변(道路邊)에 인접(隣接)한 경작지(耕作地) 토양(土壤) 및 작물체중(作物體重)의 연오염(鉛汚染) 제(第)1보(報) 경작지(耕作地) 토양중(土壤中)의 연오염(鉛汚染) 및 화학적(化學的) 형태(形態))

  • Lee, Seog-June;Kim, Jang-Eok
    • Korean Journal of Environmental Agriculture
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    • v.10 no.1
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    • pp.1-10
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    • 1991
  • The object of this stduy was to investigate the pollution of Pb in paddy field soil with different distance from roadside and to find out the relationship between the ratio of chemical fractions of total Pb and soil characteristics. Lead from automobiles is exhausted as particulates composed primarily of halide compounds (PbBrCl, $PbBr_2$, $PbCl_2$). The samples of soil were collected directly from the paddy fields with different distance from the roadside of highway and expressway which are located in Kyungpook province. A sequential extraction procedure was used to fractionate Pb in paddy field soil into the disignated forms of water soluable, exchangeable, organically bounded, carbonate, sulfide, and residual Pb. Results obtained are summerized as follows. 1. The content of Pb in paddy field soil was the highest in Chungdo, 30.0 ppm, the lowest in Koryung, 14.8 ppm, and the total average content was 21.9 ppm. The effect of traffic volume was not clear, but a slight difference according to the order of opened year of roads was showed. 2. The effect of distance from roadside was not clear. The content of Pb in paddy field soil with different distance from roadside was 22.2 ppm within l0m, 22.1 ppm in 10∼30m, 22.2 ppm in 30∼50m. and 21.3 ppm beyond 50m. 3. The distribution of Pb fractions in soil showed a wide difference depending on soil properties. The average content of exchangeable. organically bounded, carbonate, sulfide, and residual Pb was 8.6%, 33.6%, 29.8%, 21.5%, and 6.7%, of total Pb in the soil, respectively. 4. The content of organically bounded Pb in soil showed highly positive correlation with organic matter and CEC, while the content of exchangeable Pb was highly negative correlation. 5. With higher soil organic matter and CEC, organically bounded Pb fraction tend to be higher but exchangeable Pb fraction tend to be lower. Other forms of Pb showed no difference with soil organic matter contend and CEC. The distribution of Pb fraction related to CEC showed similiar tendency with that of organic matter content.

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Mechanical Characteristics of Light-weighted Foam Soil Consisting of Dredged Soils (준설토를 이용한 경량기포혼합토의 역학적 특성 연구)

  • 김주철;이종규
    • Journal of the Korean Geotechnical Society
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    • v.18 no.4
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    • pp.309-317
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    • 2002
  • The mechanical characteristics of Light-Weighted Foam Soil(LWFS) are investigated in this research. LWFS is composed of the dredged soil from offshore, cement and foam to reduce the unit-weight and increase compressive strength. For this purpose, the unconfined compression tests and triaxial compression tests are carried out on the prepared specimens of LWFS with various conditions such as initial water contents, cement contents, curing conditions and confining stresses. The test results of LWFS indicated that the stress-strain relationship and the compressive strength are strongly influenced by the cement contents rather than the intial water contents of the dredged soils. On the other hand, the stress-strain relationship from triaxial compression test has shown strain-softening behavior regardless of curing conditions. The stress-strain behavior for the various confining stress exhibited remarkable change at the boundary where the confining stress approached to the unconfined compression strength of LWFS. In order to obtain the ground improvement of the compressive strength above 200kPa, the required LWFS mixing ratio is found to be 100%~160% of the initial water contents of dredged soil and 6.6% of cement contents.

Environment-Friendly Bonding of Decorative Veneer by SIS-Based Hotmelt Pressure-Sensitive Adhesives (환경친화성 SIS계 핫멜트 점착제를 이용한 무늬목 접착)

  • Lim, Dong-Hyuk;Kim, Sumin;Park, Young-Jun;Kim, Hyun-Joong;Yang, Han-Seung
    • Journal of the Korean Wood Science and Technology
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    • v.34 no.3
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    • pp.22-29
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    • 2006
  • The overlaid panels are important materials in interior and construction with added surface layers (PVC films, decorative paper, decorative veneer). Generally, the adhesive for decorative veneer to wood-based panel is urea-formaldehyde (UF) adhesive which cause the emission of formaldehyde during not only the manufacturing process, but also service life. In this study, environment-friendly SIS-based hotmelt pressure-sensitive adhesive (PSA) was evaluated as a adhesive for bonding a decorative veneer. The various SIS-based hotmelt PSA was blended as a function of diblock content, softening point of tackifier, tackifier content, and applied to bonding the decorative veneer.

매실의 다양한 이용을 위한 가공 저장 및 포장방법

  • 은종방;김철암;차환수
    • Food preservation and processing industry
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    • v.3 no.1
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    • pp.68-80
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    • 2004
  • 매실을 다양하게 이용하고 부가가치를 높이며 매실의 품질저하 방지 및 이용성 증대를 도모하기 위하여 실시된 지금까지의 매실의 가공, 저장 및 포장 방법에 대한 것을 조사하였다. 매실의 저온저장 시청매실은 $0\~1^{\circ}C$의 저온보다도 $5\~8^{\circ}C$에서 저온 장해가 발생하기가 쉽다고 보고되었다. 이러한 장해를 방지하기 위하여 수확직후에 $0^{\circ}C$정도의 냉수로 급속히 청매실의 품온을 저하시키면 $5\~8^{\circ}C$의 저장에서도 저온장해가 경감되고 추숙도 억제한다고 한다. 상온 CA저장 조건 하에서 청매실의 선도를 유지하기 하는데 대량으로 발생하는 에틸렌의 제거와 저산소($2\%$ 하한), 고이산화탄소($8\%$)의 가스조성이 효과적이라고 보고되었다. 청매실의 저장 중 선도유지를 위하여 청매실을 저밀도폴리에틸렌(LDPE 20${\mu}m$) 필름 봉투에 포장하여 에틸렌 제거제를 넣고 $20^{\circ}C$에 저장한 결과, 에틸렌생성량은 낮은 수준으로 유지되었고 연화에 의한 품질저하가 현저히 억제된는 것을 볼 수 있다. 그리고 MA포장(LDPE 30${\mu}m+$에틸렌제거제)에서도 청매실의 녹색유지 효과가 탁월하였고 이산화탄소 농도가 높을수록 황화가 억제된 것이 연구에 의하여 밝혀졌다. 포장재의 두께를 달리할 때 청매실의 선도유지 효과도 서로 다르게 나타난다고 보고되었다. 청매실을 두께가 다른 필름에 포장, $25^{\circ}C$에서 8일간 저장한 매실은 LDPE 20, 30 필름에 포장한 것이 저장 8일에도 녹색을 그대로 유지한 것을 보아 선도유지 효과가 있음을 알 수 있다. 그리고 중량감소은 LDPE 30, 40이 적게 나타났고 장해정도는 LDPE 20, 30 적게 나타났다. 청매실의 저장 중 선도유지가 가장 양호한 LDPE 30 포장재에 청매실과 함께 탄산가스흡수제, 에틸렌제거제를 각각 또는 혼합첨가하고 밀봉한 후 $25^{\circ}C$에서 10일간 저장한 매실은 에틸렌제거제 첨가한 것이 녹색유지효과와 선도유지효과가 좋았으며 매실의 장해발생도 가장 낮은 것으로 보고되었다. 매실을 이용하여 제조되는 가공식품으로는 매실주, 매실차, 매실 Fruit leather, 매실절임, 고추장장아찌, 매실식초, 매실잼, 매실김치 등이 있다. 앞으로 매실의 이용을 증진시키고 소비를 더욱 촉진시키기 위해서는 매실의 생리학적특성을 이해하여 더욱 효과적인 저장 및 포장방법을 개발하고 생리활성을 이용한 새로운 매실제품의 개발에 대한 연구가 뒤따라야 할 것이다.

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Effects on Storage Property of Fresh Jujube Treated with Grape Fruit Stem Extracts (GFSE) and Fermented Pollen (FP) (포도줄기추출물 및 발효화분 처리가 생대추의 저장기간에 미치는 영향)

  • Woo, Koan-Sik;Hwang, In-Guk;Jang, Keum-Il;Kang, Tae-Su;Lee, Hee-Bong;Jeong, Heon-Sang
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.37 no.8
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    • pp.1090-1094
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    • 2008
  • Treatment effects of grape fruit stem extracts (GFSE) containing trans-resveratrol or fermented pollen (FP), and ethylene gas scavenging material (EGS) on the storage property of fresh jujube (Z izyphus jujuba forma hoonensis C.S. Yook) were investigated. Fresh jujubes were packed in different storage containers (PE film and Lock & Lock vessel), and treated with GFSE containing trans-resveratrol of 30 ppm or 1% FP, and EGS. The storage vessels were stored in refrigerator ($0{\pm}1^{\circ}C$) during 12 weeks, and then quality characteristics during storage period were analysed. Hardness slightly increased until 4 weeks and decreased afterward. Soluble solid ($^{\circ}Bx$) and total titratable acidity of fresh jujube slightly increased in all treatments during storage period. Vitamin C content of fresh jujube slightly decreased in all treatments during storage period. Number of microorganisms decreased until 4 weeks and increased afterward. The decay enzyme activity increased in all treatments during storage period. Storage stability was higher for PE film than Lock & Lock containers. Storage period of fresh jujube in this experiment ranges in $8{\sim}9$ weeks for maturity fruits treated with 30 ppm of GFSE and ethylene gas scavenging material.

Pre-sowing Treatments to Improve Germination of Intact Seeds in Burcucumber (Sicyos angulatus L.) (가종피가 부착된 안동대목 종자의 발아율 향상을 위한 파종전 종자처리)

  • 강진호;전병삼;윤수영;이상우;정종일
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.48 no.3
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    • pp.169-172
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    • 2003
  • Intact seeds of burcucumber (Sicyos angulatus L.) are not nearly germinated so that the farmers remove their arils before sowing. The study was carried out to measure the effort of aging, chilling, washing, chemical treatment, drying, and their sequential treatments on the germination of ones with arils and the seedling emergence. The seeds extruding over 1mm of their radicles and the seedlings with fully expanded cotyledons were counted daily for calculating the germination and the seedling emergence rates. Seedcoat softening using 10% NaOH solution somewhat enhanced their germination rate of the intact seeds harvested in the current year, but aging treatment done on 6 days at $45^{\circ}C$ after NaOH treatment increased the germination rate more than only NaOH treatment. A day washing after the NaOH treatment and a day chilling after the washing increasingly elevated the rates as well. Irrigation of 0.2% $\textrm{KNO}_3$ solution, moreover, showed the greatest germination rate of the priming treatments done during all the 7 day chilling. Drying the seeds after the combined treatment of chilling and priming more inclined the germination rate than nondrying ones, but red light treated during 24 hour desiccation was more effective in the germination rate increment than dark condition. The seeds done the sequential treatments of aging, NaOH, washing, combining chilling and priming and drying under red light illumination were germinated up to 80% but seedlings were emerged to 60%, lower than ones removed their arils.

Assessment of Pollution Level and Contamination Status on Mine Tailings and Soil in the Vicinity of Disused Metal Mines in Kangwon Province (강원도 폐금속광산지역의 광미와 주변토양의 중금속 오염현황 및 오염도 평가)

  • Kim, Joung-Dae
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.6
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    • pp.626-634
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    • 2005
  • The objectives of this study was to assess pollution level and contamination status on tailings and soil in the vicinity of four disused metal mines in Kangwon province. As the result of total metal concentrations analysis, the pollution degree of tailings and soil decreased in the order of Wondong > Second Yeonhwa > Sinyemi ${\fallingdotseq}$ Sangdong mines. Total metal concentrations of mine tailings in this study were $1.2{\sim}78.2$ and $1.1{\sim}80.6$ times higher than those in the background soil and the tolerable levels suggested by Kloke, respectively. From these results, we found that tailings served as contamination source of nearby soil. According to sequential extraction of metals, large proportion of heavy metals in all mine tailings existed in the form of a residual fraction, and heavy metals in non-residual form was mainly associated with Fe-Mn oxide fraction and sulfidic-organic fraction. Fe-Mn oxide fraction and sulfidic-organic fraction of heavy metals may be released into and contaminated the nearby environment under the oxidation or reduction condition in long-term. In particular, the proportions of the exchangeable and carbonate fraction of Cd in mine tailings from Second Yeonhwa mine were relatively high. This suggests that Cd may be easily released into and contaminated the nearby environment in the near time. Concentrations of heavy metals in mine tailings and the nearby soil exceeded the standard (agricultural area) of Soil Environment Conservation Law. So it was thought that remediation for mine tailings and the nearby soil is needed. The pollution indices of the samples in this study were for higher than 1.0 and the pollution degree was very serious. Priority remediation site for these mines was Wondong. As Results of danger indices, it was showed that exchangeable form in Wondong and Fe-Mn oxide form in the rest mines should be removed preferentially.

Re-evaluation of Genetic Environments of Zinc-lead Deposits to Predict Hidden Skarn Orebody (스카른 잠두 광체 예측을 위한 아연-연 광상 성인의 재검토)

  • Choi, Seon-Gyu;Choi, Bu-Kap;Ahn, Yong-Hwan;Kim, Tae-Hyeong
    • Economic and Environmental Geology
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    • v.42 no.4
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    • pp.301-314
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    • 2009
  • The Taebaeksan mineralized province, which is the most important one in South Korea, is rich in zinc-lead-tungsten-iron-copper-molybdenum-silver-gold mineral resources and has a diversity of deposit styles. These deposits principally coexist in time and space with porphyry-related epigenetic deposit such as skarn, hydrothermal replacement, mesothermal vein, and Carlin-like deposits. The magmatic-hydrothermal systems in the Taebaek fold belt is genetically characterized by the Bulguksa subvolcanic rocks(ca. $110{\sim}50\;Ma$) related to northwestward subduction of the paleo-Pacific Plate. The most important zinc-lead deposits in the area are the Uljin, Yeonhwa II and Shinyemi skarn, the Janggun hydrothermal replacement, and the Yeonhwa I intermediate-mixed (skarn/hydrothermal replacement) ones. In the present study, we present a compilation of metal production and mineral assemblage of the zinc-lead deposits. The metal difference of deposit styles in the area indicates a cooling path from intermediate-sulfidation to low-sulfidation state in the polymetallic hydrothermal system, reflecting spatial proximity to a magmatic source.

Preservative Safety Analysis of the Fresh Apple Snails and their Processing Products (우렁이 생체 및 가공제품의 저장안정성 조사)

  • Oh, Byung-Tae;Kang, Sung-Won;Choi, Sung-Gil;Heo, Ho-Jin;Cho, Sung-Hwan
    • Food Science and Preservation
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    • v.15 no.3
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    • pp.340-346
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    • 2008
  • This study investigated the microbial safety of apple snails and intermediate-moisture-content apple snail products subjected to various treatments, according counts of total bacteria, Escherichia coli, mold and yeast during storage at 4C Heating of raw apple snails at 95C for 5 min increased the storage period in relation to total bacteria, E. coli, mold and yeast-cell growth. Addition of 10% NaCl and 50% vinegar increased the microbial safety of apple snails. Microorganisms were not detected for 14 weeks in vacuum-packaged intermediate-moisture-content apple snail products stored at either 4C or 30C. These results suggest that heat treatment of raw apple snails, soaking in 10% NaCl and 50% vinegar solutions, and vacuum-packaging increases the shelf-life and microbial safety of apple snail products.

Optimization of Elastic Modulus and Cure Characteristics of Composition for Die Attach Film (다이접착필름용 조성물의 탄성 계수 및 경화 특성 최적화)

  • Sung, Choonghyun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.20 no.4
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    • pp.503-509
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    • 2019
  • The demand for smaller, faster, and multi-functional mobile devices in increasing at a rapidly increasing rate. In response to these trends, Stacked Chip Scale Package (SCSP) is used widely in the assembly industry. A film type adhesive called die attach film (DAF) is used widely for bonding chips in SCSP. The DAF requires high flowability at high die attachment temperatures for bonding chips on organic substrates, where the DAF needs to feel the gap depth, or for bonding the same sized dies, where the DAF needs to penetrate bonding wires. In this study, the mixture design of experiment (DOE) was performed for three raw materials to obtain the optimized DAF recipe for low elastic modulus at high temperature. Three components are acrylic polymer (SG-P3) and two solid epoxy resins (YD011 and YDCN500-1P) with different softening points. According to the DOE results, the elastic modulus at high temperature was influenced greatly by SG-P3. The elastic modulus at $100^{\circ}C$ decreased from 1.0 MPa to 0.2 MPa as the amount of SG-P3 was decreased by 20%. In contrast, the elastic modulus at room temperature was dominated by YD011, an epoxy with a higher softening point. The optimized DAF recipe showed approximately 98.4% pickup performance when a UV dicing tape was used. A DAF crack that occurred in curing was effectively suppressed through optimization of the cure accelerator amount and two-step cure schedule. The imizadole type accelerator showed better performance than the amine type accelerator.