• Journal of the Korean Society of Propulsion Engineers
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• v.17 no.3
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• pp.21-29
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• 2013

Turbulent flow and thermal fields of gaseous hydrogen/liquid oxygen flames at supercritical pressure are investigated by turbulence models. The modified Soave-Redlich-Kwong (SRK) EOS is implemented into the flamelet model to realize real-fluid combustions. For supercritical fluid flows, the modified pressure-velocity-density coupling are introduced. Based on the algorithm, the relative performance of six convection schemes and the predictions of four turbulence models are compared. The selected turbulence models are needed to be modified to consider various characteristics of real-fluid combustions.

• Transactions of the Korean hydrogen and new energy society
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• v.27 no.6
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• pp.737-746
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• 2016

This article describes a comparison on laminar burning velocity measured by Bunsen and spherical flame methods of synthetic natural gas (SNG) with various composition of hydrogen. In this study, the laminar burning velocity measurements were employed by Bunsen burner and cylindrical constant combustor at which flame images were captured by Schlieren system. These results were also compared with numerical based on CHEMKIN package with GRI 3.0, USC-II and UC Sandiego mechanism. In case of spherical flames, the suitable flame radius range and theoretical models were verified using the well-known previous results in methane/air flames. As an experimental condition, hydrogen content of SNG was adjusted 0% to 11%. Equivalence ratios of Bunsen flames were adjusted from 0.8 to 1.6. On the other hand, those of spherical flames were adjusted from 0.6 to 1.4, relatively. From results of this study, the both laminar burning velocities measured in Bunsen and spherical flame methods were resulted in similar tendency. As the hydrogen content increased, the laminar burning velocity also increased collectively. Laminar burning velocity of measured SNG-air flames was best coincided with GRI 3.0 mechanism by comparison of reaction mechanisms.

• Transactions of the Korean hydrogen and new energy society
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• v.29 no.5
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• pp.538-548
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• 2018

The thermo-acoustic instability in the combustion process of a gas turbine is caused by the interaction of the heat release mechanism and the pressure perturbation. These acoustic vibrations cause fatigue failure of the combustor and decrease the combustion efficiency. This study is to develop a segmented dynamic thermo-acoustic model to understand combustion instability of gas turbine. Therefore, this study required a dynamic analysis rather than static analysis, and developed a segmented model that can analyze the performance of the system over time using the Matlab/Simulink. The developed model can confirm the thermo-acoustic combustion instability and exhaust gas concentration in the combustion chamber according to the equivalent ratio change, and confirm the thermo-acoustic combustion instability for the inlet temperature and the load changes. As a result, segmented dynamic thermo-acoustic model has been developed to analyze combustion instability under the operating condition.

• The Transactions of The Korean Institute of Electrical Engineers
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• v.58 no.2
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• pp.327-331
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• 2009

Nano-porous $TiO_2$ powder was fabricated using Acetylene black, applied photo voltaic device based on the Dye-sensitized Solar Cells (DSCs) was investigated experimentally. $TiO_2$-powder was fabricated using Ti-isopropoxide and 2-propanol by sol-gel combustion method. For cases of variable Acetylene black, characteristic of porosity, size of particle and crystallite of obtained $TiO_2$ nano-powder was investigated. The photovoltaic efficiency of the prepared DSCs was measured using $TiO_2$ film which prepared on each different heat treatment temperature($400^{\circ}C{\sim}700^{\circ}C$) with paste of $TiO_2$ powder. The porosity and size of particle of $TiO_2$ powder made with Acetylene black 0.4g was influenced significantly effect to DSCs characteristic. Heat treatment at $500^{\circ}C$ makes the better photovoltaic efficiency which 5.02%($J_{sc}=11.79mA/cm^2$, $V_{oc}=0.73V$, ff=0.58). The sol-gel combustion method was useful to DSCs fabrication.

• Journal of the Korean Society of Propulsion Engineers
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• v.21 no.6
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• pp.73-82
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• 2017

Low-cycle thermal fatigue problem resulting from multiple use of a liquid rocket engine has to be considered for the development of a reusable launch vehicle. In this study, life prediction equations suggested by previous researchers were compared as applied to various copper alloy cases to predict fatigue lives from tensile test data. The present study has revealed that among the presently considered life prediction methods, universal slopes method provides the best life prediction result for the copper alloys, and the modified Mitchell's method provides the best life prediction result for oxygen free high conductivity (OFHC) copper.

• Transactions of the Korean Society of Mechanical Engineers
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• v.19 no.11
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• pp.3054-3062
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• 1995

Recently, the improvement of fuel economy and the reduction of exhaust smoke and NOx have been successfully achieved by supplying diesel engines with emulsified diesel oil with water particles. In the present paper, the difference between the combustion of injected emulsified fuel and that of diesel oil spray is clarified by means of taking high-speed and color photographs of the flames in the engine cylinder. As the results, the two kinds of fuels show different combustion behavior each other in the growth of initial flame and in the termination of combustion process in the cylinder. Then, suitable combustion chamber design for the use of emulsified fuel is discussed on the basis of experimental data for various distribution of spray in different kinds of piston cavities. Some methods of clearing troubles caused by emulsified fuel injection are also discussed on the basis of performance tests with a remodeling test engine.

• Korean Chemical Engineering Research
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• v.45 no.3
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• pp.209-214
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• 2007

Sr hexaaluminate($Sr_{1-x}La_xMnAl_{11}O_{19-\alpha}$) were prepared by sol-gel method of metal alkoxide with 1-butanol or ethylene glycol as a solvent. The physical properties of prepared hexaaluminates were examined by TG/DTA, XRD and $N_2$ adsorption. When ethylene glycol was used as a solvent, the decomposition reaction and dehydroxylation reaction was observed above $400^{\circ}C$ and the temperature of the formation of a crystal structure of hexaaluminate was also increased resulting in small specific surface area and low catalytic activity of methane compared to Sr-hexaaluminate with 1-butanol.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.35 no.9
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• pp.961-967
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• 2011

The objective of this study was to develop a new method for estimating gas interchangeability for 13A gas appliances. The three basic principles for the development of this method are as follows: 1) to derive the secondary interchangeability factor that represents the effect of gas composition, in addition to the major interchangeability factor, i.e., Wobbe index; 2) to test every type of and each maker's domestic gas appliances that are widely used in our country, particularly including premixed gas appliances; and 3) to develop a simple estimation method. On the basis of these principles, thirty representative gas appliances were tested, and as a result, a simple two-dimensional interchangeability diagram consisting of Wobbe index and relative density was developed. Unlike conventional methods for estimating interchangeability, this method can be applied to premixed gas appliances, which have a narrow stable flame range, and the interchangeability range of this method then becomes narrower than that of the conventional methods.

• Journal of the Korean Electrochemical Society
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• v.13 no.4
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• pp.264-269
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• 2010

$LiNi_{0.5}Mn_{0.3}Co_{0.2}O_2$ active material was prepared by simple-combustion method and investigated as the cathode material for li-ion battery. The structural characterization was analyzed by X-ray diffraction (XRD) and field emission scanning electron microscopy (FE-SEM), respectively. The XRD patterns of $LiNi_{0.5}Mn_{0.3}Co_{0.2}O_2$ sample was indicated a phase of layered hexagonal structure. The size of particles has not uniform diameters ranging from 100 to 300 nm. The electrochemical performance of the $LiNi_{0.5}Mn_{0.3}Co_{0.2}O_2$ was measured by Cyclic Voltammetry and galvanostatics. The $LiNi_{0.5}Mn_{0.3}Co_{0.2}O_2$ shows the discharge capacity of ~162 mAh/g in the range of 2.8 to 4.3 V at the first cycle.

• Journal of the Korean Ceramic Society
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• v.42 no.1
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• pp.69-75
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• 2005

To investigate the morphological effect on synthesis of aluminum nitride by SHS Process, two type of Al Powder (granular and flacky shape) with the mean size of 34 $\mu$m and the diluent AIN powders of four different mean sizes.0.12, 9.7, 39.3, 50.5 $\mu$m, were used to prepare green compact. The packing density was fixed to $35 TD\%. The initial pressure of $N_{2}$ and diluent fraction was varied in the range of $1\~10 MPa,\;0.4\~0.7$, respectively. AlN with high purity of $98\% or over and large particle size of about several tens fm can be synthesized by SHS reaction as a consequence of adjusting particle size of AlN dilutent similarly to that of Al reactant. This may be caused by improvement of $N_{2}$ gas permeation to compact after passing the propagation wave. In the case of flaky-shape aluminum used as reactant, instead of granular Al-powder, unstable combustion would be occurred. As the result, irregular propagation of combustion wave and falling-off of maximum temperature would be observed during the reaction.