• Title/Summary/Keyword: 연소반응

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A Study of Transonic Premixed Combustion in a Diverging Channel Using Asymptotic Analysis (점근해석을 이용한 확대형 채널 내의 천음속 예혼합 연소에 관한 연구)

  • Lee, Jang-Chang
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.33 no.8
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    • pp.75-83
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    • 2005
  • A steady transonic dilute premixed combustion in a diverging channel is investigated by using asymptotic analysis. This model explores the nonlinear interactions between the near-sonic speed of the flow, the small changes in geometry from a straight channel, and the small heat release due to the one-step first-order Arrhenius chemical reaction. The reactive flow is described by a nonhomogeneous transonic small-disturbance (TSD) equation coupled with an ordinary differential equation for the calculation of the reactant mass fraction in the combustible gas. Also the asymptotic analysis reveals the similarity parameters that govern the reacting flow problem. The results show the complicated nonlinear interaction between the convection, reaction, and geometry effects and its effect on the flow behavior.

A Study on the Combustion Characteristics over Pd/cordierite Catalyst (Pd/cordierite 촉매상에서 메탄의 연소 특성 고찰)

  • Cho, Won-Ihl;Oh, Young-Sam;Park, Dal-Ryung;Baek, Young-Soon;Pang, Hyo-Sun;Mok, Young-Il
    • Journal of Energy Engineering
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    • v.6 no.1
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    • pp.34-40
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    • 1997
  • This study aims to investigate the application possibility on natural gas in relation to the catalytic combustion of methane on Pd/cordierite catalyst which is currently used as an automobile converter catalyst. The surface area of the catalyst tested was determined to be about 18.7㎡/g and to keep stable condition in structure at mid-high temperatures. The activation energy for methane combustion reaction was estimated to be 19.2 kcal/mol and a hysterisis on the catalyst activity was observed in terms of the catalyst deactivation as the reaction temperature was varied for the methane combustion. On Pd/cordierite catalyst, The characteristics of methane combustion were studied as functions of space velocity and air/fuel ratios below 700$^{\circ}C$.

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Prediction of Pollutant Emissions from Lean Premixed Gas Turbine Combustor Using Chemical Reactor Network (화학반응기 네트워크을 이용한 희박 예혼합 가스터빈 연소기에서의 오염물질 예측에 관한 연구)

  • Park, Jung-Kyu;Nguyen, Truc Huu;Lee, Min-Chul;Chung, Jae-Wha
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.36 no.2
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    • pp.225-232
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    • 2012
  • A chemical reactor network (CRN) was developed for a lean premixed gas turbine combustor to predict the emission of pollutants such as NOx and CO. In this study, the predictions of NOx and CO emissions from lean premixed methane-air combustion in the gas turbine were carried out using CHEMKIN and a GRI 3.0 methane-air combustion mechanism, which includes the four NO formation mechanisms for various load conditions. The calculated results were compared with experimental data obtained from a modified test combustor to validate the model. The contributions of the four NO pathways were investigated for various load conditions. The effects of nonuniformity of the mass flux and of the equivalence ratio of the injector on the NOx formation were investigated, and a method of reducing the pollutant formation was suggested for the development of a sub-10 ppm gas turbine combustor.

The Study on Minimum Smoke Propellant to Reduce Afterburning Reaction (후연소 반응이 감소된 무연계 고체 추진제에 관한 연구)

  • Yim, Yoojin;Lee, Jongseop;Park, Euiyong;Choi, Sunghan;Yoo, Jichang;Cho, Young
    • Journal of the Korean Society of Propulsion Engineers
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    • v.17 no.5
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    • pp.10-17
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    • 2013
  • This paper describes a study on after-burning suppressant in a solid propellant to reduce the plume formed outside of rocket nozzles, which could expose the launch site and the flight track. The minimum smoke propellant to enhance the stealth ability was formulated in terms of the kinds and the effects of after-burning suppressant on the ballistic performance and the amount of primary smoke. A after-burning suppressant, $K_2SO_4$ of about 1.1% weight content was found to show profound reduction of the rocket plume, giving negligibly slight increase in pressure exponent of burning rate. Also minimum smoke propellant with less than 1.1% of $K_2SO_4$ corresponds to A-class satisfaction in primary smoke by AGARD standard.

Numerical analysis on performances and emission characteristics of HCCI engine fueled with hydrogen added biogas (반응 메커니즘 기반의 수소 첨가 바이오가스 HCCI 엔진 성능 및 배출가스에 대한 수치 해석적 연구)

  • Park, Jungsoo
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.12
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    • pp.41-46
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    • 2018
  • In this research, numerical analysis was performed to determine the effects of hydrogen on biogas combustion for homogeneous charged compression ignition (HCCI) engines. The target engine specifications were a 2300cc displacement volume, 13:1 compression ratio, 15kW of electricity, and 1.2 bar boost pressure. The engine speed was fixed to 1800rpm. By varying the excess air ratio and hydrogen contents, the cylinder pressure, nitric oxide, and carbon dioxide were measured as a function of the hydrogen contents. According to preliminary studies related to the reaction mechanism for methane combustion and oxidation, a GRI 3.0 mechanism as the base mechanism was selected for HCCI combustion calculations describing the detailed reaction mechanism. By adding hydrogen, NO was increased while $CO_2$ was decreased. The cylinder pressure was also increased, having advanced timing for the maximum cylinder pressure and pressure rise region. Furthermore, lean operation limits were extended by adding hydrogen to the HCCI engine.

Reaction Parameters on the Reactivity in the Preparation of B4C by SHS (자전연소합성법에 의한 B4C분말의 제조에 있어 반응성에 대한 반응변수의 고찰)

  • Shin, Chang-Yun;Yun, Ki-Seok;Park, Yeong-Cheol;Hayk, Nersisyan;Won, Chang-Whan
    • Journal of the Korean Ceramic Society
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    • v.42 no.1
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    • pp.22-27
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    • 2005
  • The preparation of B4C by SHS in $B_{2}O_{3}-Mg-C$ system was investigated in this study. In the preparation of B4C, the effect on reactivity and reaction products of the initial pressure of inert gas in reactor, the content of Mg and C in mixture was investigated. The minimum initial pressure of inert gas in reactor for SHS reaction in this system was 25 atm, and as the pressure increased, the concentration of unreacted Mg decreased and combustion temperature increased. At the initial inert gas pressure in reactor of 25 atm, the optimum composition for the preparation of pure B4C was $2B_{2}O_{3}+6.3Mg +0.94C$. The B4C synthesized in this condition had an irregular shape and the particle size of $1\~3{\mu}m$.

Numerical Modeling for Turbulent Combustion Processes of Vortex Hybrid Rocket (Vortex Hybrid 로켓 난류연소과정의 모델링 해석)

  • 조웅호;김후중;김용모;윤명원
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2003.05a
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    • pp.244-245
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    • 2003
  • 고체나 액체 추진로켓에 비하여 하이브리드 추진 시스템은 작동조건의 안정성과 안전함등의 많은 장점을 가지고 있다. HTPB와 같은 고체연료는 제작 및 저장, 운송 그리고 장착상의 안정성을 가지고 있으며 하이브리드 로켓의 고체연료로의 산화제의 유입을 제어하면서 추력의 변화와 엔진내부의 연소중단과 재 점화를 용이하게 할 수 있다. 이러한 이유로 인하여 하이브리드 엔진은 좀 더 경제적인 장치로 기대를 모으고 있다. 그러나, 기존의 하이브리드 로켓 엔진은 고체 추진 로켓에 비하여 낮은 연료 regression 율과 연소효율을 가지는 단점이 있다. 이러한 단점을 해결하고 요구되어지는 추력값과 연료유량을 증가시키기 위하여 고체연료의 표면적을 증가시킬 필요가 있다. 기존의 하이브리드 엔진에서는 연료 그레인에 다수의 연소포트를 만들어 표면적을 증가시켰으나 이는 비 활용 공간의 증가와 추진제의 질량 및 체적분율의 상당한 감소를 초래한다. 지난 수십년간에 걸쳐 하이브리드 엔진에서 연료의 regression 특성 및 엔진 성능 향상을 위한 연구가 계속되어 왔으며 최근에 엔진의 체적 규제를 경감시키고 연료의 regression율을 향상시키기 위하여 선회유동을 이용하는 하이브리드 로켓 엔진들이 제안되고 있다. 이러한 선회유동을 가지는 하이브리드 로켓은 고체연료 그레인에 대하여 평행하게 유입되는 기존의 하이브리드 로켓에 비하여 고체연료 벽면에서의 대류열전달이 현저하게 증가하게 되어 아주 높은 고체연료의 regression율을 얻을 수 있는 이점이 있다. 선회유동 하이브리드 로켓의 연소과정은 고체 연료의 열분해과정, 대류 열전달, 난류 혼합, 난류와 화학반응의 상호작용, soot의 생성 및 산화과정, soot 입자 및 연소가스에 의한 복사 열전달, 연소장과 음향장의 상호작용 등의 복잡한 물리적 과정을 포함하고 있다. 이러한 물리적 과정 중 난류연소, 고체연료 벽면 근방에서의 대류 열전달 및 연소과정에서 생성되는 soot 입자로부터의 복사 열전달, 그리고 고체연료 열 분해시 표면반응들은 고체연료의 regression율에 큰 영향을 미친다. 특히 고체연료의 난류화염면의 위치와 폭, 그리고 비 예혼합 난류화염장에서 생성되는 soot의 체적분율의 예측은 난류연소모델, 열전달 모델, 그리고 regression율 모델에 의해 크게 영향을 받기 때문에 수치모델의 예측 능력 향상시키기 위하여 이러한 물리적 과정을 정확히 모델링해야 할 필요가 있다. 특히 vortex hybrid rocket내의 난류연소과정은 아래와 같은 Laminar Flamelet Model에 의해 모델링 하였다. 상세 화학반응 과정을 고려한 혼합분율 공간에서의 화염편의 화학종 및 에너지 보존 방정식은 다음과 같다. 화염편 방정식과 혼합분률과 scalar dissipation rate의 관계식을 이용하여 혼합분률과 scalar dissipation rate에 따른 모든 reactive scalar들을 구하게 된다. 이러한 화염편 방정식들을 mixture fraction space에서 이산화시켜서 얻은 비선형 대수방정식은 TWOPNT(Grcar, 1992)로 계산돼 flamelet Library에 저장되게 된다. 저장된 laminar flamelet library를 이용하여 난류화염장의 열역학 상태량 평균치는 presumed PDF approach에 의해 구해진다. 본 연구에서는 강한 선회유동을 가지는 Hybrid Rocket 연소장내의 난류와 화학반응의 상호작용을 분석하기 위하여 Laminar Flamelet Model, 화학평형모델, 그리고 Eddy Dissipation Model을 이용한 수치해석결과를 체계적으로 비교하였다. 또한 Laminar Flamelet Model과 state-of-art 물리모델들을 이용하여 선회 유동을 갖는 하이브리드 로켓 엔진의 연소 및 Soot 생성 및 산화과정을 살펴보았으며 복사 열전달이 고체 연료 표면의 regression율에 미치는 영향도 살펴보았다. 특히 swirl강도, 산화제의 유입위치 그리고 선회유동의 형성방식이 하이브리드 로켓의 연소특성 및 regression rate에 미치는 영향을 상세히 해석하였다.

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고온 연소 합성법을 이용한 탄화규소(SiC)의 합성 및 핵연료 도포 연구

  • Choi, Yong;Lee, Jeong-Won;Lee, Young-Woo;Son, Dong-Seong
    • Proceedings of the Korean Nuclear Society Conference
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    • 1996.05c
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    • pp.225-230
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    • 1996
  • 탄화규소(SiC)가 도포된 핵연료 제조를 위해 고온 연소 합성법(Self-propagating High Temperature Synthesis, SHS)이 적용되었으며, 반응물로 규소(Si) 분말, 규소 박막 (Si-thin film), 흑연 분말과 카본(C) 화이버가 사용되었다. 규소 박막은 프라즈마가 강화된 화학증착법(a microwave pulsed electron cyclotron resonance plasma enhanced chemical vapor deposition)으로 준비되었다. 그 결과 규소와 탄소의 고온 연소 합성반응 생성물은 반응물이 분말이거나 박막에 관계없이. 탄화규소(SiC)가 합성되었으며, 생성물의 형상(morphology)은 초기 탄소의 형상에 의존하였다. 본 연구를 통해 고온 연소 합성법이 탄화규소와 탄소가 도포된 핵연료 제조에 적용 가능함을 알 수 있었다.

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Fast Cook-Off Test and Evaluation for HTPE IM Rocket Motor (HTPE 둔감 추진기관의 급속가열 시험 및 평가)

  • Lee, Do-Hyung;Kim, Chang-Kee;Yeon, Jeong-Mo;Jung, Jung-Young;Yoo, Ji-Chang
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2009.11a
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    • pp.167-170
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    • 2009
  • Fast cook-off test with rocket motors was performed and characteristics of the results were analyzed. The material of the motor case was carbon epoxy composite. The motor was loaded with HTPE propellants to improve the insensitive munitions characteristics. In the tests, sound pressure and heat flux sensors were used to determine the category of response according to the standard. The reaction response of all of the HTPE motors tested by fast cook-off was judged as Type V burning.

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Impact Test and Evaluation for HTPE IM Rocket Motor (HTPE 둔감 추진기관의 충격 시험 및 평가)

  • Kim, Chang-Kee;Lee, Do-Hyung;Yeon, Jeong-Mo;Yoo, Ji-Chang
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2009.11a
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    • pp.163-166
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    • 2009
  • Bullet and fragment impact test with rocket motors was performed and characteristics of the results were analyzed. The material of the motor case was carbon epoxy composite. The motor was loaded with HTPE propellants to improve the insensitive munitions characteristics. In the tests, sound pressure and heat flux sensors were used to determine the category of response according to the standard. The reaction response of all of the HTPE motors impacted by bullet and fragment was judged as Type V burning.

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