• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.19 no.8
• /
• pp.8-13
• /
• 2018

Nitrogen oxides (NOx) have recently been very influential in the generation of ultrafine dust, which is of great social interest in terms of improving the atmospheric environment. Nitrogen oxides are generated mainly by the reaction of nitrogen and oxygen in air in a combustion gas atmosphere of high temperature in a combustion apparatus such as thermal power generation. Recently, research has been conducted on the combustion that recirculates the exhaust gas to the cylindrical burner by using a piping using a Coanda nozzle. In this study, three types of burners were carried out through computational fluid analysis. Case 1 burner with the outlet of the combustion gas to the right, Case 2 burner with both sides as gas exit, Case 3 burner with left side gas exit. The pressure, flow, temperature, combustion reaction rate and distribution characteristics of nitrogen oxides were compared and analyzed. The combustion reaction occurred in Case 1 and Case 2 burner in the right direction with combustion gas recirculation inlet and Case 3 burner in the vicinity of mixed gas inlet. The temperature at the outlet was about $100^{\circ}C$ lower than that of the other burners as the Case 2 burner was exhausted to both sides. The NOx concentration of Case 1 burner at the exit was about 20 times larger than that of the other burners. From the present study, it could be seen that it is effective for the NOx reduction to exhaust the exhaust gas to both side gas exits or to exhaust the exhaust gas to the opposite direction of inlet of recirculation gas.

• Fire Science and Engineering
• /
• v.20 no.2 s.62
• /
• pp.1-7
• /
• 2006

The aim of the research is to estimate the effect of smoke and combustion gases on humane body indirectly through measuring the toxicity of those. For this purpose, the toxic index of smoke and combustion gases was investigated by smoke hazard test and analysis of smoke which were conducted by KS F 2271 and NES 713 method respectively. It i s proved by KS F 2271 method that PASCON trough is suitable to the testing standard of interior material and construction of building. In addition, it is identified by NES 713 method that combustion gases occurring in PASCON product were only carbon dioxide and carbon monoxide, and the smoke index of those was 0.944. This value means that the hazard effect of smoke gases on humane ! body can possibly happens when exposed to the smoke gases for more than 30 min. In aspect of the domestic situation that have not regulated the hazard estimation and the emissions of smoke when the flame retarding ability of the products have been requested, the toxic indexes of PASCON products are comparatively low.

• Proceedings of the Korean Environmental Sciences Society Conference
• /
• 2003.05a
• /
• pp.38-40
• /
• 2003

본 연구에서 적용한 저 NOx 연소법의 NOx 저감 효과를 비교해 보면 다단 연소법이 지연연소 효과와 국부적인 최고 화염온도 감소, 고온부에서의 산소농도 감소효과 등이 동시에 나타나 저 과잉공기 연소법, 배기가스 재순환법, 이단 연소법 보다 더 큰 NOx 저감효과를 얻을 수 있음을 알 수 있었다. 다만, 총 공급공기 량에 대한 분할 공급공기량의 비가 일정수준 이상으로 커지면 CO 발생량 증가로 효율저하 등의 문제점이 우려되므로 연소상태를 저하시키지 않는 공급비를 산정하는 것이 중요할 것으로 생각된다.

• Journal of Energy Engineering
• /
• v.6 no.2
• /
• pp.203-211
• /
• 1997

This study is on the separation of Global warming effect gas, CO$_2$by chemical absorption from mixture of CO$_2$-N$_2$which was modeled after flue gas of fire power plant. Investigation of optimum condition for absorbent was carried out by using sparged vessel apparatus. Through packed tower experiments, applicabilities of two absorption models were tested by comparing experimental results with theoretical values. Absorbent used in the experiments was Monoethanolamine (MEA) and gas mixture was made in the mole composition of 15% CO$_2$and 85% N$_2$. Through estimations of CO$_2$loading and CO$_2$removal efficiency, optimum concentration of absorbent was found in the range of 4-5 M. To find a rate of absorption, an enhancement factor was introduced. Values of rate of absorption were calculated by Film model and Higbie model, respectively. Higbie model showed good agreement with experimental results. Therefore, this models is considered to be applicable to the CO$_2$separation process for flue gas from fire power plant.

• Journal of the Korean Wood Science and Technology
• /
• v.44 no.5
• /
• pp.639-654
• /
• 2016

This study building materials by relates to human hazard assessment in accordance with the combustion gas SEM, the flame-retardant foam FTIR and cone calorimeter to configure the Forest products of MDF and preservative treated Lauan two kinds of Retardant styrofoam, Styrofoam, Urethane foam and gypsum board four kinds of plastics material by the combustion gas were each analyzed. MDF was burned to the structure of the wood and the glue evenly mixed combustion area preservative treated Lauan, kept constant even in the form of high heat to penetrate deep into the wood flame retardant agents. Retardant styrofoam is due to feed my Dropped dissolved inorganic flame retardant without the fire-stick and confirmed that the weak form of gypsum board, but keep the column. In MDF ammonia ($NH_3$), lethal concentration (750 ppm) compared to 795 ppm, preservative treated Lauan is carbon dioxide ($CO_2$) that was greater than 2.5 times the lethal concentration (100,000 ppm) to 256,965 ppm, the lethal concentration (500 ppm) of hydrogen chloride (HCl). The Urethane greater than 697 ppm, 434 ppm also greatly exceeding the nitrogen dioxide ($NO_2$) lethal concentration (250 ppm) in Retardant styrofoam and 398 ppm was released. It is confirmed that the human body is extremely harmful gas emitted from most of the materials to be utilized as basic data for evaluating the hazard-specific human future building material.

• Fire Science and Engineering
• /
• v.16 no.3
• /
• pp.77-83
• /
• 2002

We measured flame extinguishing concentration and flue gas composition in the n-heptane fuel cup-burner system using inert gas agents such as nitrogen, argon, carbon dioxide and their mixtures. The flame extinguishing concentration of binary gaseous mixture was well predicted by model which contains the flame extinguishing concentration and composition of pure components. The higher average specific gravity of the mixed inert gas agents, the more excellent flame extinguishing performance. And the structure of enclosed space also affects the fire extinguishing. The composition of carbon dioxide in the flue gas was decreased with increasing extinguishing agent used. Nitrogen monoxide production is not related with increasing nitrogen, but increased at rapid mass flow rate of air in the cup-burner.

• Clean Technology
• /
• v.24 no.3
• /
• pp.212-220
• /
• 2018

Oxy-fuel combustion is considered as a promising greenhouse gas reduction technology in power plant. In this study, the behaviors of NO and $SO_2$ were investigated under the condition that in-furnace $deNO_x$ and $deSO_x$ methods are applied in oxy-fuel circulating fluidized bed combustion condition. In addition, the generation trends of $SO_3$, $NH_3$ and $N_2O$ were observed. For the purpose, limestone and urea solution were directly injected into the circulating fluidized bed combustor. The in-furnace $deSO_x$ method using limestone could reduce the $SO_2$ concentration in exhaust gas from ~403 to ~41 ppm. At the same experimental condition, the $SO_3$ concentration in exhaust gas was also reduced from ~3.9 to ~1.4 ppm. This trend is mainly due to the reduction of $SO_2$. The $SO_2$ is the main source of the formation of $SO_3$. The negative effect of $CaCO_3$ in limestone, however, was also appeared that it promotes the NO generation. The NO concentration in exhaust gas reduced to ~26 - 34 ppm by appling selective non-catalytic reduction method using urea solution. The $NH_3$ concentration in exhaust gas was appeared up to ~1.8 ppm during injection of urea solution. At the same time, the $N_2O$ generation also increased with increase of urea solution injection. It seems that the HNCO generated from pyrolysis of urea converted into $N_2O$ in combustion atmosphere. From the results in this study, the generation of other pollutants should be checked as the in-furnace $deNO_x$ and $deSO_x$ methods are applied.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.10 no.12
• /
• pp.3761-3767
• /
• 2009

This study was investigated to determine the combustion characteristics, decomposition efficiency, and the flue gas concentrations after combustion in the high temperature reactor($1,250{\sim}1,400^{\circ}C$, 1 atm) for the liquid wastes(waste oil and waste solvent) generated from the industrial complex. The concentration of nitrogen oxide(NOx) is decreased and the synthetic gas is increased when the mass ratio of $O_2$/waste is about 1.53 because the reaction condition was changed to reduction state. And BTEXs(benzene, toluene, ethylbenzene, xylene) are decomposed more than 99.99%. If the highly concentrated liquid waste (waste oil and waste solvent) is treated under the operating conditions suggested by this study, our treatment method for the liquid waste was found to be proper because of the contaminants emission concentration is very low. In addition, the synthetic gas after combustion can be used as an alternative fuel.

• Journal of the Korean Institute of Gas
• /
• v.15 no.3
• /
• pp.26-30
• /
• 2011

Instantaneous water heater being not properly installed and not adequately maintained may produce fatal accidents due to carbon monoxide poisoning and suffocation. Insufficient supply of air into the gas appliance for complete burning of the fuel or blocking the outlet of the combustion gas could be a cause to increase carbon monoxide concentration in the exhaust gas of the gas appliance. In this work, the experiments are done with a collected instantaneous water heater using in domestic and the concentration of oxygen near the gas appliance and carbon monoxide in exhaust gas are observed to investigate the risk of instantaneous water heater. The concentration of oxygen near the gas appliance is reduced until 17.7% for the ratio of the ventilation area and floor area being 3.5%. If the outlet of combustion gas is blocked, the carbon monoxide concentration is steeply increasing more than 4,000ppm. Therefore, periodic checking the outlet of combustion gas is more important than vent area to reduce the risk of carbon monoxide poisoning.

• Journal of Energy Engineering
• /
• v.19 no.3
• /
• pp.156-162
• /
• 2010

3-D CFD(Computational Fluid Dynamics) work were carried out to investigate the combustion characteristics in a boiler depending on the variations in air supply condition. For the gas temperature, $O_2$, NO, SOx at the outlet of economizer, the predicted values were been compared with the measured data. With the verified CFD model, the effects of air flow rates through SOFA(Separated Over Fire Air) and CCOFA(Closed Coupled Over Fire Air) on the combustion behavior in a boiler were simulated, and the distributions of NOx and gas temperature were mainly compared each other. The change in SOFA air flow rate gave the more sensitive effect on NOx than that in CCOFA. The distributions of gas temperature at convection path are differed with the changes in SOFA and CCOFA flow rate, so the combustion modification such as yaw anlge adjustment are required to get an enhanced gas temperature distribution.