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Development Status and Research Direction in the Mineral Carbonation Technology Using Steel Slag (제철 슬래그를 이용한 광물 탄산화 기술의 개발 현황과 연구 방향)

  • Son, Minah;Kim, Gookhee;Han, Kunwoo;Lee, Min Woo;Lim, Jun Taek
    • Korean Chemical Engineering Research
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    • v.55 no.2
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    • pp.141-155
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    • 2017
  • In the present paper, we investigated the development status of precipitated calcium carbonate (PCC) production using steel slag, which is one of mineral carbonation (MC) technologies, from the standpoint of $CO_2$ utilization. Principle, feature, and global and domestic development status of the mineral carbonation technology were discussed together with the overview of the production method and market of PCC. Mineral carbonation is known as stable and environmentally-friendly technology enabling economical treatment of industrials wastes. Typically, PCC is produced by the reaction of $CO_2$ with supernatant solution after Ca extraction from steel slag followed by the separation of solid and liquid. The development status of MC using steel slag is at the pilot stage (Slag2PCC at Aalto University), and there remains the process economics improvement for commercialization. Key technologies for the further development are efficient extraction of Ca ions from steel slag including impurities removal, valorization of PCC via shape and size control, usage development and value-addition of residual slag, and optimization of reaction conditions for continuous process setup, etc.

In situ Microfluidic Method for the Generation of Monodisperse Double Emulsions (미세유체를 이용한 단분산성 이중 에멀젼 생성 방법)

  • Hwang, So-Ra;Choi, Chang-Hyung;Kim, Hui-Chan;Kim, In-Ho;Lee, Chang-Soo
    • Polymer(Korea)
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    • v.36 no.2
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    • pp.177-181
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    • 2012
  • This study presents the preparation of double emulsions in a poly(dimethylsiloxane) (PDMS)-based microfluidic device. To improve the wettability of hydrophilic continuous phase onto a hydrophobic PDMS microchannel, the surface was modified with 3-(trimethoxysilyl) propyl methacrylate (TPM) and then sequentially reacted with acrylic acid monomer solution, which produced selective covalent bonding between acrylic acids and methacrylate groups. For the proof of selective surface modification, tolonium chloride solution was used to identify the modified region and we confirmed that the approach was successfully performed. When water containing 0.5% w/w sodium dodecyl sulfate and 1% w/w Span80 with hexadecane were loaded into the selectively modified microfluidic channels, we can produce stable double emulsion. Based on the spreading coefficients, we predict the morphology of double emulsions. Our proposed method efficiently produces monodisperse double emulsions having 48.5 ${\mu}m$(CV:1.6%) core and 65.1 ${\mu}m$ (CV:1.6%) shell. Furthermore, the multiple emulsions having different numbers of core were easily prepared by simple control of flow rates.

Dielectric Waveguide Filters Design Embedded in PCB Substrates using Via Fence at Millimeter-Wave (밀리미터파 대역에서 Via Fence를 이용한 PCB 기판용 유전체 도파관 필터 설계)

  • 김봉수;이재욱;김광선;강민수;송명선
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.15 no.1
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    • pp.73-80
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    • 2004
  • In this paper, the implementation and embedding method of the existing air-filled waveguide-filters at millimeter-wave on general PCB substrate is introduced by systematically inserting the vias inside waveguide and mathematically manipulating the simple equations obtained ken the classical circular-post waveguide filter design. All the metal structures placed vertically such as side wall fur perfect ground plane and circular-post for signal control in the air-filled WR-22 waveguide are replaced with several types of via for constructing the bandpass-filter. Side wall and poles inside waveguide are realized by placing a series array of via and tuning the via diameter. The lengths of x, y, z axis are reduced in proportion to root square of employed substrate dielectric constant and especially the length of z axis can be more reduced due to the characteristics of the wave propagation. Because the mass production on PCB is possible without fabricating a large-scaled metal waveguide of WR-22 as input/output ports at millimeter-wave regime, the manufacturing cost is reduced considerably. Finally, when using multilayer process like LTCC for small-sized module, it is one of advantages to use only one layer f3r the filter fabrication. To evaluate the validity of this novel technique, order-3 Chebyshev BPF(Bandpass-Filter) centered at 40 GHz-band with a 2.5 % FBW (Fractional Bandwidth) were used. The employed substrate has relative dielectric constant of 2.2 and thickness of 10 mil of Rogers RT/Duroid 5880. Accroding to design and measurement results, a good performance of insertion loss of 2 ㏈ and return loss of -30 ㏈ is achieved at full input/output ports.

Antioxidation Behavior of Submicron-sized Cu Particles with Ag Coating (서브 마이크론급 구리 입자의 은도금 공정에 따른 내산화성 강화 연구)

  • Choi, Eun Byeol;Lee, Jong-Hyun
    • Journal of the Microelectronics and Packaging Society
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    • v.23 no.3
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    • pp.51-56
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    • 2016
  • To fabricate a copper (Cu)-based fine conductive filler having antioxidation property, submicron silver (Ag)-coated Cu particles were fabricated and their antioxidation property was evaluated. After synthesizing the Cu particles of $0.705{\mu}m$ in average diameter by a wet-reduction process, Ag-coated Cu particles were fabricated by successive Ag plating using ethylene grycol solvent. Main process parameters in the Ag plating were the concentration of reductant (ascorbic acid), the injection rate of Ag precursor solution, and the stirring rate in mixed solution. Thus, Ag plating characteristics and the formation of separate fine pure Ag phase were observed with different combinations of process parameters. As a result, formation of the separate pure Ag phase and aggregation between Ag-coated Cu particles could be suppressed by optimization of the process parameters. The Ag-coated Cu particles which were fabricated using optimal conditions showed slight aggregation, but excellent antioxidation property. For example, the particles indicated the weight gain not exceeding 0.1% until $225^{\circ}C$ when they were heated in air at the rate of $10^{\circ}C/min$ and no weight gain until 75 min when they were heated in air at $150^{\circ}C$.

Design of Indoor Electric Moving and Lifting Wheelchair with Minimum Rotation Radius and Obstacle Overcoming (최소 회전반경 및 장애물 극복형 실내 전동 이·승강 휠체어의 설계)

  • Kim, Young-Pil;Ham, Hun-Ju;Hong, Sung-Hee;Ko, Seok-Cheol
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.20 no.10
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    • pp.415-424
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    • 2019
  • In this paper, a minimum rotation radius was designed and fabricated to overcome the threshold so that elderly or disabled people who have difficulty moving can move and transfer safely and conveniently in a narrow room. In the indoor environment, where the sedentary culture develops, this study aimed to provide convenience for passengers with fracture diseases, geriatric diseases, and other knee and waist diseases. First, links, seats, armrests, covers, motors, batteries, chargers, controllers, etc. were attached to the frame so that they could be moved and lifted indoors. The product design and structure were designed considering the user's environment and physical characteristics, and IoT functions were added. A driving experiment was performed to confirm the operating performance of the manufactured indoor moving and lifting wheelchair. The performance tests, such as continuous running time, turning radius, maximum actuator load, maximum lift height, sound pressure level, minimum sensing distance of the driving aid sensor, interworking of server and app programs, device compatibility, and duty cycle error rate, were performed. As a result of the test, the built-in wheelchair could achieve the performance test target of each item and operate successfully.

Identification of Synthesized Pitch Derived from Pyrolyzed Fuel Oil (PFO) by Pressure (석유계 잔사유(PFO)의 피치 합성 시 압력조건에 따른 피치 특성 변화)

  • Seo, Sang Wan;Kim, Ji Hong;Lee, Young-Seak;Im, Ji Sun
    • Applied Chemistry for Engineering
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    • v.29 no.6
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    • pp.652-656
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    • 2018
  • In this study, effects of the reaction pressure were studied for petroleum-based pitch synthesis. A two-stage reaction process was performed based on different reaction pressure conditions. Each stage experiments for the two-stage reaction were consecutively carried out. The first stage was consisted of three different pressure conditions; high (10 bar), normal and low (0.1 bar). And the second stage was carried out at the normal and low (0.1 bar) pressure. The pitch synthesis was realized at $400^{\circ}C$ for 2 h. Thermal properties and molecular weight distributions of each samples were investigated by analyzing the softening point and MALDI-TOF data. Volatilized components during the pith synthesis were measured by GC-SIMDIS. In case of the first-step reaction with the high pressure condition, the low molecular weight component participated to the pitch formation more effectively and the pitch with the low softening point was obtained. However, for the case of the first-step with the low pressure, the low molecular weight component was vent outside and the partial coke formation occurred. Eventually, pitch properties such as the softening point and yield were controlled effectively by changing the pressure in the pitch synthesis reaction.

Synthesis of Polymer-Silica Hybrid Particle by Using Polyamine Nano Complex (폴리아민 나노 복합체를 이용한 고분자-실리카 복합체 입자 합성)

  • Kim, Dong-Yeong;Seo, Jun-Hee;Lee, Byungjin;Kang, Kyoung-Ku;Lee, Chang-Soo
    • Clean Technology
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    • v.27 no.2
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    • pp.115-123
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    • 2021
  • This study demonstrates a new method for the synthesis of organic-inorganic hybrid particles composed of an inorganic silica shell and organic core particles. The organic core particles are prepared with a uniform size using droplet-based microfluidic technology. In the process of preparing the organic core particles, uniform droplets are generated by independently controlling the flow rates of the dispersed phase containing photocurable resins and the continuous phase. After the generation of droplets in a microfluidic device, the droplets are photo-polymerized as particles by ultraviolet irradiation at the ends of microfluidic channels. The core particle is coated with a nano complex composed of polyallylamine hydrochloride (PAH) and phosphate ion (Pi) through strong non-covalent interactions such as hydrogen bonding and electrostatic interaction under optimized pH conditions. The polyamine nano complex rapidly induces the condensation reaction of silicic acid through the arranged amine groups of the main chain of PAH. Therefore, this method enabled the preparation of organic-inorganic hybrid particles coated with inorganic silica nanoparticles on the organic core. Finally, we demonstrated the synthesis of organic-inorganic hybrid particles in a short time under ambient and environmentally friendly conditions, and this is applicable to the production of organic-inorganic hybrid particles having various sizes and shapes.

Zhuzi Learning, Yangming Learning, and Formation of "Gukhak": Genealogy of Subjectivity and Silsim (주자학과 양명학, 그리고 '국학'의 형성 - 주체성과 실심(實心)의 계보학 -)

  • Kim, Woo-hyung
    • The Journal of Korean Philosophical History
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    • no.58
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    • pp.307-336
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    • 2018
  • This paper traces the historical genealogy of the subjectivity and the silsim (實心, true mind) that appear in Jeong In-Bo's "gukhak" (國學, the national learning) thought and illuminates its characteristics. In the modern East Asian history of thought, the beginning of the emergence of subjectivity and the silsim as the main philosophical topic comes from the Neo-Confucianism of Song Dynasty in China. Cheng Yi is the first thinker to emphasize subjectivity and consciousness. Zhu Xi and Wang Yang-ming inherit the Neo-Confucian thought based on Cheng Yi's principle of subjectivity, but only show difference in methodology. In the Chosun Dynasty, Jeong Je-Doo and his School were one example of the Neo-Confucian spirit of subjectivity and the silsim. Although Jeong In-Bo (鄭寅普) belongs to Jeong Je-Doo's school of Ganghwa in the school curriculum, he has only used it methodologically since he believed that Yangming's learning is more effective in the awareness and practice of the silsim. Especially noteworthy is that the principle of subjectivity led Jeong In-Bo to follow the frame of Zhu Xi's moral theory. Jeong's claim that selfish desire (jasasim 自私心) should be controlled by a conscious mind (silsim) being aware of the right and 'ought to do' corresponds to Zhu Xi's view that the moral mind (dosim 道心) should be selected in the conflict situation between sensual desire (insim 人心) and moral consciousness so that the insim should be supervised by the dosim. Such ethics is a position to emphasize the inner motive and the sense of duty of conduct, and there is no fundamental difference in Zhu Xi and Wang Yang-ming. At least on this point, it is necessary to look at modern and contemporary Korean studies from the perspective of continuity, not discontinuity from Confucian tradition.

Generation and Verification of Synthetic Wind Data With Seasonal Fluctuation Using Hidden Markov Model (은닉 마르코프 모델을 이용하여 계절의 변동을 동반한 인공 바람자료 생성 및 검증)

  • Park, Seok-Young;Ryu, Ki-Wahn
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.49 no.12
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    • pp.963-969
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    • 2021
  • The wind data measured from local meteorological masts is used to evaluate wind speed distribution and energy production in the specified site for wind farm However, wind data measured from meteorological masts often contain missing information or insufficient desired height or data length, making it difficult to perform wind turbine control and performance simulation. Therefore, long-term continuous wind data is very important to assess the annual energy production and the capacity factor for wind turbines or wind farms. In addition, if seasonal influences are distinct, such as on the Korean Peninsula, wind data with seasonal characteristics should be considered. This study presents methodologies for generating synthetic wind that take into account fluctuations in both wind speed and direction using the hidden Markov model, which is a statistical method. The wind data for statistical processing are measured at Maldo island in the Kokunnsan-gundo, Jeonbuk Province using the Automatic Weather System (AWS) of the Korea Meteorological Administration. The synthetic wind generated using the hidden Markov model will be validated by comparing statistical variables, wind energy density, seasonal mean speed, and prevailing wind direction with measurement data.

Enhanced Primary Production in Response to Freshwater Inflow in the Nakdong River Estuary: Characteristics of land-Ocean Coupling (LOC) (낙동강 하구에서 담수 유입에 따른 연안 클로로필-a 증가 : 낙동강의 육상-해양 coupling 패턴 분석)

  • KIM, SUHYUN;AN, SOONMO
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.26 no.2
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    • pp.96-109
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    • 2021
  • Since terrestrial input plays a major role in coastal primary production, an understanding of land-ocean coupling (LOC) is key to understand coastal ecological changes. In this study, the LOC has been classified into three stages (i.e., the baseflow, plume event and residual flow). In order to characterize its pattern in Nakdong River estuary, multi-platform data were obtained from remote sensing (geostationary ocean color image (GOCI)), in-situ measurement (marine environment information system (MEIS)), on-site measurement (discharge data and meteorological data). The MEIS data were grouped into three stages of LOC using principal component analysis (PCA), and the LOC (2013 ~ 2018) was examined at each stage using multi-platform data. In the Nakdong River estuary, the maximum value of chlorophyll-a (chl-a) was unexpectedly appeared during the plume event. It is assumed that there was no significant increase in turbidity, expected during the typical plume event, together with the weak flushing effect, caused the enhanced phytoplankton growth. Compared with other estuaries, LOC is common in estuaries affected by freshwater inflow, but LOC has different pattern depending on the size of the plume. While estuaries that form small plumes of about 10 km (low freshwater discharge and weak flushing effect) observed high chl-a in the plume event because the phytoplankton can response to the increased nutrient more rapidly. estuaries that form large plumes of more than 100 km est (high freshwater discharge and strong flushing effect) follow the typical LOC pattern conceptualized in this study (high chl-a in the residual flow).