• Journal of Environmental Impact Assessment
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• v.27 no.5
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• pp.431-446
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• 2018

In this study, chemical characteristics of $PM_{2.5}$ samples collected in an agricultural area in Nonsan of Korea were investigated focusing on of black carbon, 3 inorganic ions and 22 trace elements. It was found that the relative error and relative standard deviation of many trace elements fell below 10%, which indicates good analytical accuracy and precision. The mean values of $PM_{2.5}$ in an agricultural area were exceeded by new Korean air quality standard of March 2018. The concentration of $PM_{2.5}$ was well correlated with those of black carbon and ions. The concentrations of trace elements were in a wide range of seven orders of a magnitude. Based on these $PM_{2.5}$ data sets, a total of 6 sources were identified using PMF (Positive Matrix Factorization; secondary aerosol (34.4%), soil/road dust (20.1%), biomass burning (16.9%), incineration/fuel combustion (13.2%), vehicle exhaust(12.2%), sea-salt (3.17%). Results of our study indicate that it is very important to control illegal burning activities in agricultural area.

• Korean Journal of Food Science and Technology
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• v.14 no.2
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• pp.168-173
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• 1982

The present study was carried to observe the total mercury contents in fresh-water fishes which were collected from 24 streams in the South-East area, Korea. These total mercury contents were determined by quartz tube combustion gold amalgamation method. The value of total mercury contents in collected fresh-water fishes ranged from 0.02ppm to 0.12ppm and the mean value were 0.07ppm. The total value of mercury contents differed with the fish species showing 0.09ppm in Carassius auratus, 0.10ppm in Coilia ectenes, 0.11ppm in Moroca lagowskii and Squalidus majime and 0.12ppm in Cobitis taenia which were highly more than the mean value of collected fishes. The mean value of the total mercury contents in the Yeong Il Gun (0.09PPm), Gim Hae Gun (0.08ppm) and Meong Ju Gun (0.08ppm) were highly detected than those of other surveyed areas.

• Resources Recycling
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• v.9 no.1
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• pp.27-35
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• 2000

Characteristics of pyrolytic gasification were examined for the waste tire and 7 types of waste synthetic resin, using a bench scale experimental facility. the product gas temperature of waste tires was $150~300^{\circ}C$ and the temperature profile in the combustion zone of the lower reactor part tended to be clearly distinguished from that in the gasification zone of the upper part. However, in the case of waste synthetic resins, there were no clear distinction and temperature fluctuation was severe, depending on the reaction time. Product gas quantity, which depends on that of supplied (1st) air, was found to be 105~135% of the 1st air amount at the steady state. The concentration of noncombustible components in product gas was 80~90 vol.% and the high heating value of the product gas calculated from gas compositions was 1,500~3,000 kcal/N㎥ for waste tire, and 300~2,900 kcal/N㎥ for waste synthetic resins, respectively. Heating value of product gas and combustible gas concentration were increased in proportion to 1st air amount when 1st air amount is below $0.35N\textrm{m}^3$/min.

• Clean Technology
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• v.26 no.1
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• pp.65-71
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• 2020

Various solar hybrid energy conversion processes, which have both the advantages of renewable energy sources and fossil energy sources, have been developed in the world because stable and predictable energy supplies, such as electricity and natural gas, are necessary for modern societies. In particular, a solar hybrid energy conversion process based on a dual fluidized bed process concept has been expected as the promising solution for sustainable energy supply via thermochemical conversions, such as pyrolysis, combustion, gasification, and so on, because solar thermal energy could be captured and stored in fluidized bed materials. Therefore, the attrition and heat transfer characteristics of silicon carbide and alumina particles used for fluidized bed materials for the solar hybrid energy conversion process were studied in an ASTM D5757 reactor and a bubbling fluidized bed reactor with 0.14m diameter and 2m height. These characteristics of novel fluidized bed materials were compared with those of sand particles which have widely been used as a fluidized bed material in various commercial fluidized bed reactors. The attrition resistances of silicon carbide and alumina particles were higher than those of sand particles while the average values of heat transfer coefficient in the bubbling fluidized bed reactor were in the range of 125 ~ 152 W m^-2K^-1.

• Korean Journal of Materials Research
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• v.5 no.7
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• pp.835-841
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• 1995

The deposition properties of Si$_3$N$_4$ deposited by low pressure chemical vapor deposition were studied to evaluate Si$_3$N$_4$as part of multi-layer coatings for anti-oxidation and anti-wear coating of graphite in the propellant-burning environment. Si$_3$N$_4$was deposited on the pack-SiC coated graphite and the tendencies of deposition rate and surface morphology changes with temperatures and reaction gas ratios were investigated. In low deposition temperatures the deposition rate increased tilth increasing temperature but in high temperatures the deposition rate decreased with increasing temperature. The grain size of Si$_3$N$_4$decreased with increasing temperature. In condition that the range of reaction gas ratios is 20$\leq$NH$_3$/SiH$_4$$\leq$40, the deposition rate and surface morphology did not change. The Si$_3$N$_4$deposited at 800~130$0^{\circ}C$ was amorphous, and by post-annealing at 130$0^{\circ}C$ in a $N_2$ambient, the Si$_3$N$_4$crystalized.

• Analytical Science and Technology
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• v.13 no.5
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• pp.601-607
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• 2000

Lanthanum has been used as one of the burnup monitor in spent nuclear fuel. $U_3Si/Al$ spent nuclear fuel contains small amount of La in high concentration of U and Al. Therefore, chemical separation of La is required to remove matrix elements. At first, ion chromatography (IC) and inductively coupled plasma systems were installed in radiation shielded glove box to handle the radioactive samples. Retention behavior of uranium, aluminum, lanthanum and some interesting fission products (Sr, Zr, Y, Mo, Ru, Pd, Rh, Cs, Ba, Ce, Pr, Nd, Sm, Eu and Cd) was investigated using the CG10 column and ${\alpha}$-HiBA eluent. As all elements were eluted earlier than lanthanum in 0.2 M ${\alpha}$-HiBA eluent, a portion of U and Al was directly passed to waste using a three way valve between the column and the nebulizer. Thus it was possible to determine the lanthanum in a high concentration of U and Al matrix. Retention time of La was about 12 minutes in this separation condition. Optimum range for the determination of La in $U_3Si/Al$ spent nuclear fuel was $1-10{\mu}g/L$ (ppb) with this system and detection limit was $0.25{\mu}g/L$ in case of $200{\mu}L$ of sample volume.

• Applied Chemistry for Engineering
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• v.17 no.1
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• pp.44-51
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• 2006

Effects of multiple-cycle operation and $SO_2$ concentration on $CO_2$ capture characteristics of three limestones were investigated in a fluidized bed reactor. For each of these sorbents, the measured $CO_2$ capture capacity decreased as the number of cycles increased and as the $SO_2$ concentration increased. On the other hand, the $SO_2$ capture increased with the increased number of cycles and the $SO_2$ concentration. The total calcium utilization decreased as the number of cycles increased, but the effect of $SO_2$ concentrations on the total calcium utilization depended on the type of limestone. For Strassburg limestone, the total calcium utillization decreased with increasing $SO_2$ concentration. However, for Luscar and Danyang limestones, the total calcium utilization was almost independent of $SO_2$ concentration for the range investigated. The results showed that $SO_2$ in flue gas reduced the $CO_2$ capture capacity of limestone and that the sulfation pattern affected the $CO_2$ capture capacity.

• Fire Science and Engineering
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• v.30 no.5
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• pp.67-73
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• 2016

This paper examined the structure, fire resistance of brass fittings type CSST employed in gas appliances and the reliability verification. Brass fittings of type CSST consisted of cladding, tubing, nut, clamp ring, socket, and ball valve. The applicable JIA standard regulates the maximum working pressure to be 4.2 kPa, which is the highest pressure of the relevant standards and the KS D 3625 stipulates the maximum pressure to be 3.24 kPa. With a normal product, the average resistance within the confidence interval was found to be $7.36m{\Omega}$. The average resistance within the confidence interval was $6.67m{\Omega}$ after the fire resistance tests. The analysis indicated that the AD was 1.584 and the standard deviation was 0.3972 with respect of a normal product. Compared to the normal product, however, the damaged product after the fire resistance test showed better features, such as an AD of 1.145 and a standard deviation of 0.2467. Moreover, the average resistance of the normal product was $7.359m{\Omega}$ and the standard deviation in histogram analysis was 0.3972. The average resistance of the damaged product after the fire resistance test in the histogram was $6.67m{\Omega}$ and the standard deviation was 0.2467.

• Journal of the Korean Magnetics Society
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• v.24 no.3
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• pp.81-85
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• 2014

Nano-sized Ba-ferrite, Ni-Zn ferrite and $BaFe_{12}O_{19}/Ni_{0.5}Zn_{0.5}Fe_2O_4$ nanocomposite ferrite were prepared by sol-gel combustion method. Nanocomposite was calcined at temperature range of $600{\sim}900^{\circ}C$ for 1 h. According to the diffraction patterns, hard/soft nanocomposite was indicated to the coexistence of the magnetoplumbite structural $BaFe_{12}O_{19}$ and spinel $Ni_{0.5}Zn_{0.5}Fe_2O_4$ and agree with the standard data (JCPDS 10-0325). The particle size of nanocomposite turn out to be less than 90 nm. The nanocomposite ferrite shows a single-phase magnetization behavior, implying that the hard magnetic phase and soft magnetic phase were well exchange-coupled. The specific saturation magnetization ($M_s$) of the nanocomposite is located between hard ($BaFe_{12}O_{19}$) and soft ferrite ($Ni_{0.5}Zn_{0.5}Fe_2O_4$). The remanence (Mr) of nanocomposite ferrite is much higher than that for the individual $BaFe_{12}O_{19}$ and $Ni_{0.5}Zn_{0.5}Fe_2O_4$ ferrite. $(BH)_{max}$ is increased, generally.

• Journal of Digital Convergence
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• v.10 no.7
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• pp.201-206
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• 2012

Benzo(a)pyrene is a polycyclic aromatic hydrocarbons (PAHs) whose metabolites are mutagenic and highly carcinogenic and is listed as a Group 1 carcinogen by the IARC. It has been found at variable concentrations in several foods and is associated with several factors during the process including contaminated raw materials, exposure of environment, and procedure of process or cooking. In this study, benzo(a)pyrene in 45 oriental medicines were determined by HPLC/FLD. The calibration curves of benzo(a)pyrene was linear over the concentration range of 0.5~40 ng/mL with correlation coefficient of above 0.999. The limit of detection (LOD) and limit of quantitation (LOQ) of benzo(a)pyrene were 0.04 and 0.10 ${\mu}g/kg$. Benzo(a)pyrene in 3 samples out of 45 samples was not detected. The level of benzo(a)pyrene in 26 (57.7%), 8 (17.8%) and 7 (15.6%) samples was 0.1~0.5, 0.5~1.0 and 1.0~5.0 ${\mu}g/kg$, respectively. Especially, content of benzo(a)pyrene in Coptis Rhizome is the highest (5.97 ${\mu}g/kg$). In conclusion, these results suggest that could be applied to fundamental study and guideline on drying condition to decrease content of benzo(a)pyrene in oriental medicine.